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See detailScreening for the metabolic syndrome in subjects with migraine
Streel, Sylvie ULg; Donneau, Anne-Françoise ULg; Dardenne, Nadia ULg et al

in Cephalalgia : An International Journal of Headache (2016)

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See detailMise en place de pratiques agricoles de conservation: quel impact sur la vie du sol
Degrune, Florine ULg; Boeraeve, Fanny ULg; Vandenbol, Micheline ULg et al

Poster (2016, October 04)

Le projet Farm4Future a été lancé en 2015 et consiste en un suivi intégré d’un réseau d’exploitations agricoles belges en cours de transition vers des pratiques dites « de conservation ». Les ... [more ▼]

Le projet Farm4Future a été lancé en 2015 et consiste en un suivi intégré d’un réseau d’exploitations agricoles belges en cours de transition vers des pratiques dites « de conservation ». Les exploitations étudiées dans le cadre de ce projet sont caractérisées par des changements de gestion incluant notamment : (1) des associations de culture, (2) des couverts permanents, (3) une réduction du travail du sol et (4) l’introduction de structures vertes telles que les haies ou les bandes fleuries. Afin d’évaluer le potentiel agronomique et écologique de ces systèmes agricoles, une série de mesures ont été effectuées dans deux types de sol aux propriétés texturales contrastées : sable limoneux et un limon sableux. Afin d’obtenir un point de comparaison, les mêmes mesures ont été effectuées sur les parcelles des agriculteurs voisins restés en intensif et conventionnel. Parmi ces mesures, nous étudions la réponse de plusieurs indicateurs biologiques de qualité des sols telle que la diversité microbienne. L’étude a démontré un effet du type de pratiques agricoles sur la diversité microbienne en fonction du type de sol. Nous avons également identifié les microorganismes sensibles au type de pratiques agricoles. Cependant, l’étude nous amène à démontrer une grande hétérogénéité de réponses au sein de chacun de ces groupes. En effet, même si certains grands groupes sont globalement plus abondants sous pratiques de conservation (ou conventionnel), la réponse des microorganismes au sein de ces groupes à des niveaux taxonomiques plus fins (genre ou espèce) n’est pas uniforme. Aujourd’hui, même si les outils moléculaires de séquençage à haut débit ont permis de mettre en lumière l’incroyable diversité microbienne des sols, les services écosystémiques rendus par ces microorganismes sont encore très peu connus car moins de 1% des organismes est cultivable en laboratoire. [less ▲]

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See detailInterprétation des souffles et arythmies chez le cheval: Quand faut-il s'inquiéter?
Leroux, Aurélia ULg

Conference given outside the academic context (2016)

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See detailMaize plants can enter a standby mode to cope with chilling stress
Riva-Roveda, Laetitia ULg; Escale, Brigitte; Giauffret, Catherine et al

in BMC Plant Biology (2016), 16

Background European Flint maize inbred lines are used as a source of adaptation to cold in most breeding programs in Northern Europe. A deep understanding of their adaptation strategy could thus provide ... [more ▼]

Background European Flint maize inbred lines are used as a source of adaptation to cold in most breeding programs in Northern Europe. A deep understanding of their adaptation strategy could thus provide valuable clues for further improvement, which is required in the current context of climate change. We therefore compared six inbreds and two derived Flint x Dent hybrids for their response to one-week at low temperature (10°C day/7 or 4°C night) during steady-state vegetative growth. Results Leaf growth was arrested during chilling treatment but recovered fast upon return to warm temperature, so that no negative effect on shoot biomass was measured. Gene expression analyses of the emerging leaf in the hybrids suggest that plants maintained a ‘ready-to-grow’ state during chilling since cell cycle genes were not differentially expressed in the division zone and genes coding for expansins were on the opposite up-regulated in the elongation zone. In photosynthetic tissues, a strong reduction in PSII efficiency was measured. Chilling repressed chlorophyll biosynthesis; we detected accumulation of the precursor geranylgeranyl chlorophyll a and down-regulation of GERANYLGERANYL REDUCTASE (GGR) in mature leaf tissues. Excess light energy was mostly dissipated through fluorescence and constitutive thermal dissipation processes, rather than by light-regulated thermal dissipation. Consistently, only weak clues of xanthophyll cycle activation were found. CO2 assimilation was reduced by chilling, as well as the expression levels of genes encoding phosphoenolpyruvate carboxylase (PEPC), pyruvate orthophosphate dikinase (PPDK), and the small subunit of Rubisco. Accumulation of sugars was correlated with a strong decrease of the specific leaf area (SLA). Conclusions Altogether, our study reveals good tolerance of the photosynthetic machinery of Northern European maize to chilling and suggests that growth arrest might be their strategy for fast recovery after a mild stress. [less ▲]

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See detailRisques et catastrophes climatiques en Afrique de l’Ouest : Gérer l’inéluctable
Ozer, Pierre ULg

Scientific conference (2016, October 03)

L’Afrique de l’Ouest compte de plus en plus de personnes affectées par les catastrophes climatiques. Cette conférence présentera quelques études de cas en Afrique de l’Ouest pour finalement s’interroger ... [more ▼]

L’Afrique de l’Ouest compte de plus en plus de personnes affectées par les catastrophes climatiques. Cette conférence présentera quelques études de cas en Afrique de l’Ouest pour finalement s’interroger sur l’immunité du Niger confrontée à de multiples stress endogènes et exogènes dont la juxtaposition pourrait éroder sa résilience sur le long terme et entraîner le pays dans une spirale de ‘maladaptation’. [less ▲]

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See detailThe functional-biogeography of the reef fishes in the Gulf of California: over-importance of a handful of sites
Olivier, Damien ULg; Reyes Bonilla, Hector

Poster (2016, October 03)

Functional biogeography is a new discipline allowing to link biogeographical patterns of trait and species diversity. This new area of research has a role in conservation policy because it permits to ... [more ▼]

Functional biogeography is a new discipline allowing to link biogeographical patterns of trait and species diversity. This new area of research has a role in conservation policy because it permits to create functional maps to highlight hotspots of biodiversity. In this study, we evaluate the taxonomic and functional diversity of the reef-fishes in 30 “archipelagoes” widespread along the Gulf of California (GOC). The question before us is to highlight areas requiring a particular intention in conservation policy because they represent a large part of the legacy of reef-fish diversity in the GOC. To do so, we used a recently developed method to classify the reef-fishes species of the GOC in functional entities (FEs). The FEs are based on unique combinations of six categorical traits known to influence the functional role of fishes (e.g. size, diet…) and their number represent the level of functional diversity of the community. The results showed that the Baja California Sur has the most diversified reef-fishes community, both taxonomically and functionally (more than 90% of the species and of the functional diversity are represented). This result is mainly due to four archipelagoes that present a dazzling diversity, i.e. Carmen, San José, Espiritu Santo and Cerralvo. Each of these islands includes 60% or more of the taxonomic and functional diversity of the GOC. Two of these archipelagoes benefit of a protection level through the National Parks of Loreto and Espiritu Santo. However, the former is poorly functioning and the latter is under evaluation. The outcomes of the present study provide a global map of the reef-fishes diversity through the GOC, in term of species number and functional diversity. These results allow the identification of four major hotspots of diversity that should require a particular attention to preserve the legacy of reef-fishes diversity in the GOC. [less ▲]

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See detailDe la carte à la géovisualisation 3D
Billen, Roland ULg

Conference given outside the academic context (2016)

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See detailA Stochastic Multi-Scale Approach for the Modeling of Thermo-Elastic Damping in Micro-Resonators
Wu, Ling ULg; Lucas, Vincent ULg; Nguyen, Van Dung ULg et al

in Computer Methods in Applied Mechanics & Engineering (2016), 310

The aim of this work is to study the thermo-elastic quality factor (Q) of micro-resonators with a stochastic multi-scale approach. In the design of high-Q micro-resonators, thermo-elastic damping is one ... [more ▼]

The aim of this work is to study the thermo-elastic quality factor (Q) of micro-resonators with a stochastic multi-scale approach. In the design of high-Q micro-resonators, thermo-elastic damping is one of the major dissipation mechanisms, which may have detrimental effects on the quality factor, and has to be predicted accurately. Since material uncertainties are inherent to and unavoidable in micro-electromechanical systems (MEMS), the effects of those variations have to be considered in the modeling in order to ensure the required MEMS performance. To this end, a coupled thermo-mechanical stochastic multi-scale approach is developed in this paper. Thermo-mechanical micro-models of polycrystalline materials are used to represent micro-structure realizations. A computational homogenization procedure is then applied on these statistical volume elements to obtain the stochastic characterizations of the elasticity tensor, thermal expansion, and conductivity tensors at the meso-scale. Spatially correlated meso-scale random fields can thus be generated to represent the stochastic behavior of the homogenized material properties. Finally, the distribution of the thermo-elastic quality factor of MEMS resonators is studied through a stochastic finite element method using as input the generated stochastic random field. [less ▲]

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See detailFacteurs d’ambiance dans l’industrie textile en République Démocratique du Congo: état de lieu
Panda Lukongo, Kitronza ULg; Mairiaux, Philippe ULg

in Pan African Medical Journal (The) (2016), 25(44),

Introduction: This case study aims to make an assessment of environmental health nuisances in textile industry in the Democratic Republic of Congo. Methods: We conducted a cross-sectional and analytical ... [more ▼]

Introduction: This case study aims to make an assessment of environmental health nuisances in textile industry in the Democratic Republic of Congo. Methods: We conducted a cross-sectional and analytical study. Out of 257 workers selected using systematic sampling, 229 workers were enrolled in the study. 223 workstations were subjected to measurements in order to determine the level of noise, lighting and heat. Data were collected from company documents, by means of a direct-question interview focusing on socio professional informations and through measurements. Descriptive analysis was used for sociodemographic and professional data and analytical approach was used for themeasurements. Results: In the company studied 88% of employees were workers. Weaving department included almost 68% of workers. The majority of employees worked as part of a three shift (85%). The study population was predominantly male (85%), aging (52%) over 40 years and educated (80%). In the company studied, only 12.1% of workstations met the noise standards and 18% of workstations met the lighting standards. 94% of workstations didn't meet the heat standards for heavy work. Conclusion: Our study highlighted the environmental health nuisances in textile industry, demonstrating the existence of significant gaps related to the prescribed standards for the measured nuisances. These results are a plea for the development of appropriate preventive measures. They should be confronted with other more detailed studies in this work environment. [less ▲]

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See detailTweeting is not investing! But...
Choffray, Jean-Marie ULg

E-print/Working paper (2016)

So, here we are! Hundreds of Tweets on The Art and Science of Investing to “show you the way”, to share some observations on the markets and their behavior, and to illustrate the key heuristics that I ... [more ▼]

So, here we are! Hundreds of Tweets on The Art and Science of Investing to “show you the way”, to share some observations on the markets and their behavior, and to illustrate the key heuristics that I learned over the last twenty years. As, without any doubt, I am no Warren Buffett, feel free to disagree and develop you own “theory” of investing. Painful and solitary work... Success is at that price! And, based on what I did - and did not! - achieve, it shouldn’t be hard to do better... That’s my wish for you! [less ▲]

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See detailOPTIMIZATION OF A FULLY AUTOMATED ELECTROPHORETICALLY MEDIATED MICROANALYSIS SYSTEM FOR CYP1A1 ACTIVITY MONITORING
Farcas, Elena ULg; Servais, Anne-Catherine ULg; Lamalle, Caroline et al

Conference (2016, October 01)

Objective of the study Since CYP1A1, a member of cytochrome P450 superfamily, has been described to be over expressed in various types of cancer, our study was focused on the optimization of a fully ... [more ▼]

Objective of the study Since CYP1A1, a member of cytochrome P450 superfamily, has been described to be over expressed in various types of cancer, our study was focused on the optimization of a fully automated system for the monitoring of this particularly interesting enzyme. Moreover, the potentiality of this approach to screen CYP1A1 inhibitors was investigated. Materials and methods The experiments were carried out on a HP3DCE system using an on-column DAD. The EMMA procedure was performed by injecting a plug containing the co-factor(NADPH) and the substrate(7-ethoxycoumarin) between two plugs of CYP1A1 supersomes. The reaction was triggered by the application of a voltage switch. The voltage was then turned off to allow the metabolic reaction to occur. The separation of the components was then performed. Results Satisfying results were obtained using CYP1A1 at a concentration of 200 pmol/mL, while the incubation time was settled to 15 min. A DoE was performed to find the best mixing conditions. The amount of metabolite obtained was comparable to the one detected after conventional off-line metabolization. The ability of our system to monitor CYP1A1 inhibition was then proven with apigenin, a well-known CYP1A1 inhibitor. Conclusions The present study describes the development of a fully automatized in-capillary method for CYP1A1 activity monitoring and proves the potentialy of our system to be used for the screening of CYP1A1 inhibitors. The advantages of performing inline metabolization assays are mainly the miniaturization and the automatization of the process. Besides, the reagents consumption is drastically reduced due to the injection of few tens of nanoliters. [less ▲]

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See detailThe OD/OH Isotope Ratio in Comets 8P/Tuttle and C/2012 F6 (Lemmon)
Rousselot, Philippe; Jehin, Emmanuel ULg; Hutsemekers, Damien ULg et al

in Bulletin of the American Astronomical Society (2016, October 01), 48

The determination of isotopic ratios in solar system objects is an important source of information about their origin, especially for comets. Among these ratios the D/H is of particular importance because ... [more ▼]

The determination of isotopic ratios in solar system objects is an important source of information about their origin, especially for comets. Among these ratios the D/H is of particular importance because of its sensitivity to fractionation processes and physical environment, and the abundance of hydrogen in the solar system. The main molecule used to derive this ratio in comets is water. So far, apart water, only HCN has permitted to derive D/H ratio and not only upper limits.Most of the existing determinations of D/H in water molecules have been obtained by spectroscopic observations of water lines in the sub-mm or near infrared range [1,2]. So far only one measurement has been based on OD/OH emission lines radicals in the near-UV [3] and another one on the Lyman-alpha D emission [4]. In situ measurements have also been obtained in comets 1P/Halley and 67P/Churyumov-Gerasimenko using mass spectrometer [5,6,7,8].In this work we have used the OH and OD ultraviolet bands at 310 nm observed with the ESO 8-m Very Large Telescope feeding the Ultraviolet-Visual Echelle Spectrograph (UVES) for measuring the D/H ratio in comets 8P/Tuttle and C/2012 F6 (Lemmon). The OH and OD being the photodissociation products of H[SUB]2[/SUB]O and HDO such observations allow to derive D/H ratio for water molecules. This work constitutes an independant determination of the D/H ratios already published for these comets and based on observations performed in the sub-mm and near infrared range of H[SUB]2[/SUB]O and HDO lines. We present our modeling, data analysis and numerical values obtained for this ratio.[1] D. Bockelée-Morvan et al., 2015, SSR 197, 47-83 [2] N. Biver et al., 2016, A&A 589, id A78, 11p [3] D. Hutsemékers et al., 2008, A&A 490, L31 [4] H.A. Weaver et al., 2008, LPI Contributions 1405, 8216 [5] H. Balsiger, K. Altwegg, J. Geiss, 1995, JGR 100, 5827 [6] P. Eberhardt et al., 1995, A&A 302, 301 [7] R.H. Brown et al., 2012, PSS 60, 166 [8] K. Alwegg et al., 2015, Science 347, article id. 1261952 [less ▲]

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See detailSurvey for Ortho-to-Para Abundance Ratios (OPRs) of NH2 in Comets: Revisit to the Meaning of OPRs of Cometary Volatiles
Kawakita, Hideyo; Shinnaka, Yoshiharu; Jehin, Emmanuel ULg et al

in Bulletin of the American Astronomical Society (2016, October 01), 48

Since molecules having identical protons can be classified into nuclear-spin isomers (e.g., ortho-H[SUB]2[/SUB]O and para-H[SUB]2[/SUB]O for water) and their inter-conversions by radiative and non ... [more ▼]

Since molecules having identical protons can be classified into nuclear-spin isomers (e.g., ortho-H[SUB]2[/SUB]O and para-H[SUB]2[/SUB]O for water) and their inter-conversions by radiative and non-destructive collisional processes are believed to be very slow, the ortho-to-para abundance ratios (OPRs) of cometary volatiles such as H[SUB]2[/SUB]O, NH[SUB]3[/SUB] and CH[SUB]4[/SUB] in coma have been considered as primordial characters of cometary molecules [1]. Those ratios are usually interpreted as nuclear-spin temperatures although the real meaning of OPRs is in strong debate. Recent progress in laboratory studies about nuclear-spin conversion in gas- and solid-phases [2,3] revealed short-time nuclear-spin conversions for water, and we have to reconsider the interpretation for observed OPRs of cometary volatiles. We have already performed the survey for OPRs of NH[SUB]2[/SUB] in more than 20 comets by large aperture telescopes with high-resolution spectrographs (UVES/VLT, HDS/Subaru, etc.) in the optical wavelength region [4]. The observed OPRs of ammonia estimated from OPRs of NH[SUB]2[/SUB], cluster around ~1.1 (cf. 1.0 as a high-temperature limit), indicative of ~30 K as nuclear-spin temperatures. We present our latest results for OPRs of cometary NH[SUB]2[/SUB] and discuss about the real meaning of OPRs of cometary ammonia, in relation to OPRs of water in cometary coma. Chemical processes in the inner coma may play an important role to achieve un-equilibrated OPRs of cometary volatiles in coma.This work was financially supported by MEXT Supported Program for the Strategic Research Foundation at Private Universities, 2014–2018 (No. S1411028) (HK) and by Graint-in-Aid for JSPS Fellows, 15J10864 (YS).References:[1] Mumma & Charnley, 2011, Annu. Rev. Astro. Astrophys. 49, 471.[2] Hama & Watanabe, 2013, Chem. Rev. 113, 8783.[3] Hama et al., 2008, Science 351, 6268.[4] Shinnaka et al., 2011, ApJ 729, 81. [less ▲]

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See detailTracing back the evolution of the candidate LBV HD 168625
Mahy, Laurent ULg; Hutsemekers, Damien ULg; Royer, P. et al

in Astronomy and Astrophysics (2016), 594

Context. The luminous blue variable phase is a crucial transitory phase that is not clearly understood in the massive star evolution. <BR /> Aims: We have obtained far-infrared Herschel/PACS imaging and ... [more ▼]

Context. The luminous blue variable phase is a crucial transitory phase that is not clearly understood in the massive star evolution. <BR /> Aims: We have obtained far-infrared Herschel/PACS imaging and spectroscopic observations of the nebula surrounding the candidate LBV HD 168625. By combining these data with optical spectra of the central star, we want to constrain the abundances in the nebula and in the star and compare them to trace back the evolution of this object. <BR /> Methods: We use the CMFGEN atmosphere code to determine the fundamental parameters and the CNO abundances of the central star whilst the abundances of the nebula are derived from the emission lines present in the Herschel/PACS spectrum. <BR /> Results: The far-infrared images show a nebula composed of an elliptical ring/torus of ejecta with a ESE-WNW axis and of a second perpendicular bipolar structure composed of empty caps/rings. We detect equatorial shells composed of dust and ionized material with different sizes when observed at different wavelengths, and bipolar caps more of less separated from the central star in Hα and mid-IR images. This complex global structure seems to show two different inclinations: ~40° for the equatorial torus and ~ 60° for the bipolar ejections. From the Herschel/PACS spectrum, we determine nebular abundances of N/H = 4.1 ± 0.8 × 10[SUP]-4[/SUP] and , as well as a mass of ionized gas of 0.17 ± 0.04 M[SUB]⊙[/SUB] and a neutral hydrogen mass of about 1.0 ± 0.3 M[SUB]⊙[/SUB] which dominates. Analysis of the central star reveals T[SUB]eff[/SUB] = 14 000 ± 2000 K, log g = 1.74 ± 0.05 and log (L/L[SUB]⊙[/SUB]) = 5.58 ± 0.11. We derive stellar CNO abundances of about N/H = 5.0 ± 1.5 × 10[SUP]-4[/SUP], C/H = 1.4 ± 0.5 × 10[SUP]-4[/SUP] and O/H = 3.5 ± 1.0 × 10[SUP]-4[/SUP], not significantly different from nebular abundances. All these measurements taken together are compatible with the evolutionary tracks of a star with an initial mass between 28 and 33 M[SUB]⊙[/SUB] and with a critical rotational rate between 0.3 and 0.4 that has lost its material during or just after the blue supergiant phase. Based in part on observations taken by Herschel satellite. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.Based in part on observations collected at the European Southern Observatory, in Chile. [less ▲]

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See detailApsidal motion in the massive binary HD 152218
Rauw, Grégor ULg; Rosu, S.; Noels-Grötsch, Arlette ULg et al

in Astronomy and Astrophysics (2016), 594(A33), 1-12

Massive binary systems are important laboratories in which to probe the properties of massive stars and stellar physics in general. In this context, we analysed optical spectroscopy and photometry of the ... [more ▼]

Massive binary systems are important laboratories in which to probe the properties of massive stars and stellar physics in general. In this context, we analysed optical spectroscopy and photometry of the eccentric short-period early-type binary HD 152218 in the young open cluster NGC 6231. We reconstructed the spectra of the individual stars using a disentangling code. The individual spectra were then compared with synthetic spectra obtained with the CMFGEN model atmosphere code. We furthermore analysed the light curve of the binary and used it to constrain the orbital inclination and to derive absolute masses of (19.8 ± 1.5) and (15.0 ± 1.1) M⊙. Combining radial velocity measurements from over 60 yr, we show that the system displays apsidal motion at a rate of (2.04 ± .24)°/yr. Solving the Clairaut-Radau equation, we used stellar evolution models, obtained with the CLES code, to compute the internal structure constants and to evaluate the theoretically predicted rate of apsidal motion as a function of stellar age and primary mass. In this way, we determine an age of 5.8 ± 0.6 Myr for HD 152218, which is towards the higher end of, but compatible with, the range of ages of the massive star population of NGC 6231 as determined from isochrone fitting. [less ▲]

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See detailArchitectures du XX ème siècle à Liège
Frankignoulle, Pierre ULg

Diverse speeche and writing (2016)

Visite organisée le 1/10/2016 à l'intention de DOCOMOMO Allemagne

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See detailTowards a large scale aqueous sol-gel synthesis of doped TiO2: Study of various metallic dopings for the photocatalytic degradation of p-nitrophenol
Mahy, Julien ULg; Lambert, Stéphanie ULg; Léonard, Géraldine ULg et al

in Journal of Photochemistry and Photobiology A : Chemistry (2016), 329

In this paper, an easy aqueous sol-gel synthesis developed previously by Mahy et al. [J. Sol-Gel Sci. Technol. (2016)] is adapted to produce highly active TiO2 catalysts doped with Fe3+, Ag+, Cu2+, Zn2 ... [more ▼]

In this paper, an easy aqueous sol-gel synthesis developed previously by Mahy et al. [J. Sol-Gel Sci. Technol. (2016)] is adapted to produce highly active TiO2 catalysts doped with Fe3+, Ag+, Cu2+, Zn2+, Cr3+, Al3+, Mn2+, and Co2+ ions and Pt metallic nanoparticles. Samples are characterized by inductively coupled plasma–atomic emission spectroscopy (ICP-AES), X-ray diffraction (XRD), Mössbauer spectroscopy, transmission electron microscopy (TEM), nitrogen adsorption–desorption measurements and diffuse reflectance spectroscopy measurements. Results show that the samples are composed of anatase-brookite TiO2 nanoparticles with a spherical shape and mean diameter of around 5-8 nm and a surface area of between about 150 - 250 m2 g-1. In each doped sample, the dopant is present in the form added during the synthesis, given that the sample has not undergone any particular treatment. Photoactivity tests show improvement in catalyst activity for Fe3+, Ag+, Cu2+, Zn2+, and Al3+ ion and Pt metallic nanoparticle dopants, while a decrease of activity is obtained for Cr3+, Mn2+ and Co2+ ion dopants. For some dopants, the activity of TiO2 doped with metallic ions and synthesized from the aqueous sol-gel process is equal or superior to the activity of the commercial photocatalyst Degussa P25. Some mechanisms are proposed to explain these modifications of activity with doping. Furthermore, cost comparison at laboratory scale showed that Zn and Cu nitrate salt dopings are clearly less expensive for a halogen light (UV/visible) or low energy light enhanced catalyst and may be considered for industrial applications. Using this method, a large scale Zn-doped TiO2 photocatalyst is synthesized with properties homologous to the lab-scale product. Results show that the aqueous sol-gel synthesis developed previously can be easily adapted for doping in order to produce an up-scalable synthesis. [less ▲]

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See detailA large strain hyperelastic viscoelastic-viscoplastic-damage constitutive model based on a multi-mechanism non-local damage continuum for amorphous glassy polymers
Nguyen, Van Dung ULg; Lani, Frédéric; Pardoen, Thomas et al

in International Journal of Solids and Structures (2016), 96

A large strain hyperelastic phenomenological constitutive model is proposed to model the highly nonlinear, rate-dependent mechanical behavior of amorphous glassy polymers under isothermal conditions. A ... [more ▼]

A large strain hyperelastic phenomenological constitutive model is proposed to model the highly nonlinear, rate-dependent mechanical behavior of amorphous glassy polymers under isothermal conditions. A corotational formulation is used through the total Lagrange formalism. At small strains, the viscoelastic behavior is captured using the generalized Maxwell model. At large strains beyond a viscoelastic limit characterized by a pressure-sensitive yield function, which is extended from the Drucker-Prager one, a viscoplastic region follows. The viscoplastic flow is governed by a non-associated Perzyna-type flow rule incorporating this pressure-sensitive yield function and a quadratic flow potential in order to capture the volumetric deformation during the plastic process. The stress reduction phenomena arising from the post-peak plateau and during the failure stage are considered in the context of a continuum damage mechanics approach. The post-peak softening is modeled by an internal scalar, so-called softening variable, whose evolution is governed by a saturation law. When the softening variable is saturated, the rehardening stage is naturally obtained since the isotropic and kinematic hardening phenomena are still developing. Beyond the onset of failure characterized by a pressure-sensitive failure criterion, the damage process leading to the total failure is controlled by a second internal scalar, so-called failure variable. The final failure occurs when the failure variable reaches its critical value. To avoid the loss of solution uniqueness when dealing with the continuum damage mechanics formalism, a non-local implicit gradient formulation is used for both the softening and failure variables, leading to a multi-mechanism non-local damage continuum. The pressure sensitivity considered in both the yield and failure conditions allows for the distinction under compression and tension loading conditions. It is shown through experimental comparisons that the proposed constitutive model has the ability to capture the complex behavior of amorphous glassy polymers, including their failure. [less ▲]

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See detailAdvancing the integration of corporate sustainability measurement, management and reporting
Maas, Karen; Schaltegger, Stefan; Crutzen, Nathalie ULg

in Journal of Cleaner Production (2016), 133

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