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See detailPreparations for the use of Raman spectrometers on Mars
Malherbe, Cédric ULg; Ingley, Richard; Hutchinson, Ian B. et al

Conference (2014, October)

Raman spectroscopy has been selected as a non-destructive powerful analytical method for forthcoming planetary exploration. In the context of the upcoming ExoMars and NASA 2020 missions (developed by the ... [more ▼]

Raman spectroscopy has been selected as a non-destructive powerful analytical method for forthcoming planetary exploration. In the context of the upcoming ExoMars and NASA 2020 missions (developed by the European Space Agency, IKI Roscomos and NASA) analysis of the biological and geological terrestrial analogues using laboratory instrumentation is of great importance; especially testing the performance of flight-like operating modes and conditions on the feasibility of flight instruments meeting their science goals. Here we present a set of measurements of terrestrial analogues (among them desert varnishes) selected in preparation for in-situ Raman analysis on Mars. Laboratory instrumentation has been used to fully characterise the samples in addition to being operated in modes consistent with ExoMars RLS instrument flight designs, sample preparation and delivery. We discuss the performance of the spectrometers regarding the detection of the target signatures and their geological context. The impact of instrument operating modes and application of flight instrument sampling philosophy (i.e. spot size, grain size, number of target locations, sample preparation and delivery) on the signal intensity and the limits of detection are also discussed. [less ▲]

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See detailUsing XCO2 retrievals fo rassessing the long-term consistency of NDACC/FTIR data sets
Barthlott; Schneider, M; Hase, F et al

in Atmospheric Measurement Techniques. Papers in Open Discussion (2014), 7

Within the NDACC (Network for the Detection of Atmospheric Composition Change), more than 20 FTIR (Fourier–Transform InfraRed) spectrometers, spread worldwide, provide long-term data records of many ... [more ▼]

Within the NDACC (Network for the Detection of Atmospheric Composition Change), more than 20 FTIR (Fourier–Transform InfraRed) spectrometers, spread worldwide, provide long-term data records of many atmospheric trace gases. We present a method that uses measured and modelled XCO2 for assessing the consistency of these data records. Our NDACC XCO2 retrieval setup is kept simple so that it can easily be adopted for any NDACC/FTIR-like measurement made since the late 1950s. By a comparison to coincident TCCON (Total Carbon Column Observing Network) measurements, we empirically demonstrate the useful quality of this NDACC XCO2 product (empirically obtained scatter between TCCON and NDACC is about 4‰ for daily mean as well as monthly mean comparisons and the bias is 25 ‰). As XCO2 model we developed and used a simple regression model fitted to CarbonTracker results and the Mauna Loa CO2 in-situ records. A comparison to TCCON data suggests an uncertainty of the model for monthly mean data of below 3 ‰. We apply the method to the NDACC/FTIR spectra that are used within the project MUSICA (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water) and demonstrate that there is a good consistency for these globally representative set of spectra measured since 1996: the scatter between the modelled and measured XCO2 on a yearly time scale is only 3 ‰. [less ▲]

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See detailIsocinétisme et muscles rotateurs d'épaule
Forthomme, Bénédicte ULg; Crielaard, Jean-Michel ULg; Kaux, Jean-François ULg et al

in Innovations technologiques et préhension (2014, October)

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See detailEtiology in Parthenius of Nicaea
Vandersmissen, Marc ULg

in Euphrosyne (2014), 42

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See detailLe mystère belge de la translucidité des SCI françaises
Docclo, Caroline ULg

in Tijdschrift voor Fiscaal Recht (2014), (466), 694-697

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See detailDevenir art-thérapeute
Vandeninden, Elise ULg

in SociologieS (2014)

In the field of mental health workers, a new profession is emerging: animators of art workshops in psychiatry, also called ‘art therapists’. Our paper reveals the results of a survey conducted in Belgium ... [more ▼]

In the field of mental health workers, a new profession is emerging: animators of art workshops in psychiatry, also called ‘art therapists’. Our paper reveals the results of a survey conducted in Belgium among these new professionals. In portraying this new group of ‘distributed’ workers, we will discuss the reasons for their difficult process of professionalization [less ▲]

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See detailAprès Fukushima. La vie préfabriquée
Gemenne, François ULg

in Agier, Michel (Ed.) Un Monde de Camps (2014)

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See detailAdherence to Continuous Positive Airway Pressure (CPAP) Therapy
Deflandre, Eric ULg; Degey, Stéphanie; BONHOMME, Vincent ULg et al

Poster (2014, October)

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See detailAdherence to Continuous Positive Airway Pressure (CPAP) Therapy
Deflandre, Eric ULg; Degey, Stéphanie; BONHOMME, Vincent ULg et al

Poster (2014, October)

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See detailVtriusque sermonis cognatio : la lexicographie bilingue à la fin de l'Antiquité
Rochette, Bruno ULg

in Martorelli, Luca (Ed.) Greco antico nell'Occidente carolingo. Frammenti di testi attici nell'Ars di Prisciano (2014)

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See detailProspection géophysique de la zone faillée de Hockai dans la région de Malmedy: Rapport des tomographies de résistivité électrique
Hermans, Thomas ULg; Nguyen, Frédéric ULg

Report (2014)

Ce rapport consiste en la présentation des résultats des prospections géophysiques par tomographie de résistivité électrique (ERT) menées sur la zone faillée de Hockai dans la région de Malmedy. Le but ... [more ▼]

Ce rapport consiste en la présentation des résultats des prospections géophysiques par tomographie de résistivité électrique (ERT) menées sur la zone faillée de Hockai dans la région de Malmedy. Le but principal de ces investigations est de juger de la fracturation de la roche dans et en dehors de la Zone de Faille de Hockai (ZFH) et de mettre en évidence les structures liées à cette zone de failles. [less ▲]

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See detailNegative polarity as a trigger for the development of modal meaning
Davidse, Kristin; Van linden, An; Brems, Lieselotte ULg

Conference (2014, October)

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See detailHighly dispersed iron xerogel catalysts for p-nitrophenol degradation by photo-Fenton effects
Mahy, Julien ULg; Tasseroul, Ludivine ULg; Zubiaur, Anthony ULg et al

in Microporous and Mesoporous Materials (2014), 197

Several iron xerogel catalysts were synthesized by hydrolysis and condensation of tetraethoxysilane (TEOS) and 3-(2-aminoethylamino)propyltrimethoxysilane (EDAS) which is able to form a chelate with iron ... [more ▼]

Several iron xerogel catalysts were synthesized by hydrolysis and condensation of tetraethoxysilane (TEOS) and 3-(2-aminoethylamino)propyltrimethoxysilane (EDAS) which is able to form a chelate with iron ions. The EDAS/TEOS ratio strongly influences the texture of xerogel catalysts. The specific surface area and the micro- and mesoporous volume increase with this ratio. It seems that EDAS plays a nucleating agent role for silica particles and allows to anchor Fe-based moieties inside the silica network. Iron oxide nanoparticles of diameter 1-1.5 nm and Fe3+ ions result, encapsulated in silica particles with sizes of about 10-30 nm in diameter. The iron species was determined by Mössbauer spectroscopy and magnetometry measurements and only Fe3+ species were observed in xerogel catalysts. The Fenton and photo-Fenton effect of these catalysts were evaluated on the degradation of p-nitrophenol in aqueous media under different conditions. Results show that in the presence of H2O2, iron xerogel catalysts present a photo-Fenton effect, reaching 99 % of degradation after 24 h. [less ▲]

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See detailDissociation Pathways of Benzylpyridinium “Thermometer” Ions Depend on the Activation Regime: An IRMPD Spectroscopy Study
Morsa, Denis ULg; Gabelica, Valérie ULg; Rosu, Frédéric et al

in Journal of Physical Chemistry Letters (2014), 5

The dissociation of benzylpyridinium “thermometer” ions is widely used to calibrate the internal energy of ions produced in mass spectrometry. The fragmentation mechanism is usually believed to yield a ... [more ▼]

The dissociation of benzylpyridinium “thermometer” ions is widely used to calibrate the internal energy of ions produced in mass spectrometry. The fragmentation mechanism is usually believed to yield a benzylium cation, although recent studies suggest the possibility of a rearrangement leading to the tropylium isomer, which would compromise the accuracy of energy calibrations. In this study, we used IRMPD spectroscopy to probe the dissociation pathways of the p-(tert-butyl)- benzylpyridinium ion. Our results show that the formation of both benzylium and tropylium products is feasible depending on the activation regime and on the reaction time scale. Varying the trapping delays in the hexapole gives insight into a rearrangement mechanism occurring through consecutive reactions with an isomerization from benzylium to tropylium. Our work provides experimental validations for the established calibration procedure and highlights the adequacy of IRMPD spectroscopy to qualitatively resolve gas-phase rearrangement kinetics. [less ▲]

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See detailImproved spectral fitting of nitrogen dioxide from OMI in the 405-465 nm window
van Geffen, J H G M; Boersma, K F; Van Roozendael, M et al

in Atmospheric Measurement Techniques. Papers in Open Discussion (2014), 7

An improved nitrogen dioxide (NO2) slant column density retrieval for the Ozone Monitoring Instrument (OMI) in the 405–465 nm spectral region is presented. Since the launch of OMI on board NASA's EOS-Aura ... [more ▼]

An improved nitrogen dioxide (NO2) slant column density retrieval for the Ozone Monitoring Instrument (OMI) in the 405–465 nm spectral region is presented. Since the launch of OMI on board NASA's EOS-Aura satellite in 2004, DOAS retrievals of NO2 slant column densities have been the starting point for the KNMI DOMINO (v2.0) and NASA SP (v2.1) retrievals. However, recent intercomparisons between NO2 retrievals from OMI and other UV/Vis and limb spectrometers, as well as ground-based measurements, clearly suggested that OMI stratospheric NO2 is biased high. This study revises the OMI NO2 retrieval in detail. The representation of the OMI slit function to convolve high-resolution reference spectra onto the relevant spectral grid is improved. The window used for the wavelength calibration is optimised, leading to much-reduced fitting errors. Ozone and water vapour spectra used in the fit are updated, reflecting the recently improved knowledge on their absorption cross section as documented in the literature. The improved spectral fit also accounts for absorption by the O2–O2 collision complex and by liquid water over clear-water areas. The main changes in the improved spectral fitting result from the updates related to the wavelength calibration: the RMS error of the fit is reduced by 23% and the NO2 slant column by 0.85 × 1015 molec cm-2, independent of latitude, solar zenith angle and NO2 value. Including O2–O2 and liquid water absorption and updating the O3 and water vapour cross-section spectra further reduces NO2 slant columns on average by 0.35 × 1015 molec cm-2, accompanied with a further 9% reduction in the RMS error of the fit. The improved OMI NO2 slant columns are consistent with independent NO2 retrievals to within a range that can be explained by photo-chemically driven diurnal increases in stratospheric NO2 and by small differences in fitting window and fitting approach. The revisions indicate that current OMI NO2 slant columns suffered mostly from an additive, positive offset that is removed by the improved wavelength calibration and representation of the OMI slit function. It is therefore anticipated that the improved NO2 slant columns are most important to retrievals of spatially homogeneous stratospheric NO2 rather than to heterogeneous tropospheric NO2. [less ▲]

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See detailFiabilité et confiance
de Saint Georges, Marie-Christine; Haxhe, Stéphanie ULg

Conference (2014, October)

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See detailL’ANATOMIE REVISITÉE DU PETIT BASSIN
Bonnet, Pierre ULg

in Louvain Medical (2014), 133(8), 3-13

Le petit bassin est un espace cônique musculoosseux comportant la portion inférieure de la cavité péritonéale surmontant l’espace endopelvien. Les viscères pelviens reçoivent leur vascularisation des ... [more ▼]

Le petit bassin est un espace cônique musculoosseux comportant la portion inférieure de la cavité péritonéale surmontant l’espace endopelvien. Les viscères pelviens reçoivent leur vascularisation des parois latérales au sein de l’espace endopelvien, leur innervation dépend d’une double origine, abdominale et pelvienne. Les parois de cet espace abritent les nerfs somatiques et vaisseaux destinés aux parois de la partie inférieure du tronc et aux membres inférieurs. La connaissance pratique de cette anatomie peut être aidée par une approche constructive élaborant les parois et ensuite le contenu de cet espace. [less ▲]

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