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See detailQualité diagnostique et efficacité d'un dispositif en ligne entraînant à la résolution de problèmes complexes en physique
Marique, Pierre-Xavier ULg; Jacquet, Maud ULg; Georges, François ULg et al

in Actes du colloque ADMEE-Europe - Actes du 27e colloque qui s'est tenu en janvier 2015 à Liège (in press)

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See detailFrémok: Comics Out-of-Bounds
Dejasse, Erwin ULg

in World Literature Today (in press)

Article about that analize the history, background and publishing policity of French-Belgian publisher Frémok

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See detailMetal binding to the N-terminal cytoplasmic domain of the PIB ATPase HMA4 is required for metal transport in Arabidopsis.
Laurent, Clémentine ULg; Lekeux, Gilles ULg; Ukuwela, Ashwinie A et al

in Plant Molecular Biology (in press)

PIB ATPases are metal cation pumps that transport metals across membranes. These proteins possess N- and C-terminal cytoplasmic extensions that contain Cys- and His-rich high affinity metal binding ... [more ▼]

PIB ATPases are metal cation pumps that transport metals across membranes. These proteins possess N- and C-terminal cytoplasmic extensions that contain Cys- and His-rich high affinity metal binding domains, which may be involved in metal sensing, metal ion selectivity and/or in regulation of the pump activity. The PIB ATPase HMA4 (Heavy Metal ATPase 4) plays a central role in metal homeostasis in Arabidopsis thaliana and has a key function in zinc and cadmium hypertolerance and hyperaccumulation in the extremophile plant species Arabidopsis halleri. Here, we examined the function and structure of the N-terminal cytoplasmic metal-binding domain of HMA4. We mutagenized a conserved CCTSE metal-binding motif in the domain and assessed the impact of the mutations on protein function and localization in planta, on metal-binding properties in vitro and on protein structure by Nuclear Magnetic Resonance spectroscopy. The two Cys residues of the motif are essential for the function, but not for localization, of HMA4 in planta, whereas the Glu residue is important but not essential. These residues also determine zinc coordination and affinity. Zinc binding to the N-terminal domain is thus crucial for HMA4 protein function, whereas it is not required to maintain the protein structure. Altogether, combining in vivo and in vitro approaches in our study provides insights towards the molecular understanding of metal transport and specificity of metal P-type ATPases. [less ▲]

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See detailSolubility and speciation of ketoprofen and aspirin in supercritical CO2 by infrared spectroscopy
Champeau, Mathilde; Thomassin, Jean-Michel ULg; Jérôme, Christine ULg et al

in Journal of Chemical & Engineering Data (in press)

The solubility of ketoprofen and aspirin in subcritical and supercritical CO2 was measured using FTIR absorption spectroscopy in the large range of temperature of 298.2−353.2 K and pressure of 5−35 MPa ... [more ▼]

The solubility of ketoprofen and aspirin in subcritical and supercritical CO2 was measured using FTIR absorption spectroscopy in the large range of temperature of 298.2−353.2 K and pressure of 5−35 MPa. The evolution of the solubility of both active pharmaceutical ingredients (APIs) was fitted using the Chrastil’s equation. In addition, the speciation of both APIs in monomeric and dimeric forms was explored by analyzing the characteristic carbonyl stretching vibrations of the carboxylic acid functions assigned to the dimers and monomers, respectively. Moreover, the evolution of the dimerization constant K of the two drugs as a function of the temperature and the pressure of scCO2 has been reported. [less ▲]

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See detailComputerized adaptive testing with R: Recent updates of the package catR
Magis, David ULg; Barrada, Juan Ramon

in Journal of Statistical Software (in press)

The purpose of this paper is to list the recent updates of the R package catR. This package allows for generating response patterns under a computerized adaptive testing (CAT) framework with underlying ... [more ▼]

The purpose of this paper is to list the recent updates of the R package catR. This package allows for generating response patterns under a computerized adaptive testing (CAT) framework with underlying item response theory (IRT) models. Among the most important updates, well-known polytomous IRT models are now supported by catR; several item selection rules have been added; and it is now possible to perform post-hoc simulations. Some functions were also rewritten or withdrawn to improve the usefulness and performances of the package. [less ▲]

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See detailStakeholders’ perceptions, attitudes and practices towards risk prevention in the food chain
Lupo, C; Wilmart, O; Van Huffel, X et al

in Food Control (in press)

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See detailConfusion de codes graphiques dans les papyrus latins
Rochette, Bruno ULg; Nocchi Macedo, Gabriel

in Cappasso, Mario (Ed.) Mélanges à la mémoire de Paolo Radiciotti (in press)

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See detailGünter Grass and his translators: from a collaborative dynamic to a controlling apparatus?
Letawe, Céline ULg

in Cordingley, Anthony; Frigau Manning, Céline (Eds.) Collaborative Translation: from the Renaissance to the Digital Age (in press)

Entre 1978 et 2013, Günter Grass a réuni ses traducteurs autour de chacun de ses romans pour qu’ils puissent discuter avec lui et entre eux des problèmes de traduction. L’expérience fascine, mais elle ... [more ▼]

Entre 1978 et 2013, Günter Grass a réuni ses traducteurs autour de chacun de ses romans pour qu’ils puissent discuter avec lui et entre eux des problèmes de traduction. L’expérience fascine, mais elle pose aussi de nombreuses questions. A partir de correspondances, de protocoles et d’enregistrements conservés aux archives et de comparaisons entre l’original de Günter Grass et plusieurs traductions, il a été possible non seulement de retracer le processus, mais aussi d’en évaluer le résultat, pour ainsi mieux cerner les enjeux multiples liés à ces séminaires de traducteurs. A côté de leur finalité avouée (l’amélioration de la qualité des traductions), ils participent à un système de contrôle plus large et contribuent à légitimer les traductions et à en faire la publicité, mais ils ont aussi pour effet de créer une dynamique entre les traducteurs et de leur donner davantage de visibilité. [less ▲]

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See detailLe socio-écosystème : dynamiques institutionnelles et interdisciplinarité.
Denayer, Dorothée ULg; Couvet, Denis

in Interdisciplinarités entre Natures et Sociétés. (in press)

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See detailLes animaux comme révélateurs et passeurs de frontières.
Roué, Marie; Manceron, Vanessa; Denayer, Dorothée ULg et al

in Interdisciplinarités entre Natures et Sociétés. (in press)

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See detailSur les pas des hommes qui ont vu l’ours. La conservation de la faune sauvage, un travail réel.
Denayer, Dorothée ULg; Mougenot, Catherine ULg; Collard, Damien

in Natures Sciences Sociétés (in press)

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See detailStructural analysis of monometallic ruthenium–arene complexes using ion mobility mass spectrometry, collision-induced dissociation, and density functional theory
Cserwinska, Izabella; Far, Johann ULg; Kune, Christopher ULg et al

in Journal of the Chemical Society. Dalton Transactions (in press)

Ion mobility mass spectrometry (IM-MS) and collision-induced dissociation (CID) techniques were used to investigate the influence of the phosphine ligand on the physicochemical properties of [RuCl2(p ... [more ▼]

Ion mobility mass spectrometry (IM-MS) and collision-induced dissociation (CID) techniques were used to investigate the influence of the phosphine ligand on the physicochemical properties of [RuCl2(p-cymene)(PCy3)] (1), [RuCl2(p-cymene)-(PPh3)] (2), and [RuCl2(p-cymene)(PTA)] (3) in the gas phase (PTA is 1,3,5-triaza-7-phosphaadamantane). Electrospray ionization of complexes 1 and 2 led to the corresponding [RuCl(p-cymene)(PR3)]+ ions via the dissociation of a chlorido ligand, whereas RAPTA-C (3) afforded two molecular ions by in-source oxidation ([RuIIICl2(p-cymene)(PTA)]+) or protonation ([RuCl2(p-cymene)(PTA+H)]+). Control experiments showed that the balance between these two ionization paths was strongly influenced by the nature of the solvent used for infusion. Collision cross sections (CCSs) of the four molecular ions accurately reflected the variations of steric bulk inferred from the Tolman steric parameters (θ) of the phosphine ligands. Moreover, DFT calculations combined with a model based on the kinetic theory of gases (the trajectory method of the IMoS software) afforded reliable CCS predictions. The almost two times higher dipole moment of [RuCl2(p-cymene)-(PTA+H)]+ (μ = 13.75 D) compared to [RuIIICl2(p-cymene)(PTA)]+ (μ = 7.18 D) was held responsible for increased ion-induced dipole interactions with a polarizable drift gas such as N2. Further experiments with He and CO2 confirmed that increasing the polarizability of the buffer gas improved the separation between the two molecular ions derived from complex 3. The fragmentation patterns of complexes 1–3 were determined by CID. The sequence of collision voltages at which 50% of a precursor ion dissociates (V50) recorded for the molecular ions derived from compounds 1–3 was in good agreement with simple electronic considerations based on the donor strength of the phosphine ligand. Thus, the CCS and V50 parameters used to determine the shape and stability of ionic species in the gas phase are complementary to the Tolman steric and electronic parameters (θ and TEP) commonly used by organometallic chemists in condensed phases. [less ▲]

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See detailNi utopie ni solidarisme. Une refonte matérialiste et critique de l'association est-elle possible ?
Frère, Bruno ULg

in Delaunay, Catarina (Ed.) Democracia, promessas, utopias e (des)ilusoes : dilemas e disputas nas arenas publicas (2017)

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See detailHow to account for new forms of resistance to domination: An argument for a materialist renewal in European social theory
Frère, Bruno ULg; Tulle, Emmanuelle

E-print/Working paper (2017)

Many significant intellectual developments have taken place in 20th century European social theories. Notably the first Frankfurt School and Bourdieu’s work have successfully shown how workers, social ... [more ▼]

Many significant intellectual developments have taken place in 20th century European social theories. Notably the first Frankfurt School and Bourdieu’s work have successfully shown how workers, social actors, etc. are alienated or dominated by capitalist social structures. But according to Habermas, neither perspective successfully allows for the possibility that people could contribute to their own emancipation. The emergence of new forms of social resistance to domination such as those embodied by the Indignados, Anonymous, Femen, the practitioners of alternative economy, movements of unemployed people or illegals compels us to envisage the possibility for emancipation, but how? In this paper we explore opportunities for accounting for this by considering the work of a range of other European social theorists, more specifically Boltanski whose critical intent is embodied in his pragmatic sociology, and evident in his coining and use of the concept of the world. In addition we will consider Latour’s own pragmatic stance as we believe that despite his disinterest in new social movements, his work, informed by pure immanence, might offer potential solutions. But we would argue that even in these innovations there is either a persistent tendency to imagine emancipation primarily as a return to some ideal state or a lack of critical engagement with alienation. In response, we propose a materialist renewal, which will lead us to ponder on the political role of sociologists. [less ▲]

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See detailBack to materialism Reflections on Marx’s labour, praxis, cooperative and libertarian socialism in the 19th century
Frère, Bruno ULg

E-print/Working paper (2017)

From Marx to Althusser, the materialist approach has tended to assume that individuals (that is, workers, proletarians and other social actors), unconsciously reproduce the social structures of capitalism ... [more ▼]

From Marx to Althusser, the materialist approach has tended to assume that individuals (that is, workers, proletarians and other social actors), unconsciously reproduce the social structures of capitalism which alienate them. It is assumed that individuals accept the conditions forced upon them and no longer seek to rebel against a world which substantially impoverishes their labour, their spirit and their creativity. In this paper, I will try to show that by dint of favouring almost exclusively Marx's concept of alienation, there is a considerable risk that materialist thought will adopt only a negative path. Whilst I acknowledge Marx’s significance to materialism, I wish to argue that his stance should be combined with that of the anarchist and libertarian French thinker Proudhon. Proudhon has succeeded in presenting a conception of the worker as more than just alienated. Workers can also cooperate and experience a reciprocity seemingly at odds with the character of capitalism. Under Proudhon’s influence materialism takes a positive turn, enabling us to avoid falling into the utopianism that the theory of social economy employs to critique capitalism – a utopianism that renders its critique even less effective than that of Marx. [less ▲]

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See detailExplain Your Thesis in Three Minutes
Kreusch, Marie ULg

Article for general public (2016)

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See detailRapport sur l'Habilitation de Catherine GUYON : Par la roue de sainte Catherine. Dévots, pèlerins et pèlerinage à sainte Catherine d’Alexandrie (VIIIe- début du XVIe siècle)
George, Philippe ULg

Report (2016)

Madame Guyon a étudié le culte de sainte Catherine d'Alexandrie et son développement tous azimuts.

Detailed reference viewed: 17 (1 ULg)