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See detailPhoton correlation spectroscopy for molecular self-assembly investigations
Razafindralambo, Hary ULg

Conference (2013, April 11)

The molecular self-assembly performance is among the most important functionalities of amphiphilic compounds in colloidal system areas. This aptitude is required in numerous applications, depending on ... [more ▼]

The molecular self-assembly performance is among the most important functionalities of amphiphilic compounds in colloidal system areas. This aptitude is required in numerous applications, depending on solubilization, hydrotropy, rheology, separation, loading and delivery, encountered in biological and industrial processes. The main physicochemical parameter predicting the capacity of amphiphiles to self-assembly in bulk liquid, aqueous (normal micelles) or non-aqueous phase (reverse micelles), is the pair critical micelle concentration (CMC) and temperature (CMT). A variety of methods based on surface tension, spectral changes, and electrical conductivity are commonly used for determining the value of CMC. The choice usually depends on the ionic or non-ionic nature of the amphiphilic compounds. In this communication, a standard Photon Correlation Spectroscopy (PCS), also known Light Scattering-based technique for CMC determination will be theoretically and practically described in details. Its particular interest for measuring the performance of non-ionic and very high hydrophobic tail, mono or disubstituted carbohydrate-based compounds, from C16 alkyl chain, will be demonstrated. Such a method is advantageous regarding the time, amount, and resolution required, but also for additional information on micelle size, aggregate number, and stability it may provide, compared to surface tension and electrical conductivity-based measurements. [less ▲]

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See detailThe future sea-level rise contribution of Greenland's glaciers and ice caps
Machguth, H.; Rastner, P.; Bolch, T. et al

in Environmental Research Letters (2013), 8(025005), 14

We calculate the future sea-level rise contribution from the surface mass balance of all of Greenland's glaciers and ice caps (GICs, ~90 000 km2) using a simplified energy balance model which is driven by ... [more ▼]

We calculate the future sea-level rise contribution from the surface mass balance of all of Greenland's glaciers and ice caps (GICs, ~90 000 km2) using a simplified energy balance model which is driven by three future climate scenarios from the regional climate models HIRHAM5, RACMO2 and MAR. Glacier extent and surface elevation are modified during the mass balance model runs according to a glacier retreat parameterization. Mass balance and glacier surface change are both calculated on a 250 m resolution digital elevation model yielding a high level of detail and ensuring that important feedback mechanisms are considered. The mass loss of all GICs by 2098 is calculated to be 2016 ± 129 Gt (HIRHAM5 forcing), 2584 ± 109 Gt (RACMO2) and 3907 ± 108 Gt (MAR). This corresponds to a total contribution to sea-level rise of 5.8 ± 0.4, 7.4 ± 0.3 and 11.2 ± 0.3 mm, respectively. Sensitivity experiments suggest that mass loss could be higher by 20–30% if a strong lowering of the surface albedo were to take place in the future. It is shown that the sea-level rise contribution from the north-easterly regions of Greenland is reduced by increasing precipitation while mass loss in the southern half of Greenland is dominated by steadily decreasing summer mass balances. In addition we observe glaciers in the north-eastern part of Greenland changing their characteristics towards greater activity and mass turnover. [less ▲]

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See detail- Fundamental property and functional aptitude relationships in emulsion and foam applications of amphiphilic compounds
Razafindralambo, Hary ULg

Conference (2013, April 11)

Amphiphilic compounds are issued of a combination of two opposite entities, covalently assemblied within a single structure. By the diversity of the origin, class, number of monomer and substitute, size ... [more ▼]

Amphiphilic compounds are issued of a combination of two opposite entities, covalently assemblied within a single structure. By the diversity of the origin, class, number of monomer and substitute, size, linker or spacer, stereochemistry of the molecular entities, their chemical structure may be very different but also close each other. However, they may fulfill the same role in reducing surface and interfacial free energy in dynamic or static ways, ensuring especially the formation of dispersed systems like emulsion and foam. If the relationships between the structural variable and fundamental properties are strictly chemical residue dependent, those between fundamental and functional aptitudes are not necessarily. In this case, general and universal rules may exist, whatever the kind of amphiphilic compounds. In order to achieve a rational design for any expected functionality, we attempt to find out some predictive and conception rules from a lot of screening data of fundamental and functional properties. In this communication, some correlations between fundamental data related to surface and interfacial properties, measured by molecule adsorption or spreading under dynamic or static mode, in compression or dilation of adsorbed or spread film, and emulsifying and foaming performances of various bio-based surfactants will be presented. [less ▲]

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See detailChanges of soil structure and earthworm community under different agricultural management
Lemtiri, Aboulkacem ULg; Alabi, Taofic; Francis, Frédéric ULg et al

Conference (2013, April 11)

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See detailChanges of soil structure and earthworm community under different agricultural management
Lemtiri, Aboulkacem ULg

Conference (2013, April 11)

The living soil is represented by soil biota that interacts with aboveground biota and with the abiotic constructs of soil, represented as soil structure, organic matter, and nutrients. Maintenance of ... [more ▼]

The living soil is represented by soil biota that interacts with aboveground biota and with the abiotic constructs of soil, represented as soil structure, organic matter, and nutrients. Maintenance of soil organic matter through integrated soil fertility management is necessary for soil quality and agricultural productivity. Earthworms are key actors in soil structure formation through the formation of casts and the incorporation of soil organic matter in the soil. Little is known about the interactive effects of various tillage and crop residue management practices on earthworm populations and physical properties of soil. To investigate the impacts of two tillage management systems and two cropping systems on earthworms populations and soil stucture dynamics, we carried out a three years study of the earthworm communities in experimental site having for experimental treatments : two tillage management systems and two cropping systems. In consequence, the aims of this experimentation were to determine the effects of the tillage systems on the abundance, biomass and diversity of earthworms and examine temporal variation of soil structure and dynamics of nutrient elements. The first results reveal that tillage management had a significant affect on earthworm abundance and biomass. However, crop residue management did not affect abundance, biomass and diversity of earthworms. The analyze of nutrient element dynamics showed that some nutrient elements (phosphore,…) decrease with tillage practice. This study has shown that soil structure was variable within the fields and between them, although the successive cultivation operations and the equipement used for wheat cropping were identical in the study site. [less ▲]

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See detailRelationship between the Synthesis of Prussian Blue Pigments, Their Color, Physical Properties, and Their Behavior in Paint Layers
Samain, Louise ULg; Grandjean, Fernande ULg; Long, Gary J. et al

in Journal of Physical Chemistry A (2013), 117(19), 96939712

Prussian blue pigments, highly insoluble mixed-valence iron(III) hexacyanoferrate(II) complexes of typical stoichiometry Fe4III[FeII(CN)6]3·xH2O or KFeIII[FeII(CN)6]·xH2O, have been used as pigments in ... [more ▼]

Prussian blue pigments, highly insoluble mixed-valence iron(III) hexacyanoferrate(II) complexes of typical stoichiometry Fe4III[FeII(CN)6]3·xH2O or KFeIII[FeII(CN)6]·xH2O, have been used as pigments in oil paintings and watercolors for 300 years. For poorly understood reasons, these pigments often fade with time. Although the preparation methods have been recognized since the mid-eighteenth century as a contributory factor in the fading of the pigment, the spectral and physical properties of Prussian blue that vary with the type of synthesis were not precisely identified. Several Prussian blue pigments have been prepared by different methods and characterized by thermogravimetric analyses, high-energy powder X-ray diffraction, atomic absorption and flame emission, UV–visible, iron-57 Mössbauer, iron K-edge X-ray absorption, and Raman spectroscopy. The type of synthesis influences the hue, tinting strength, and hiding power properties of the Prussian blue pigments. Two major features appear to be strongly dependent on the preparative methods, the particle size and the local disorder. Both a nitrogen atmosphere and an intermediate aging step of the Berlin white, Fe2II[FeII(CN)6], during the synthesis are required to obtain a highly colored pigment through the optimization of particle size, minimization in the perturbations to the FeII–CN–FeIII intervalence electron transfer pathway, and the minimization of disordered vacancies. The potassium containing Prussian blue structure has been revisited. It can be described with the Pm3m space group, where approximately one-quarter of the [FeII(CN)6]4– sites are vacant and where the potassium cation is located at a zeolitic-like position inside the lattice cavities. The degree of ordering of the [FeII(CN)6]4– vacancies in all Prussian blues was quantified using atomic pair distribution analysis, an ordering that is consistent with the iron K-edge X-ray absorption spectra. The presence of strain in the crystals is observed by both powder X-ray diffraction and Mössbauer spectroscopy. The structural similarity between the alkali-free, improperly referred to as “insoluble”, and the alkali containing, “soluble”, Prussian blues may explain why the two varieties are almost undistinguishable by spectroscopic techniques. [less ▲]

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See detailCooking and eating in the name of Allah. Food practices among Moroccan women in Milan.
Mescoli, Elsa ULg

Scientific conference (2013, April 10)

A large body of literature currently exists regarding the relationship between food and Islamic religion in contemporary world. Works mostly address dietary prescriptions, often using a comparative ... [more ▼]

A large body of literature currently exists regarding the relationship between food and Islamic religion in contemporary world. Works mostly address dietary prescriptions, often using a comparative approach, and the way in which people negotiate with them in the global era. Besides this, a little prominence is given to the role of Islamic religion into the very same culinary practices exerted daily. Based on ethnographic experience, my article aims at highlighting this role, exploring the everyday lives of Moroccan Muslim women living in Milan hinterland. The assumption of my ongoing doctoral research in anthropology, from which this paper stems, consists of the adherence to a praxeological approach to subjectivation (Warnier 2001): it focuses on the construction of human selves through material culture. As a matter of fact, observing Moroccan women living in context of migration, I studied how they shape themselves trough daily micro-practices (De Certeau 1980). In particular, while cooking these women revealed me, inter alia, how complex is the interaction between food and Islamic religion; interaction which cannot be reduced to dietary prescriptions since it also involves the ways in which dished are prepared, served and consumed. In my paper I will try to explain such complexity through ethnographic examples. Furthermore, I will attempt to show how, in the context under analysis, the public performing of food practices and related objects is functional to the declaration of a shared religious identity in “acceptable” (since artistic) terms. Visual materials (photos and videos) will support such attempts. De Certeau, Michel. L’invention du quotidien. Tome I. Arts de faire. Gallimard, Paris 1980 Warnier Jean-Pierre. A praxeological approach to subjectivation in a material world, in Journal of Material Culture, Vol. 6(1): 5–24, 2001 [less ▲]

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See detailOccupational activity and cognitive reserve: implications in terms of prevention of cognitive aging and Alzheimer’s disease
Adam, Stéphane ULg; Bonsang, Eric; Grotz, Catherine ULg et al

in Clinical Interventions in Aging (2013), 8

This paper investigates the relationship between the concept of activity (including both professional and nonprofessional) and cognitive functioning among older European individuals. In this research, we ... [more ▼]

This paper investigates the relationship between the concept of activity (including both professional and nonprofessional) and cognitive functioning among older European individuals. In this research, we used data collected during the first wave of SHARE (Survey on Health, Ageing and Retirement in Europe), and a measurement approach known as stochastic frontier analysis, derived from the economic literature. SHARE includes a large population (n . 25,000) geographically distributed across Europe, and analyzes several dimensions simultaneously, including physical and mental health activity. The main advantages of stochastic frontier analysis are that it allows estimation of parametric function relating cognitive scores and driving factors at the boundary and disentangles frontier noise and distance to frontier components, as well as testing the effect of potential factors on these distances simultaneously. The analysis reveals that all activities are positively related to cognitive functioning in elderly people. Our results are discussed in terms of prevention of cognitive aging and Alzheimer’s disease, and regarding the potential impact that some retirement programs might have on cognitive functioning in individuals across Europe. [less ▲]

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See detailValidation of the Structural-Thermal Model of the Small Earth Observation Satellite Flying Laptop
Steinmetz, Fabian; Lengowski, Michael; Winter, Daniel et al

in Selected Proceedings of the 9th IAA International Symposium on Small Satellites for Earth Observation (2013, April 10)

Thorough thermal design and testing is compulsory for every satellite mission. A well-known thermal behavior of the entire satellite system is therefore indispensable and needs to be verified during the ... [more ▼]

Thorough thermal design and testing is compulsory for every satellite mission. A well-known thermal behavior of the entire satellite system is therefore indispensable and needs to be verified during the spacecraft development. A Structural-Thermal-Model (STM) was constructed for the Flying Laptop, a satellite currently being developed at the Institute of Space Systems (IRS) of the University of Stuttgart, which enables the validation of mechanical and thermal simulations for the satellite’s Flight-Model. The STM was vibration and thermal-vacuum tested at the Centre Spatial Liège (CSL). This paper will de-scribe the design and construction of the STM as well as the facilities and test equipment used for the tests. Conclusions will be drawn from the actual test results. [less ▲]

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See detailDynamic Stall and Stall Flutter Simulations for a 2D Airfoil Using Viscous-Inviscid Coupling
Rothkegel Ide, José Ignacio ULg; Dimitriadis, Grigorios ULg

in Proceedings of the 54th AIAA/ASME/ASCE/AHS/ASC Structures, Structural Dynamics and Materials Conference (2013, April 10)

An interactive boundary layer model has been developed and coupled with a pitch plunge airfoil in 2d in order to solve the unsteady flow around the airfoil when undergoing light dynamic stall. The ... [more ▼]

An interactive boundary layer model has been developed and coupled with a pitch plunge airfoil in 2d in order to solve the unsteady flow around the airfoil when undergoing light dynamic stall. The inviscid problem is solved by means of a panel method, by the discretization of the airfoil into vortex panels. The boundary layer is solved in a mixed manner, starting the solution in a direct way by imposing the external velocity and continuing it in an inverse way by imposing the displacement thickness. The solution of the boundary layer equations is carried out using a finite volume scheme. Viscous-inviscid coupling is preformed through the imposition of a permeation velocity on the skin panels of the airfoil and the addition of a free wake at each separation point. [less ▲]

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See detailParis seen by a Black Man. Narrative Point of View and Ethnic Identity in Raoul Gineste’s Le Nègre de Paris (1903)
Stienon, Valérie ULg

Scientific conference (2013, April 10)

Although he does not seem to have had any apparent connection with the Black community, Raoul Gineste (a.k.a. Adolphe Augier) might have chosen the topic of the negro man both as a literary frame for a ... [more ▼]

Although he does not seem to have had any apparent connection with the Black community, Raoul Gineste (a.k.a. Adolphe Augier) might have chosen the topic of the negro man both as a literary frame for a kind of novel of manners and as a fictional support for a true social reflection. [less ▲]

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See detailValidation of the Structural-Thermal-Model of the Small Earth Observation Satellite Flying Laptop
Steinmetz, Fabian; Lengowski, Michael; Winter, Daniel et al

Poster (2013, April 10)

Thorough thermal design and testing is compulsory for every satellite mission. A well-known thermal behavior of the entire satellite system is therefore indispensable and needs to be verified during the ... [more ▼]

Thorough thermal design and testing is compulsory for every satellite mission. A well-known thermal behavior of the entire satellite system is therefore indispensable and needs to be verified during the spacecraft development. A Structural-Thermal-Model (STM) was constructed for the Flying Laptop, a satellite currently being developed at the Institute of Space Systems (IRS) of the University of Stuttgart, which enables the validation of mechanical and thermal simulations for the satellite’s Flight-Model. The STM was vibration and thermal-vacuum tested at the Centre Spatial Liège (CSL). This paper will de-scribe the design and construction of the STM as well as the facilities and test equipment used for the tests. Conclusions will be drawn from the actual test results. [less ▲]

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See detailEstimation of the Greenland ice sheet surface mass balance contribution to future sea level rise using the regional climate model MAR
Fettweis, Xavier ULg; Gallée, H.; van den Broeke, M. et al

Conference (2013, April 10)

With the aim of estimating the sea level rise (SLR) coming from Surface Mass Balance (SMB) changes over the Greenland ice sheet (GrIS), we report future projections obtained with the regional climate ... [more ▼]

With the aim of estimating the sea level rise (SLR) coming from Surface Mass Balance (SMB) changes over the Greenland ice sheet (GrIS), we report future projections obtained with the regional climate model MAR, forced by outputs of three CMIP5 General Circulation Models (GCMs). Our results indicate that in warmer climates, the mass gained due to increased winter snowfall over GrIS does not compensate the mass lost through increased meltwater run-off in summer. All the MAR projections shows similar non-linear melt increases with rising temperatures as a result of the positive surface albedo feedback, because no change is projected in the general atmospheric circulation over Greenland. Nevertheless, MAR exhibits a large range in its future projections. By coarsely estimating the GrIS SMB changes from CMIP5 GCMs outputs, we show that the uncertainty coming from the GCM-based forcing represents about half of projected SMB changes. In 2100, the CMIP5 ensemble mean projects a SLR, resulting from a GrIS SMB decrease, estimated to be 4 2 cm and 9 4 cm for the RCP 4.5 and RCP 8.5 scenarios, respectively. However, these future projections do not consider the positive melt-elevation feedback. Sensitivity MAR experiments using perturbed ice sheet topographies consistent with the projected SMB changes highlight the importance of coupling climate models to an ice sheet model. Such a coupling will allow to consider the future response of both surface processes and ice-dynamic changes, and their mutual feedbacks to rising temperatures. [less ▲]

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See detailOn women’s bodies. Religion and female circumcision in Egypt
Mescoli, Elsa ULg

Scientific conference (2013, April 10)

Among discourses about female circumcision, frequent are those which attribute it to religious beliefs, in particular Islamic ones. An ethnographic research conducted in Egypt, lead me to deconstruct such ... [more ▼]

Among discourses about female circumcision, frequent are those which attribute it to religious beliefs, in particular Islamic ones. An ethnographic research conducted in Egypt, lead me to deconstruct such simplistic association, in order to explore how we can (and if is it possible to) consider such a practice as a performing of religion on women’s bodies. In fact, in the context considered, first of all not only the Islamic religion is called into question, but also the Christian one; secondly, social dynamics are deeply intertwined with spiritual beliefs. In this framework, female circumcision has a precise role in the definition of the healthy sexuality of the couple and in the maintaining of the very same social order insofar it reflects a cosmic one. As a matter of fact, on the one hand religion is functional to legitimize a practice exerted upon women’s bodies which is perceived as essential to regulate social interactions, in the domestic context as well as in the public space. On the other hand, discourses and acts promoting and abandonment of female circumcision rely they themselves on religious precepts. These complex dynamics need to be deeply explored, in order to produce a wider knowledge about a controversial practice. The aim of my paper is to give voice to the literature on the subject and to the social actors involved in my ethnographic experience, among which several women themselves, so as to highlight in which ways religion (Islamic and Christian ones) and the practice of female circumcision are connected. [less ▲]

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See detailImpact of grazing on carbon balance of an intensively grazed grassland in Belgium
Jerome, Elisabeth ULg; Beckers, Yves ULg; Beekkerk van Ruth, Jöran ULg et al

Poster (2013, April 09)

This work analyzes the impact of grazing on the carbon balance of a grassland grazed by the Belgian Blue breed of cattle. The research was run at the Dorinne terrestrial observatory (DTO). The ... [more ▼]

This work analyzes the impact of grazing on the carbon balance of a grassland grazed by the Belgian Blue breed of cattle. The research was run at the Dorinne terrestrial observatory (DTO). The experimental site is a permanent grassland of ca. 4.2 ha located in the Belgian Condroz (50° 18’ 44’’ N; 4° 58’ 07’’ E; 248 m asl.). Other studies are conducted at the DTO including measurements of methane (CH4) and nitrous oxide fluxes (Dumortier et al., Geophysical Research Abstracts, Vol. 15, EGU2013-2083-1, 2013; Beekkerk van Ruth et al., Geophysical Research Abstracts, Vol. 15, EGU2013-3211, 2013, respectively). Grassland carbon budget (Net Biome Productivity, NBP) was calculated from Net Ecosystem Exchange (NEE) measured by eddy covariance by taking imports and exports of organic C and losses of carbon as CH4 into account (Soussana et al., 2010). After 2 years of measurements (May 2010 - May 2012), the grassland behaved on average as a CO2 source (NEE = 73 ±31 g C m-2 y-1). After inclusion of all the C inputs and outputs the site was closed to equilibrium (NBP = 23 ±34 g C m-2 y-1). To analyze the impact of grazing on CO2 fluxes, we studied the temporal evolution of gross maximal photosynthetic capacity GPPmax and dark respiration Rd (deduced from the response of daytime fluxes to radiation over 5-day windows). We calculated GPPmax and Rd variation between the end and the beginning of grazing or non-grazing periods (∆GPPmax and ∆Rd, respectively). We observed a significant decrease of GPPmax during grazing periods and measured a ∆GPPmax dependence on the average stocking rate. This allows us to quantify the assimilation reduction due to grass consumption by cattle. On the contrary, no Rd decrease was observed during grazing periods. Moreover, we found that cumulated monthly NEE increased significantly with the average stocking rate. In addition, a confinement experiment was carried out in order to analyze livestock contribution to Total Ecosystem Respiration. Each experiment extended over two days: the first day, cattle was confined in the footprint of the eddy covariance set-up (1.76 ha, 27 LU ha-1) and the second day, it was removed from it. We compared filtered half-hourly data made at 24h intervals, in the presence or absence of cattle, considering that environmental conditions were equivalent (air temperature, wind speed, radiation and wind direction). Results showed that CO2 fluxes were significantly higher when cattle were on the plot. Livestock contribution estimation to CO2 fluxes was on average 6.6 µmol m-2 s-1. [less ▲]

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See detailMeasurements of hydrogen cyanide (HCN) and acetylene (C2H2) from the Infrared Atmospheric Sounding Interferometer (IASI)
Duflot, V.; Hurtmans, D.; Clarisse, L. et al

in Atmospheric Measurement Techniques (2013), 6

Hydrogen cyanide (HCN) and acetylene (C2H2) are ubiquitous atmospheric trace gases with medium lifetime, which are frequently used as indicators of combustion sources and as tracers for atmospheric ... [more ▼]

Hydrogen cyanide (HCN) and acetylene (C2H2) are ubiquitous atmospheric trace gases with medium lifetime, which are frequently used as indicators of combustion sources and as tracers for atmospheric transport and chemistry. Because of their weak infrared absorption, overlapped by the CO2 Q branch near 720 cm−1, nadir sounders have up to now failed to measure these gases routinely. Taking into account CO2 line mixing, we provide for the first time extensive measurements of HCN and C2H2 total columns at Reunion Island (21° S, 55° E) and Jungfraujoch (46° N, 8° E) in 2009–2010 using observations from the Infrared Atmospheric Sounding Interferometer (IASI). A first order comparison with local ground-based Fourier transform InfraRed (FTIR) measurements has been carried out allowing tests of seasonal consistency which is reasonably captured, except for HCN at Jungfraujoch. The IASI data shows a greater tendency to high C2H2 values. We also examine a nonspecific biomass burning plume over austral Africa and show that the emission ratios with respect to CO agree with previously reported values. [less ▲]

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See detailEvolution of methanol (CH3OH) above the Jungfraujoch station (46.5°N) : Variability, seasonal modulation and long-term trend.
Bader, Whitney ULg; Mahieu, Emmanuel ULg; Lejeune, Bernard ULg et al

Poster (2013, April 09)

Methanol (CH3OH) is the second most abundant organic compound in the Earth’s atmosphere with concentrations close to a few ppbv, after methane, despite a short lifetime of a few days (Jacob et al., 2005 ... [more ▼]

Methanol (CH3OH) is the second most abundant organic compound in the Earth’s atmosphere with concentrations close to a few ppbv, after methane, despite a short lifetime of a few days (Jacob et al., 2005). Natural sources of CH3OH include plant growth, oceans, decomposition of plant matter, oxidation of methane and other VOCs,. . . while anthropogenic sources are from vehicles, industry,. . . biomass burning completes the emission budget. The main sink is the oxidation by hydroxyl radical, leading to the formation of carbon monoxide (CO) and formaldehyde (H2CO). The retrieval of methanol is very challenging due to the presence of strong absorption of ozone and its isotopologues in addition to water vapour and carbon dioxide in the region of the selected strong nu8 band of CH3OH. First retrievals from satellite observations using the Atmospheric Chemistry Experiment infrared Fourier Transform Spectrometer (ACE-FTS) on board the SCISAT satellite have been performed by Dufour et al. (2007 and references therein) using a spectral interval going from 995.5 to 1008.3 cm-1. In 2009, first retrievals from a ground-based FTS, using spectra recorded at Kitt Peak (31.9°N) and a window going from 992 to 999 cm-1 have been reported by Rinsland et al. (2009), followed by Vigouroux et al. (2012 and references therein) who used yet another spectral interval going from 1029 to 1037cm-1. From those former retrieval strategies and also considering the Mahieu et al. (2012) contribution, we redefined our spectral intervals to maximize the information content. Indeed, our first window, starting from 992 to 1008.3 cm-1, is issued from the merge of Rinsland et al. and Dufour et al. windows while our second, going from 1029 to 1037 cm-1, is the one used by Vigouroux et al.With this new combination of windows, we were able to enlarge the range of zenith angles providing robust results while maintaining good correlation between our two windows; this also resulted in an improvement of the fitting residuals and of the information content. We used the 2008 HITRAN compilation (Rothman et al., 2009) for spectroscopic parameters. However, systematic residuals still remain in the 1033 cm-1 region which are attributed to unsatisfactory line parameters for methanol. New cross sections recorded at the Molecular Spectroscopy Facility of the Rutherford Appleton Laboratory (Harrison et al. 2012) and calibrated in intensity by using the reference spectra from the Pacific Northwest National Laboratory (PNNL) IR database will be tested as soon as converted into pseudolines. In this work, we will present the first long-term time series of methanol total columns, resulting from the implementation of our new retrieval strategy. All retrievals have been performed with the SFIT2 algorithm (v 3.91) (Rinsland et al., 1998) using a series of about 7 000 spectra recorded between 1995 and 2012, with zenith angles between 60 and 85°. These solar absorption observations have been recorded with a high-resolution FTIR Bruker 120HR instrument, at the high altitude station of the Jungfraujoch (46.5°N, 8°E, 3580 m asl), within the framework of the Network for the Detection of Atmospheric Composition Change (NDACC, visit http://www.ndacc.org). [less ▲]

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