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See detailRapport des prospections géophysiques ESO-ESU
Nguyen, Frédéric ULg; Hermans, Thomas ULg

Report (2017)

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See detailEl idealismo europeo frente a la realidad global.¿Del enfoque regional a una preferencia por potencias emergentes?
Santander, Sébastian ULg

in Molano Cruz, Giovanni (Ed.) La UNIÓN EUROPEA en AMÉRICA LATINA y el CARIBE Lógicas y políticas de un actor global (2017)

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See detailfәrā amәṣ̌ā spәṇtā gāθā̊ gə̄uruuāin. Homenaje a Helmut Humbach en su 95º aniversario
Cantera, Alberto; Ferrer-Losilla, Joan Josep ULg

Book published by Sociedad de Estudios Iranios y Turanios (2017)

Third volume of the journal "Estudios Iranios y Turanios" in hommage of prof. Helmut Humbach in his 95th birthday.

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See detailExperimental observation of the Poincaré-Birkhoff scenario in a driven many-body quantum system
Tomkovic, Jiri; Muessel, Wolfgang; Strobel, Helmut et al

in Physical Review A (2017), 95

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See detailAssessing Inter-and Intramolecular Continuous-Flow Strategies towards Methylphenidate Hydrochloride
Gerardy, Romaric ULg; Winter, Marc; Vizza, Alessandra et al

in Reaction Chemistry and Engineering (2017)

The batch-to-flow translation of inter- and intramolecular strategies for the diastereoselective preparation of the active pharmaceutical ingredient threo-methylphenidate hydrochloride is presented. Both ... [more ▼]

The batch-to-flow translation of inter- and intramolecular strategies for the diastereoselective preparation of the active pharmaceutical ingredient threo-methylphenidate hydrochloride is presented. Both inter- and intramolecular strategies imply the telescoping of multiple processing steps and the generation of unstable diazospecies under continuous-flow conditions. The intermolecular strategy relies on an unprecedented continuous-flow Rh-catalyzed intermolecular C-H carbene insertion, providing enriched threo-N-Boc methylphenidate in 38% or 19% isolated yield according to sequential or fully telescoped processes, respectively. Quantitative Boc-deprotection is carried out off-line. The intramolecular strategy relies on a continuous-flow thermal intramolecular C-H carbene insertion, providing enriched threo-methylphenidate hydrochloride in 70% isolated yield. A continuous-flow photochemical alternative is also presented. The critical step of the most promising intramolecular strategy is implemented on mesoscale in a pilot-scale continuous-flow reactor. [less ▲]

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See detailMetabolomic and molecular signatures of Mascarene Aloes using a multidisciplinary approach
Govinden-Soulange, J.; Lobine, D.; Frederich, Michel ULg et al

in South African Journal of Botany (2017), 108

In this research a multidisciplinary approach was used to unveil the genetic, metabolic uniqueness and relationships of endemic Mascarene Aloes (Aloe macra, Aloe purpurea, Aloe tormentorii) with respect ... [more ▼]

In this research a multidisciplinary approach was used to unveil the genetic, metabolic uniqueness and relationships of endemic Mascarene Aloes (Aloe macra, Aloe purpurea, Aloe tormentorii) with respect to Aloe vera. Nuclear magnetic resonance spectroscopy, DNA sequencing and antioxidant profiles of these Aloes were studied. Principal component analysis following 1H NMR revealed the specificity of the Mascarene Aloes relative to Aloe vera. The superior free radical scavenging ability of A. purpurea, A. macra and A. tormentorii as compared to other Aloes was also unveiled. Phylogenetic analyses of chloroplast genes and ITS region sequences of these Mascarene Aloes were done using maximum parsimony and Bayesian analysis. Mascarene Aloes clustered within one clade separate from Aloe vera confirming their relative recent emergence in this genus. Results from this study showed that there is sufficient evidence at the metabolomic and molecular level to distinguish between Aloe ​purpurea from Mauritius and that of Reunion. © 2016 SAAB [less ▲]

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See detailThe neural bases of proactive and reactive control processes in normal aging
Manard, Marine ULg; François, Sarah ULg; Phillips, Christophe ULg et al

in Behavioural Brain Research (2017), 320

Introduction. Research on cognitive control suggests an age-related decline in proactive control abilities (anticipatory control), whereas reactive control (following conflict detection) seems to remain ... [more ▼]

Introduction. Research on cognitive control suggests an age-related decline in proactive control abilities (anticipatory control), whereas reactive control (following conflict detection) seems to remain intact. As proactive and reactive control abilities are associated with specific brain networks, this study investigated age-related effects on the neural substrates associated with each kind of control. Methods. In an event-related fMRI study, a modified version of the Stroop task was administered to groups of 20 young and 20 older healthy adults. Based on the theory of dual mechanisms of control, the Stroop task has been built to induce proactive or reactive control depending on task context. Results. Behavioral results (p < .05) indicated faster processing of interfering items in the mostly incongruent (MI) than the mostly congruent (MC) context in both young and older participants. fMRI results showed that reactive control is associated with increased activity in left frontal areas for older participants. For proactive control, decreased activity in the bilateral anterior cingulate cortex was associated with more activity in the right middle frontal gyrus in the older than the younger group. Conclusion. These observations support the hypothesis that aging affects the neural networks associated with reactive and proactive cognitive control differentially. These age-related changes are very similar to those observed in young adults with low dopamine availability, suggesting that a general mechanism (prefrontal dopamine availability) may modulate brain networks associated with various kinds of cognitive control. [less ▲]

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See detailRapid Effects of Estrogens on Avian Brain and Social Behavior
Remage-Healey, Luke; Heimovics, Sarah A.; Soma, Kiran K et al

in Pfaff, Donald W; Arnold, Arthur P; Etgen, Anne M (Eds.) et al Hormones, Brain and Behavior (2017)

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See detailExtreme intra-clutch egg size dimorphism is not coupled with corresponding differences in antioxidant capacity and stable isotopes between eggs
Poisbleau, Maud; Beaulieu, Michaël; Dehnhard, Nina et al

in Comparative Biochemistry and Physiology Part A : Molecular & Integrative Physiology (2017), 205

Oviparous females need to allocate resources optimally to their eggs in order to maximize their fitness. Among these resources, dietary antioxidants, acquired by females and transferred to the eggs during ... [more ▼]

Oviparous females need to allocate resources optimally to their eggs in order to maximize their fitness. Among these resources, dietary antioxidants, acquired by females and transferred to the eggs during egg formation, can greatly affect the development and survival of the embryo and chick. In crested penguins, incubation starts after the second and last egg is laid and, as opposed to many other bird species, this egg hatches first, thereby enhancing the survival of the chick. Here, we assessed whether antioxidant and isotopic composition could underlie these differences between eggs within clutches of southern rockhopper penguins (Eudyptes chrysocome chrysocome). The second-laid egg had higher total antioxidant capacity than the first-laid egg, although this was not due to higher antioxidant concentration but to its higher mass. This suggests that resources are allocated by females at a constant rate in both eggs within clutches. Accordingly, we found a strong correlation for isotopic compositions between eggs suggesting that resources were allocated similarly to each egg within the clutch. Overall, we found little evidence for a significant role of antioxidant and isotopic compositions to explain differences in terms of embryo/chick development between eggs in crested penguins. However, since our results suggest a constant rate of antioxidant transfer from females to eggs, limiting the mass of the first-laid egg might represent a strategy for females to spare antioxidant defences and preserve self-maintenance. [less ▲]

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See detailLe colloque Francarbi à Bruxelles : le principe du contradictoire en arbitrage
Caprasse, Olivier ULg

in Journal des Tribunaux (2017)

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See detailThe Chika Unigwe Bibliography
Tunca, Daria ULg

Textual, factual or bibliographical database (2017)

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See detailFoam fractionation as a tool to study the air-water interfacestructure-function relationship of wheat gluten hydrolysates
Wouters, Arno G.B.; Rombouts, Ine; Schoebrechts, Nele et al

in Colloids and Surfaces B : Biointerfaces (2017), 151

Enzymatic hydrolysis of wheat gluten protein improves its solubility and produces hydrolysates withfoaming properties which may find applications in food products. First, we here investigated whetherfoam ... [more ▼]

Enzymatic hydrolysis of wheat gluten protein improves its solubility and produces hydrolysates withfoaming properties which may find applications in food products. First, we here investigated whetherfoam-liquid fractionation can concentrate wheat gluten peptides with foaming properties. Foam andliquid fractions had high and very low foam stability (FS), respectively. In addition, foam fractions wereable to decrease surface tension more pronouncedly than un-fractionated samples and liquid fractions,suggesting they are able to arrange themselves more efficiently at an interface. As a second objective,foam fractionation served as a tool to study the structural properties of the peptides, causing thesedifferences in air-water interfacial behavior. Zeta potential and surface hydrophobicity measurements didnot fully explain these differences but suggested that hydrophobic interactions at the air-water interfaceare more important than electrostatic interactions. RP-HPLC showed a large overlap between foam andliquid fractions. However, a small fraction of very hydrophobic peptides with relatively high averagemolecular mass was clearly enriched in the foam fraction. These peptides were also more concentratedin un-fractionated DH 2 hydrolysates, which had high FS, than in DH 6 hydrolysates, which had low FS.These peptides most likely play a key role in stabilizing the air-water interface. [less ▲]

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See detailLes frontières du droit à l'épreuve des films de mafias
Thirion, Nicolas ULg; Pasteger, David ULg

in Flores-Lonjou, Magalie (Ed.) Frontière(s) au cinéma - Actes des septièmes rencontres "Droit et cinéma" (2017)

demander dans quelle mesure l’injonction du brigand qui exige « la bourse ou la vie ! » peut être comparée à la norme de comportement édictée par un Etat sous la forme d’une loi, c’est poser la ... [more ▼]

demander dans quelle mesure l’injonction du brigand qui exige « la bourse ou la vie ! » peut être comparée à la norme de comportement édictée par un Etat sous la forme d’une loi, c’est poser la sempiternelle question de la frontière qui sépare le droit du non-droit, tout au moins dans une perspective juspositiviste, en tant que cette école de théorie du droit refuse de définir le phénomène juridique en se référant à une valeur ou un ensemble de valeurs. La frontière du droit et du non-droit est en effet particulièrement difficile à tracer, nonobstant plusieurs siècles de discussions philosophiques à ce sujet. Lorsque, fatigué de parcourir les chemins, le brigand décide de s’installer en ville pour s’y adonner au racket des commerçants du quartier et qu’il s’adjoint ensuite le concours d’autres bandits, c’est un gang de malfaiteurs qui voit le jour. Si, ultérieurement, ce gang se concerte avec d’autres bandes de truands pour s’épauler mutuellement dans les exactions auxquelles ils se livrent sur leurs territoires respectifs, il prend alors la forme d’une organisation criminelle ou, au sens large du terme, d’une « mafia ». Le cinéma de Francis Ford Coppola, Martin Scorsese, Brian De Palma, Sergio Leone ou bien encore Matteo Garrone, entre autres, dépeint, souvent avec réalisme, la genèse et le fonctionnement de telles organisations criminelles. La communication a proposé, au moyen d’illustrations tirées des films de ces grands cinéastes, une analyse de microscopie juridique du crime organisé. Une description serrée de la particule élémentaire du phénomène juridique, identifiée par Lucien François dans son ouvrage de théorie du droit Le cap des Tempêtes sous l’appellation de « jurème », met en lumière une indéniable proximité entre les techniques de pouvoir utilisées respectivement par le brigand isolé, la bande organisée et l’Etat souverain. En remontant ensuite vers la structure plus complexe d’un système étatique, on se demandera si, en fin de compte, dans la vision juspositiviste poussée au bout de sa logique par Lucien François, l’Etat ne pourrait être réduit, d’un point de vue ontologique, à un pouvoir de fait comparable, par les techniques de contrainte qu’il exerce sur ses sujets, à une organisation criminelle – abstraction faite des valeurs promues ou poursuivies par tel ou tel appareil étatique. [less ▲]

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See detailIntermodal network design: a three-mode bi-objective model applied to the case of Belgium
Mostert, Martine ULg; Caris, An; Limbourg, Sabine ULg

in Flexible Services and Manufacturing Journal (2017)

Freight transport planning is nowadays encouraged to align with environmental objectives. Among those, climate change is of particular interest for many countries. In its White Paper on Transport, the ... [more ▼]

Freight transport planning is nowadays encouraged to align with environmental objectives. Among those, climate change is of particular interest for many countries. In its White Paper on Transport, the European Commission considers intermodal transport as a potential solution for reducing environmental impacts. In order to make good strategic transport decisions, realistic decision support models for freight transport networks must be developed, so that insights can be derived for the different stakeholders of the transportation chain. This research proposes a bi-objective mathematical formulation which takes into account economic and environmental objectives, on a road and intermodal network with three modes of transport (road, intermodal rail, and intermodal inland waterways), and in which economies of scale of intermodal transport can be considered. With this model better fitting reality, an application to the Belgian case study provides practical information on how flows, terminal types and locations vary depending on the chosen policy, on the integration or not of economies of scale, on costs or emissions modifications and on the number of terminals to locate. Results show that the chosen policy influences the terminal type and the intermodal market share. The study also highlights the interest of intermodal transport on short distances, and the risk of flow exchanges inside the intermodal market share, rather than between road and intermodal transport. [less ▲]

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See detailAu-delà de la croissance : quel projet, quelle pensée ?
Cassiers, Isabelle; Maréchal, Kevin ULg

Scientific conference (2017)

Le terme post-croissance désigne l’entrée dans une ère que nous ne parvenons pas encore à nommer, si ce n’est par référence à celle que nous quittons. Les symptômes qui signent la fin d’une époque sont ... [more ▼]

Le terme post-croissance désigne l’entrée dans une ère que nous ne parvenons pas encore à nommer, si ce n’est par référence à celle que nous quittons. Les symptômes qui signent la fin d’une époque sont clairs et sans appel : un retour aux régularités du passé est illusoire. La poursuite de la croissance économique ne constitue plus un projet de société crédible, pour des raisons écologiques, sociales et géopolitiques. Toutefois, l’inédit historique et la complexité actuelle du monde sont tels que nous avançons à tâtons. Renoncer à la croissance pose aux économistes (théoriciens et praticiens) des défis majeurs qui exigent de reprendre à leur racine, sous un éclairage transdisciplinaire, les questions dont ils traitent couramment. Plus fondamentalement, un tel exercice les confronte à l’examen des finalités poursuivies. Ce cours-conférence présente l’ouvrage collectif « Vers une société post-croissance » (Éd. de l’Aube, 2017). Les auteurs de ce volume s’interrogent : quels sont les problèmes majeurs qui surgissent à l'esprit dès lors qu'on abandonne un objectif de croissance continue ? Par où passe la transition vers un autre horizon ? Quels sont les courants de pensée et les modes de gouvernance susceptibles d'articuler un projet cohérent ? Ces deux leçons parcourent les grandes lignes de l’ouvrage et en exposent les trois premiers chapitres, traitant du projet et de la pensée « post-croissance », et des thèmes spécifiques de l’emploi, du travail et de la démarchandisation. [less ▲]

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See detailMethanol emissions from maize: Ontogenetic dependence to varying light conditions and guttation as an additional factor constraining the flux
Mozaffar, Ahsan ULg; Schoon, N.; Digrado, Anthony ULg et al

in Atmospheric Environment (2017), 152

Because of its high abundance and long lifetime compared to other volatile organic compounds in the atmosphere, methanol (CH3OH) plays an important role in atmospheric chemistry. Even though agricultural ... [more ▼]

Because of its high abundance and long lifetime compared to other volatile organic compounds in the atmosphere, methanol (CH3OH) plays an important role in atmospheric chemistry. Even though agricultural crops are believed to be a large source of methanol, emission inventories from those crop ecosystems are still scarce and little information is available concerning the driving mechanisms for methanol production and emission at different developmental stages of the plants/leaves. This study focuses on methanol emissions from Zea mays L. (maize), which is vastly cultivated throughout the world. Flux measurements have been performed on young plants, almost fully grown leaves and fully grown leaves, enclosed in dynamic flow-through enclosures in a temperature and light-controlled environmental chamber. Strong differences in the response of methanol emissions to variations in PPFD (Photosynthetic Photon Flux Density) were noticed between the young plants, almost fully grown and fully grown leaves. Moreover, young maize plants showed strong emission peaks following light/dark transitions, for which guttation can be put forward as a hypothetical pathway. Young plants’ average daily methanol fluxes exceeded by a factor of 17 those of almost fully grown and fully grown leaves when expressed per leaf area. Absolute flux values were found to be smaller than those reported in the literature, but in fair agreement with recent ecosystem scale flux measurements above a maize field of the same variety as used in this study. [less ▲]

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See detailEmbedded solids of any dimension in the X-FEM. Part I - Building a dedicated P1 function space
Duboeuf, Frédéric ULg; Béchet, Eric ULg

in Finite Elements in Analysis and Design (2017)

This paper focuses on the design of a dedicated P1 function space to model elliptic boundary value problem on a manifold embedded in a space of higher dimension. Using the traces of the linear P1 shape ... [more ▼]

This paper focuses on the design of a dedicated P1 function space to model elliptic boundary value problem on a manifold embedded in a space of higher dimension. Using the traces of the linear P1 shape functions, it introduces an algorithm to reduce the function space into an equivalent space having the same properties than a P1 Lagrange approximation. Convergence studies involving problems of codimension one or two embedded in 2D or 3D show good accuracy with regard to classical finite element and analytical solutions. The effects of the relative position of the domain with respect to the mesh are studied in a sensitivity analysis; it illustrates how the proposed solution allows to keep the condition number bounded. A comparative study is performed with the method introduced by Olshanskii et al. 2009 on a closed surface to validate our approach. The robustness of the proposed approach is investigated with regard to their method and that of Burman et al. 2016. This paper is the first in a series of two, on the topic of embedded solids of any dimension within the context of the extended finite element method. It investigates problems involving borderless domains or domains with boundary subject to Dirichlet constraint defined only on the boundaries of the bulk mesh, while the forthcoming paper overcomes this limitation by introducing a new stable Lagrange multiplier space for Dirichlet boundary condition (and more generally stiff condition), that is valid for every combination of the background mesh and manifold dimensions. The combination of both algorithms allows to handle any embedding i.e. 1D, 2D and 3D problems embedded in 2D or 3D background meshes. [less ▲]

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See detailPitfalls in supermatrix phylogenomics
Philippe, Hervé; Vienne, Damien M. De; Ranwez, Vincent et al

in European Journal of Taxonomy (2017), 283

In the mid-2000s, molecular phylogenetics turned into phylogenomics, a development that improved the resolution of phylogenetic trees through a dramatic reduction in stochastic error. While some then ... [more ▼]

In the mid-2000s, molecular phylogenetics turned into phylogenomics, a development that improved the resolution of phylogenetic trees through a dramatic reduction in stochastic error. While some then predicted “the end of incongruence”, it soon appeared that analysing large amounts of sequence data without an adequate model of sequence evolution amplifies systematic error and leads to phylogenetic artefacts. With the increasing flood of (sometimes low-quality) genomic data resulting from the rise of high-throughput sequencing, a new type of error has emerged. Termed here “data errors”, it lumps together several kinds of issues affecting the construction of phylogenomic supermatrices (e.g., sequencing and annotation errors, contaminant sequences). While easy to deal with at a single-gene scale, such errors become very difficult to avoid at the genomic scale, both because hand curating thousands of sequences is prohibitively time-consuming and because the suitable automated bioinformatics tools are still in their infancy. In this paper, we first review the pitfalls affecting the construction of supermatrices and the strategies to limit their adverse effects on phylogenomic inference. Then, after discussing the relative non-issue of missing data in supermatrices, we briefly present the approaches commonly used to reduce systematic error. [less ▲]

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