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See detailDerjaguin-Broekhoff-de Boer analysis of adsorption in very disordered mesopores using probabilistic models
Gommes, Cédric ULg

Conference (2017, May 08)

Our current ability to produce mesoporous materials with ordered morphology has raised fascinating questions about the impact of geometrical disorder on adsorption and desorption states [1]. Many recent ... [more ▼]

Our current ability to produce mesoporous materials with ordered morphology has raised fascinating questions about the impact of geometrical disorder on adsorption and desorption states [1]. Many recent works have investigated the role of mild elements of disorder, such as local constriction or corrugation superimposed to otherwise geometrically ideal cylindrical pores [2,3]. These works have notably shown that elements of disorder may act as nucleation sites and destabilize vapor-like metastable states. The relevance of these perturbation-like results to fundamentally disordered materials, such as gels, is unclear. In particular, do vapor-like metastable states exist at all in this type of very disordered material? In the present communication, we address this question using probabilistic models to investigate the role of disorder. We generalize the classical Gaussian field models of porous materials [4] and use them to analyze adsorption and desorption in the Derjaguin-Broekhof-de Boer approximation. Our approach differs from earlier contributions in that both the adsorbent and the adsorbate are described in terms of probabilities [5]. This enables us to analyze the adsorbate configuration in very disordered solids using a low-dimensional yet realistic configuration space. We notably show that vapor-like metastable states are unlikely in gel-like disordered materials. [less ▲]

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See detailStudy of Meta-analysis strategies for network inference using information-theoretic approaches
Pham, Cam Ngoc ULg; Haibe-Kains; Bellot, Pau et al

in BioData Mining (2017)

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See detailObjets directs en kirundi
Tuyubahe, Pascal ULg

Conference (2017, May 05)

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See detailStaaten mit ausgeprägter Regionalautonomie - Fallstudie : Belgien
Behrendt, Christian ULg

Conference (2017, May 05)

Exposé donné à l'invitation du Congrès des pouvoirs locaux et régionaux du Conseil de l'Europe, dans le cadre de la conférence "Pour une réforme territoriale réussie : Causes et méthodes de réformes infra ... [more ▼]

Exposé donné à l'invitation du Congrès des pouvoirs locaux et régionaux du Conseil de l'Europe, dans le cadre de la conférence "Pour une réforme territoriale réussie : Causes et méthodes de réformes infra-nationales dans les pays membres du Conseil de l'Europe", Eupen, Belgique, 5 mai 2017. [less ▲]

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See detailHow microbes network (and are networked) in geological disposal research: a sociological perspective
Van Oudheusden, Michiel ULg; Schröder, Jantine; Turcanu, Catrinel

Conference (2017, May 05)

In MIND subtask 3.2, we ascertain whether and how microbes, microbiologists, and microbiology are enrolled into research on the geological disposal of radioactive waste. We adopt a social studies of ... [more ▼]

In MIND subtask 3.2, we ascertain whether and how microbes, microbiologists, and microbiology are enrolled into research on the geological disposal of radioactive waste. We adopt a social studies of science (actor-network theory) perspective that observes how actors within MIND (e.g. MIND researchers, members of the MIND Implementer Review Board) and outside the project (e.g. geologists, waste management regulators, policy makers) process data and generate insights on the role of microbes in waste disposal, and how these processes elicit challenges and opportunities for enrolment. Examples of the latter include mixed appreciations of the impact of microbial activity on artificial barriers (e.g. negligible vs. substantial), the scope for, and appeal of, institutional uptake of microbiology research (e.g. through the coupling of microbiology research to “the safety case”), and the (re)drawing of disciplinary boundaries (e.g. between microbiology and geology). Drawing on these and related examples, we explore how through projects like MIND, microbes network, and are networked, differently for the joint purpose of radioactive waste disposal. [less ▲]

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See detailManaging donor-related variability in cell production by means of data-based modelling
Mehrian, Mohammad ULg

Scientific conference (2017, May 05)

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See detailLes Hormones Glycoprotéiques: de la Clinique à la Recherche.
VALDES SOCIN, Hernan Gonzalo ULg

Doctoral thesis (2017)

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See detailLe volontariat : un levier vers l'emploi ?
Orianne, Jean-François ULg

Conference given outside the academic context (2017)

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See detailActivational and organizational disruption of folliculogenesis and estrous cycle caused by exposure to Bisphenol A (BPA) during early postnatal or adult life
Lopez Rodriguez, David ULg; Franssen, Delphine ULg; GERARD, Arlette ULg et al

Conference (2017, May 05)

Our previous studies have shown that an early postnatal exposure to a very low dose of bisphenol A (BPA) disrupts sexual maturation and pubertal timing. However, the long-term effects of such low dose ... [more ▼]

Our previous studies have shown that an early postnatal exposure to a very low dose of bisphenol A (BPA) disrupts sexual maturation and pubertal timing. However, the long-term effects of such low dose exposure as well as the effects of adult exposure have not been studied. One day-old and 90 day-old female rats received daily subcutaneous injections of corn oil (vehicle) or BPA (25ng/kg/d or 5mg/kg/d) for 15 days. The early postnatal exposure to both BPA doses significantly decreased the percentage of females with a regular cycle (BPA-25ng: 51±15%; BPA-5mg: 7±7%; OIL: 86±2%). The estrus cycle alterations were characterized by a decrease in time spent in proestrus (BPA-25ng: 13±3%; BPA-5mg: 12±3%; OIL: 18±3%). During adult exposure, both doses caused a disruption of the estrous cycle characterized by a significant decrease in the average time spent in proestrus (BPA-25ng: 19±2%; BPA-5mg: 17±1%; OIL: 23±1%). This effect was transient as the exposed females showed a regular cycle one month after the last dose of BPA. After adult exposure, we also observed a disruption of folliculogenesis characterized by a significant decrease of antral follicles (BPA-25ng: 21±2%; BPA-5mg: 21±2%; OIL: 36±2%) and increase of atretic follicles (BPA-25ng: 24±4%; BPA-5mg: 26±6%; OIL: 15±1%). GnRH secretion measured ex vivo 24h after adult exposure was moderately affected by BPA. Indeed, GnRH interpulse interval was significantly different when comparing animals exposed to the high or low dose of BPA but not when comparingexposed animals to the control group (BPA-25ng: 42.6±0.5; BPA-5mg: 40.2±0.6%; OIL: 41.1±0,2minutes±SEM). In conclusion, while exposure to BPA produces persistent alterations of the estrous cycle after early postnatal exposure, exposure during adulthood appears to cause activational non-persistent alternations of both the estrous cycle and folliculogenesis. [less ▲]

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See detailAdipsic diabetes insipidus revealing a bifocal intracranial germinoma
KREUTZ, Julie ULg; Potorac, Iulia ULg; LUTTERI, Laurence ULg et al

in Annales d'Endocrinologie (2017)

Abstract Adipsic diabetes insipidus is a rare complication of intracranial tumors in which impaired antidiuretic hormone secretion is associated with the loss of thirst sensation. Here, we present the ... [more ▼]

Abstract Adipsic diabetes insipidus is a rare complication of intracranial tumors in which impaired antidiuretic hormone secretion is associated with the loss of thirst sensation. Here, we present the case of a patient with bifocal intracranial germinoma, diagnosed due to symptoms mainly caused by adipsic diabetes insipidus. This is, to our knowledge, the first case of adipsic diabetes insipidus revealing an intracranial germinoma reported in the literature. We describe the diagnostic procedures and the three-year follow-up of this patient. Management of intracranial germ-cell tumors is made complex by the wide range of histological features. Although germinomas have a generally better prognosis than most nongerminomatous tumors, they can have severe or even life-threatening presentations. Adipsic diabetes insipidus is one such severe presentation and its rarity can make it difficult to recognize and manage. Awareness of this potential entity is therefore important for clinical practice. Le diabète insipide adipsique est une des rares complications des tumeurs intracrâniennes. Il associe une baisse de la sécrétion d’hormone antidiurétique à une perte de la sensation de soif et ilsignale souvent la présence d’une lésion qui atteint ou envahit l’hypothalamus. Nous présentons le cas d’une patiente avec un germinome intracrânien bifocal diagnostiqué devant un tableau de diabète insipide adipsique. À notre connaissance, il s’agit du premier cas de la littérature d’un diabète insipide révélant un germinome intracrânien. La prise en charge des tumeurs germinales intracrâniennes est complexe du fait des phénotypes histologiques divers. Bien que les germinomes ont généralement un meilleur pronostic que les tumeurs non-germinomateuses, ils peuvent avoir des présentations sévères. Le diabète insipide adipsique est une de ces présentations sévères et sa rareté peut rendre son diagnostic et sa prise en charge difficiles. La reconnaissance de cette entité potentielle est, dès lors, importante pour la pratique clinique [less ▲]

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See detailAIP mutations and gigantism
Rostomyan, Liliya ULg; Potorac, Iulia ULg; BECKERS, Pablo ULg et al

in Annales d'Endocrinologie (2017)

AIP mutations are rare in sporadic acromegaly but they are seen at a higher frequency among certain specific populations of pituitary adenoma patients (pituitary gigantism cases, familial isolated ... [more ▼]

AIP mutations are rare in sporadic acromegaly but they are seen at a higher frequency among certain specific populations of pituitary adenoma patients (pituitary gigantism cases, familial isolated pituitary adenoma (FIPA) kindreds, and patients with macroadenomas who are diagnosed ≤ 30 years). AIP mutations are most prevalent in patients with pituitary gigantism (29% of this group were found to have mutations in AIP gene). These data support targeted genetic screening for AIP mutations/deletions in these groups of pituitary adenoma patients. Earlier diagnosis of AIP-related acromegaly-gigantism cases enables timely clinical evaluation and treatment, thereby improving outcomes in terms of excessive linear growth and acromegaly comorbidities. Bien que les mutations du gène AIP soient rares dans les cas d’acromégalie sporadique, l’importance de ces mutations est établie dans des populations spécifiques de patients telles que les patients qui souffrent de familial isolated pituitary adenomas (FIPA), de gigantisme ou qui présentent un macroadénome hypophysaire avant l’âge de 30 ans. C’est dans le gigantisme qu’elles sont le plus fréquemment retrouvées (29 % des géants présentent une mutation de ce gène). Dans ces populations, nos données suggèrent qu’il est utile de réaliser un screening ciblé pour les mutations ou délétions du gène AIP. La reconnaissance précoce des cas d’acromégalie et de gigantisme permet une évaluation clinique et un traitement appropriés de ces patients. Elle contribue à améliorer les résultats des traitements tant en terme de croissance excessive qu’en ce qui concerne les comorbidités liées à l’acromégalie. [less ▲]

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See detailFunctional emulsion-templated macroporous polymers via controlled radical polymerization
Mathieu, Kevin ULg; Jérôme, Christine ULg; Debuigne, Antoine ULg

Conference (2017, May 05)

Macroporous polymer monoliths with interconnected structures have attracted considerable interest in the fields of supported catalysis, chromatography, water purification, etc. A popular and ... [more ▼]

Macroporous polymer monoliths with interconnected structures have attracted considerable interest in the fields of supported catalysis, chromatography, water purification, etc. A popular and straightforward synthesis approach for such open-cell polymers is based on the emulsion-templated polymerization. In this strategy, a major phase is dispersed in a minor continuous phase containing monomers, cross-linker, initiator and surfactant. The curing of the continuous phase followed by the removal of the dispersed phase leads to a monolith with voids interconnected by pores. Size and number of the latters are influenced by several parameters and especially by the nature of the surfactant. Consequently, we prepared by controlled radical polymerization a series of well-defined amphiphilic copolymers having different hydrophilic-lipophilic balance (HLB) and chain-ends, used it as stabilizers for the emulsion-templated polymerizations and demonstrated the crucial effect of the macromolecular features as well as the concentration on the foam morphology. Secondly, the physical and the chemical anchoring of the macromolecular surfactants at the surface of the pores were also considered for tuning the surface properties of the porous monoliths in one step. This strategy was also implemented with alkyne-terminated copolymers in order to decorate the surface of the cavities with “clickable” moieties which broadens the scope of functional macroporous polymers. [less ▲]

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See detailGérer ses références bibliographiques avec ZOTERO
Cordier, Quentin ULg; Desseilles, François ULg

Scientific conference (2017, May 05)

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See detailMONitOring des flux de POLluants dans les Eaux Souterraines
Jamin, Pierre ULg; Dassargues, Alain ULg; Brouyère, Serge ULg

Poster (2017, May 05)

Contaminated aquifers management is currently based on the evaluation of pollutant concentration in the groundwater. This approach is necessary but totally insufficient to evaluate the risk posed by the ... [more ▼]

Contaminated aquifers management is currently based on the evaluation of pollutant concentration in the groundwater. This approach is necessary but totally insufficient to evaluate the risk posed by the contamination to potential receptors. Since the risk is due to the pollutant that are actually moving, and might reach a receptor, this concentration measurement should be combined to a measurement of the groundwater flow velocity (i.e. the driving force of contaminant migration in aquifers), to quantify the contaminant mass flux at which the receptor is exposed. We propose a new point dilution technique able to measure accurately the groundwater flux and to monitor continuously its changes with time. [less ▲]

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See detailTo be plastic is fantastic: delineate coral species niches for assessing their tolerance to changes
Denis, Vianney; Sturaro, Nicolas ULg; Yang, Shan-Hua et al

Conference (2017, May 05)

Climatic and anthropogenic disturbances alter coral reefs by reconfiguring existing coral assemblages. Surviving species are selected by the new environment based on particular traits that they may ... [more ▼]

Climatic and anthropogenic disturbances alter coral reefs by reconfiguring existing coral assemblages. Surviving species are selected by the new environment based on particular traits that they may exhibit, with the plasticity in traits defining ecological strategies associated with contrasting degrees of tolerance to changes. In this process, specialists are expected to tolerate few changes to the environmental conditions and are restricted to specific habitat, while generalists can cope with a wider range of environmental conditions by readjusting traits according to the habitat’s features. Ecological strategies in corals have been exclusively defined according to species’ trait averages, irrespective of individual variations. Challenges representing the acquisition and use of energy have also tended to be oversimplified, specifically by the choice of easy traits in the absence of strong scientific evidence. In this study, we propose a re-examination of strategies in scleractinian corals by focusing on the intraspecific variation of traits. We will investigate how the characteristics of a given species niche can help coral species to tolerate changes. Our multidisciplinary approach will focus on three major characteristics of the coral holobiont (its physiology, trophic ecology, and associated microbiome) which together can define the ecological plasticity of species. This work is of tremendous importance for enhancing the understanding of coral response to environmental changes and for ensuring functions as well as the services of this ecosystem to future generations. [less ▲]

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See detailFrom the shortest to the tallest
Beckers, Albert ULg

in Annales d'Endocrinologie (2017), 78

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