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See detailDe la crise à l’entreprise, en passant par toi…
Choffray, Jean-Marie ULg

E-print/Working paper (2014)

De la crise à l’entreprise, en passant par toi… est une invitation à l’action, à la prise de responsabilité, à la création responsable de valeur économique et à la recherche obstinée de croissance ... [more ▼]

De la crise à l’entreprise, en passant par toi… est une invitation à l’action, à la prise de responsabilité, à la création responsable de valeur économique et à la recherche obstinée de croissance rentable. Oui! Notre monde vient d’échapper à un effondrement systémique dont 1929 n’aurait constitué qu’un aimable préambule. Oui ! L’entreprise est le seul acteur social créateur de richesse économique et la seule solution au mal qui se répand. Oui ! Il est extrêmement difficile de changer quoi que ce soit sur terre et d’apprendre à dire « non ! » En cas d’échec, le coût est connu : licenciement, exil, condamnation à mort ! [less ▲]

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See detailSynthesis, Surface characterization and photocatalytic activity of TiO2 supported on almond shell activated carbon
Omri, Abdessalem; Lambert, Stéphanie ULg; Geens, Jérémy ULg et al

in Journal of Materials Science & Technology (2014), 30(9), 894-902

Three types of photocatalysts were synthesized by metal organic chemical vapor deposition and impregnation methods using the almond shell activated carbon as support. These photocatalysts denoted by (TiO2 ... [more ▼]

Three types of photocatalysts were synthesized by metal organic chemical vapor deposition and impregnation methods using the almond shell activated carbon as support. These photocatalysts denoted by (TiO2/ASAC (V), TiO2/ASAC (I1) and TiO2/ASAC (I2)) were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), diffuse reflectance spectroscopy (DRS) and nitrogen adsorptionedesorption isotherms. SEM observation shows that TiO2 was deposited on activated carbon surface. XRD results confirm that TiO2 existed in a mixture of anatase and rutile phases. The DRS spectra show the characteristic absorption edge of TiO2 at approximate 380 nm corresponding to the optical band gap of 3.26 eV. Besides, FTIR spectrum indicated the presence of (TieO) groups. The specific surface area of photocatalysts decreased drastically in comparison with the original activated carbon. The catalysts were very efficient for the photodegradation of total organic carbon (TOC) from industrial phosphoric acid solution under UV irradiation. The kinetics of photocatalytic TOC degradation was found to follow a pseudofirst- order model. The prepared TiO2/ASAC showed high photoactivity for the photodegradation of TOC in the following order: TiO2/ASAC (V) > TiO2/ASAC (I1) > TiO2/ASAC (I2) > ASAC > TiO2 (P25). [less ▲]

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See detailA Geometrical Acoustics Approach Linking Surface Scattering and Reverberation in Room Acoustics
Embrechts, Jean-Jacques ULg

in Acta Acustica United with Acustica (2014), 100(5), 864-879

A general model of the influence of surface scattering on the reverberation time would have several applications in room acoustics. Such a model is not yet available, and it is the purpose of this paper ... [more ▼]

A general model of the influence of surface scattering on the reverberation time would have several applications in room acoustics. Such a model is not yet available, and it is the purpose of this paper to investigate a geometrical acoustics approach. Starting from the radiative transfer equation, an exponential solution is first developed for the reverberation energy decay in rooms with diffusely reflecting boundaries. Differences with the diffuse sound field (Sabine) theory are highlighted, leading to a modified formula for the reverberation time which is shown to be more in accordance with ray tracing simulations. A general model is then proposed for rooms in which specular and diffuse reflections coexist. This general model is applied in rooms where the specular contribution can be assumed to be quasi-isotropic and uniform. Under this assumption, the reverberation decay is represented by the sum of two exponential functions, depending on the scattering coefficients. However, it is shown that the influence of surfaces’ scattering on reverberation is rather limited in this case. On the contrary, rooms with a pair of parallel surfaces are prone to create significant anisotropy in the cloud of image sources. An analytical formulation is proposed in this case for the specular and diffuse contributions, provided that some assumptions are again made on the specularly reflected sound field. The final expression is not really intuitive concerning the relation between scattering coefficients and reverberation, but it contains all the variables influencing this relation. This allows fast evaluations of the effect of surface scattering in particular situations. Finally, the application of this model to room acoustics computer simulations is illustrated by an example. [less ▲]

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See detailPolymer topology revealed by ion mobility coupled with mass spectrometry
Morsa, Denis ULg; Defize, Thomas ULg; Dehareng, Dominique ULg et al

in Analytical Chemistry (2014), 86(19), 96939700

Hyperbranched and star shaped polymers have raised tremendous interests because of their unusual structural and photochemical properties which provide them potent applications in various domains, namely ... [more ▼]

Hyperbranched and star shaped polymers have raised tremendous interests because of their unusual structural and photochemical properties which provide them potent applications in various domains, namely in the biomedical field. In this context, the development of adequate tools aiming to probe particular three-dimensional features of such polymers is of crucial importance. In this present work, ion mobility coupled with mass spectrometry was used to experimentally derive structural information related to cationized linear and star-shaped poly-ε-caprolactones as a function of their charge state and chain length. Two major conformations were observed and identified using theoretical modeling: (1) near spherical conformations whose size is invariant with the polymer topology for long and lightly charged chains and (2) elongated conformations whose size varies with the polymer topology for short and highly charged chains. These conformations were further confirmed by collisional activation experiments based on the ejection thresholds of the coordinated cations that vary according to the elongation amplitude of the polymer chains. Finally, a comparison between solution and gas-phase conformations highlights a compaction of the structure with a loss of specific chain arrangements during the ionization and desolvation steps of the electrospray process, fueling the long-time debated question related to the preservation of the analyte structure during the transfer into the mass spectrometer. [less ▲]

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See detailRole of estradiol in the feminization of lordosis behavior
Trouillet, Anne-Charlotte ULg

Poster (2014, September)

The classic theory of mammalian brain and behavioral sexual differentiation holds that an organizational action of testosterone, secreted perinatally by the male’s testes, controls male-typical aspects of ... [more ▼]

The classic theory of mammalian brain and behavioral sexual differentiation holds that an organizational action of testosterone, secreted perinatally by the male’s testes, controls male-typical aspects of brain and behavioral development, whereas no active perinatal sex hormone signaling is required for female-typical differentiation. However, it has recently been shown using aromatase knock out (ArKO) mice, which are deprived of estradiol due to a targeted mutation in the aromatase gene, that estradiol may also actively contribute to the differentiation of female-typical aspects of behavior over a specific pre-pubertal period. Sexual behavior is a well known sexually dimorphic behavior, and thus provides a good model for studying the sexual differentiation of the brain. Female ArKO mice showed significantly lower levels of lordosis behavior than wild type controls following adult ovariectomy and treatment with ovarian hormones. This deficit was restored by treating female ArKO mice with estradiol benzoate between postnatal days 15 and 25. However, the mechanism by which estradiol acts prepubertally in female mice to feminize lordosis behavior remains to be elucidated. Therefore, in a first attempt, we will determine which neuropeptides are in particularly sensitive to estradiol action over the prepubertal period. We will focus on neuropeptides which have been shown to be implicated in lordosis behavior. Studies by the group of Micevych have proposed an important role for NPY and beta-endorphin (B-END) neurons in the arcuate nucleus (ARC) in the estradiol-mediated activation of lordosis behavior in female rats. An in vitro study recently showed that kisspeptin directly activates arcuate (ARC) B-END neurons. This is particularly interesting since unpublished results from our laboratory showed that Kp neurons are directly involved in the expression of lordosis behavior. We are thus currently determining the expression of NPY, B-END, and kisspeptin in the ARC as well as μ-opioid receptors MORs in the MPN over the prepubertal period and their possible modulation by prepubertal estradiol treatment. Interestingly, we also observed that our treatment may have an organizational effect on the regulation of energy balance. Indeed, administration of estradiol over the prepubertal period restores a normal weight in ArKO mice, which are normally obese in adulthood. It has been shown that ArKO mice present a lower spontaneous physical activity which can be one cause of their obesity. However, our treated mice did not show an increase in their locomotion behavior. These new observations suggest that estradiol during prepubertal development may have an additional role in the organization of brain circuits regulating the energy balance. [less ▲]

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See detailBrentano, la théorie des catégories et la définition de la substance
Boccaccini, Federico ULg

Scientific conference (2014, September)

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See detailManuel de droit du travail
Clesse, Jacques ULg; Kéfer, Fabienne ULg

Book published by Larcier (2014)

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See detailMathematical modeling of HIV dynamics after antiretroviral therapy initiation: A clinical research study
Moog, Claude; Rivadeneira, Pablo; Stan, Guy-Bart et al

in AIDS Research and Human Retroviruses (2014), 30(9), 831-834

Immunological failure is identified from the estimation of certain parameters of a mathematical model of the HIV infection dynamics. This identification is supported by clinical research results from an ... [more ▼]

Immunological failure is identified from the estimation of certain parameters of a mathematical model of the HIV infection dynamics. This identification is supported by clinical research results from an original clinical trial. Standard clinical data were collected from infected patients starting Highly Active Anti-Retroviral Therapy (HAART), just after one month following therapy initiation and were used to carry out the model identification. The early diagnosis is shown to be consistent with the patients monitoring after six months. [less ▲]

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See detailIntroducing the Belgian Science and Technology Studies Network (BSTS)
Meyers, Gert; Van Oudheusden, Michiel ULg; Thoreau, François ULg et al

Poster (2014, September)

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See detailGabriel García Márquez herschrijft Columbus
Vanden Berghe, Kristine ULg

in Streven. Cultureel Maatschappelijk maandblad (2014), 81/8

In "De herfst van de patriarch" (1975) parodieert Gabriel García Márquez een fragment uit de logboeken van Columbus. In de parodie komen enkele thema's en stijlkenmerken naar voren die het oeuvre van de ... [more ▼]

In "De herfst van de patriarch" (1975) parodieert Gabriel García Márquez een fragment uit de logboeken van Columbus. In de parodie komen enkele thema's en stijlkenmerken naar voren die het oeuvre van de Colombiaanse schrijver ten volle typeren, zoals het idee dat de geschiedenis zich herhaalt, het rechtmatige streven van Latijns-Amerika naar culturele en politieke ontvoogding tegenover Spanje en de VS, en het gevoel voor humor van de auteur - ook wanneer hij het over dergelijke ernstige kwesties heeft. [less ▲]

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See detailSELF BROADENING COEFFICIENTS AND IMPROVED LINE INTENSITIES FOR THE v7 BAND OF C2H4 NEAR 10.5 µm, AND IMPACT ON ETHYLENE RETRIEVALS FROM JUNGFRAUJOCH SOLAR SPECTRA
Vander Auwera, Jean; Fayt, André; Tudorie, Marcella et al

Poster (2014, September)

Relying on high-resolution Fourier transform infrared (FTIR) spectra, the present work involved extensive measurements of individual line intensities and self-broadening coefficients for the ν7 band of ... [more ▼]

Relying on high-resolution Fourier transform infrared (FTIR) spectra, the present work involved extensive measurements of individual line intensities and self-broadening coefficients for the ν7 band of 12C2H4. The measured self-broadening coefficients exhibit a dependence on both J and Ka. Compared to the corresponding information available in the latest edition of the HITRAN spectroscopic database, the measured line intensities were found to be higher by about 10 % for high J lines in the P branch and lower by about 5 % for high J lines of the R branch, varying between these two limits roughly linearly with the line positions. The impact of the presently measured line intensities on retrievals of atmospheric ethylene in the 949.0–952.0cm 1 microwindow was evaluated using a subset of ground-based high-resolution FTIR solar spectra recorded at the Jungfraujoch station. The use of HITRAN 2012 with line intensities modified to match the present measurements led to a systematic reduction of the measured total columns of ethylene by -4.1 +/- 0.1 %. [less ▲]

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See detailA case of true hermaphrodism in a horse
Parrilla-Hernadez, Sonia; de la Rebière de Pouyade, Geoffroy ULg; Grulke, Sigrid ULg et al

in Reproduction in Domestic Animals (2014, September), 49(suppl 3), 50

True hermaphroditism in horses, is a complex and poorly under- stood disorder of sexual development characterized by the presence of both male and female gonads as separate organs or in a combined ... [more ▼]

True hermaphroditism in horses, is a complex and poorly under- stood disorder of sexual development characterized by the presence of both male and female gonads as separate organs or in a combined structure called ovotestis. A 3-year-old Spanish nullipa- rous mare with a history of stallion behaviour and an abnormal reproductive exam was presented at the Equine Clinic of the University of Li ege. Externally, a small vulva with an enlarged clitoris was observed. Transrectal ultrasonography showed a thin (<1 cm) uterus, leading to a small heterogeneous structure in the normal place of the left ovary. No structure could be identified in the presumed location of the right ovary. Speculum exam was compatible with a vaginal agenesis, as the cervix opened craniad the urethral meatus. Oestradiol, progesterone and testosterone concen- trations were compatible with a stallion’s endocrinology. Gonads were laparoscopically found in the usual location of the ovaries in both flanks and excised. Histopathology of both gonads showed atrophic testicular tissue with hyperplastic Leydig cells. The left gonad also contained ovarian tissue with some scarce primordial follicles. Clitoral enlargement is the first symptom most commonly identified in animals with true hermaphroditism and can be explained by the production of testosterone by the gonads, however, the aetiology of the vaginal agenesis is unknown. True hermaph- roditism in horses is generally related to 64XX syndrome with or without SRY gene translocation (impending karyotyping analysis). After 5 days the mare was discharged from the clinic, and in absence of testosterone the stallion behaviour disappeared in a couple of months. [less ▲]

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See detailClinical and genetic aspects of familial isolated pituitary adenomas
Beckers, Albert ULg

in Abstract book - 14th International Workshop on Multiple Endocrine Neoplasia and other rare endocrine tumors (2014, September)

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See detailPituitary gland in MEN1 syndrome : from histopathology to prognosis
Villa, C; Bernier, M; Gaillard, S et al

in Abstract book - 14th International Workshop on Multiple Endocrine Neoplasia and other rare endocrine tumors (2014, September)

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See detailElicitor screening to protect winter wheat against Septoria tritici Blotch: preliminary results
Le Mire, Géraldine ULg; Deleu, Magali ULg; Ongena, Marc ULg et al

Conference (2014, September)

Elicitors are plant immunity-triggering compounds which are currently considered as one of the most promising tools in agriculture for the induction of plant resistance to various diseases (Mejía-Teniente ... [more ▼]

Elicitors are plant immunity-triggering compounds which are currently considered as one of the most promising tools in agriculture for the induction of plant resistance to various diseases (Mejía-Teniente et al., 2010). By contributing to both economic and environmental performances of agroecosystems, they can help reducing the use of chemical inputs. Although some elicitor products are already available on the market, it appears that a variable efficiency in the field, along with an uneasy integration in the current legislation and agricultural strategies, make these tools difficult to use (Walters, Ratsep, & Havis, 2013). Besides these limitations, few elicitor treatments have yet been efficiently and specifically designed to protect crop plants such as wheat, which is grown and consumed worldwide, against major diseases threatening both their yield and quality. There is a strong need to better understand the mechanisms of induced resistance in plants and develop elicitor use in agriculture. A phD research is currently led in Gembloux Agro Bio-Tech to develop a method based on eliciting agents, tested in greenhouse and field conditions, to protect winter wheat against major diseases, namely Septoria tritici, Fusarium graminearum and Fusarium culmorum. This project focuses on the screening of a large number of elicitors from different origins and structures. In 2014, we focused the first screening experiments on the protection of wheat against Septoria tritici Blotch (STB). Two winter wheat genotypes were tested: susceptible ‘Avatar’ and semi-resistant ‘Sy Epson’. Plants at 3-leaf stage were first sprayed till runoff with different concentrations of elicitors, and then inoculated 5 days later with a Septoria tritici spore suspension (106 spores mL-1) using a hand sprayer. Control plants were treated, prior to disease inoculation, with sterile water (negative control) or with BION® (ASM, Syngenta Europe; positive control). The disease severity and incidence were scored every 2 days for 28 days post-inoculation (d.p.i) by measuring the percentage of area covered with lesions and bearing pycnidia on the third leaf. The first results of these tests should enable a first discrimination of elicitors considering their dose-efficiency to reduce disease severity. After further screening of all the elicitors in hand, a determination of the elicitation pathways of the most efficient molecules tested will be undertaken. We intend to study the influence of various factors (i.e Temperature, relative humidity, plant development stage) on the elicitation potential and develop a formulation to be finally tested under field conditions. [less ▲]

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See detailHow to check analytically the robustness of a building submitted to a column loss - A premiere
Huvelle, Clara ULg; Jaspart, Jean-Pierre ULg; Demonceau, Jean-François ULg

in Proceedings of Eurosteel 2014 conference (2014, September)

Recent events such as natural catastrophes or terrorism attacks have highlighted the necessity to ensure the structural integrity of buildings under an exceptional event. According to Eurocodes and some ... [more ▼]

Recent events such as natural catastrophes or terrorism attacks have highlighted the necessity to ensure the structural integrity of buildings under an exceptional event. According to Eurocodes and some other national design codes, the structural integrity of civil engineering structures should be guaranteed through appropriate measures and one way to guarantee it is to ensure an appropriate robustness of the structure, which may be defined as the ability of a structure to remain globally stable in case of exceptional event leading to local damages. However, although global design approaches are provided in modern codes and standards, no easy-to-apply practical guidelines are provided. The present paper reflects recent researches realised at the University of Liege with the scope of proposing such practical guidelines for the activation of alternative load path in the structure, design strategy generally leading to the most economical solutions. [less ▲]

Detailed reference viewed: 35 (14 ULg)