Last 7 days
Bookmark and Share    
Full Text
Peer Reviewed
See detailEvaluation of the quantitative performances of Supercritical Fluid Chromatography : from method development to validation
Dispas, Amandine ULg; Lebrun, Pierre ULg; Ziemons, Eric ULg et al

in Journal of Chromatography. A (2014), 1353(Method Validation), 78-88

Recently, the number of papers about SFC increased drastically but scientists did not truly focus their work on quantitative performances of this technique. In order to prove the potential of UHPSFC, the ... [more ▼]

Recently, the number of papers about SFC increased drastically but scientists did not truly focus their work on quantitative performances of this technique. In order to prove the potential of UHPSFC, the present work discussed about the different steps of the analytical life cycle of a method: from development to validation and application. Moreover, the UHPSFC quantitative performances were evaluated in comparison with UHPLC, which is the main technique used for quality control in the pharmaceutical industry and then could be considered as a reference. The methods were developed using Design Space strategy, leading to the optimization of robust method. In this context, when the Design Space optimization shows guarantee of quality, no more robustness study is required prior to the validation. Then, the methods were geometrically transferred in order to reduce the analysis time. The UHPSFC and UHPLC methods were validated based on the total error approach using accuracy profile. Even if UHPLC showed better precision and sensitivity, UHPSFC method is able to give accurate results in a dosing range larger than the 80–120% range required by the European Medicines Agency. Consequently, UHPSFC results are valid and could be used for the control of active substance in a finished pharmaceutical product. Finally, UHPSFC validated method was used to analyse real samples and gave similar results than the reference method (UHPLC). [less ▲]

Detailed reference viewed: 31 (14 ULg)
Peer Reviewed
See detailInsulin Sensitivity Variability during Hypothermia
Sah Pri, Azurahisham; Chase, J. Geoffrey; Pretty, Christopher et al

in Proceedings of the 19th IFAC Conference (2014, August)

Detailed reference viewed: 5 (1 ULg)
Peer Reviewed
See detailSurvey about diffusion and adoption of glycaemic controller in European intensive care units
Penning, Sophie ULg; Pironet, Antoine ULg; Chase, J. Geoffrey et al

in Proceedings of the 19th IFAC Conference (2014, August)

Detailed reference viewed: 6 (2 ULg)
Peer Reviewed
See detailPrediction of Body Weight of Primiparous Dairy Cows Throughout Lactation
Vanrobays, Marie-Laure ULg; Vandenplas, Jérémie ULg; Hammami, Hedi ULg et al

in Proceedings of the 10th World Congress on Genetics Applied to Livestock Production (2014, August)

Body weight (BW) can be computed using linear conformation traits (CBW). However, these traits are recorded mostly once during a lactation. Therefore, predicted BW (PBW) is needed throughout the lactation ... [more ▼]

Body weight (BW) can be computed using linear conformation traits (CBW). However, these traits are recorded mostly once during a lactation. Therefore, predicted BW (PBW) is needed throughout the lactation (e.g., allowing feed intake prediction in milk recording systems). A two-step procedure was developed to obtain PBW using a random regression test-day model using CBW as observations. Added second step consisted in changing prior distribution for additive genetic random effects using results from first step to predict again PBW. This method was applied on 24,919 primiparous Holstein cows having 25,061 CBW to obtain PBW for 232,436 test-days. Results showed that applying both steps provided more accurate estimates than using only the first step. Furthermore, this procedure predicting PBW throughout lactation is also extremely flexible because actual BW can also be used together with CBW, the prediction model being able to accommodate different levels of accuracies. [less ▲]

Detailed reference viewed: 16 (4 ULg)
Full Text
Peer Reviewed
See detailAssessment of pulmonary hypertension in dogs with chronic pulmonary diseases by thoracic ct-angiography.
Couvreur, T.; Roels, Elodie ULg; Merveille, Anne-Christine ULg et al

in Proceedings of the ECVDI Meeting, Utrecht - Netherlands - 27-30 August 2014 (2014, August)

Detailed reference viewed: 3 (0 ULg)
Full Text
Peer Reviewed
See detailde Mérode (Prince Werner)
Genin, Vincent ULg; Philippe de Schoutheete de Tervarent

in Nouvelle Biographie Nationale (2014)

Detailed reference viewed: 18 (3 ULg)
Full Text
Peer Reviewed
See detailQuality of Work Life, Burnout, and Stress in Emergency Department Physicians: A Qualitative Review
Bragard, Isabelle ULg; Dupuis, Gilles; Fleet, Richard

in European Journal of Emergency Medicine (2014)

Detailed reference viewed: 10 (0 ULg)
Full Text
Peer Reviewed
See detailCompeting Latin American Regionalisms in a changing world
Santander, Sébastian ULg

in Telò, Mario (Ed.) European Union and New Regionalism. (2014)

Collective ambitions in Latin America (LA) go hand in hand with the processes of independence and the creation of States. Since the 19th century, the continent has experienced wave after wave of different ... [more ▼]

Collective ambitions in Latin America (LA) go hand in hand with the processes of independence and the creation of States. Since the 19th century, the continent has experienced wave after wave of different types of regionalism: the ‘Bolivarian’ joint project, ‘introverted’ regional associations and ‘open’ regionalism. LA’s ‘left-turn’ has given rise to a new wave of regional projects. Described by some as post-liberal, these projects have also seen changes. Shared ambitions have therefore continued to be at the heart of the political debate of LA decision-makers. Nonetheless, while LA regionalism is a constant over time, it is still a work-in-progress. Its nature keeps evolving, based on changes in the domestic and international political context. As a political phenomenon, regionalism covers a dynamic and shifting reality. This reality can move forward, slow down or move backwards, as this comparative analysis of LA regional organisations (ROs) shows. These changes can also be the result of competition between these projects. We will also see that, while regionalisms are the result of a political will of their own, they can also be fashioned by external actors’ strategies. The US’s penchant for bilateralism and the EU’s role as an active promoter of international regionalism all affect these collective LA projects. Thus, this paper does not just aim to study regionalism in a comparative way but also to situate it in its links with international relations (IR). The article is structured in three parts. The first aims to study the structural nature of regionalism in LA. To do so, a comparative analysis of the different regional initiatives is suggested, plus a look at the impact from outside factors and actors. This approach will also allow us to bring out the similarities and differences between the different waves of regionalism, to understand what has been achieved and the lessons learnt from old projects in order to better grasp the specificity and nature of current regional initiatives. Our last point will focus on the implications of LA and global geopolitical changes for the new regionalism in LA. [less ▲]

Detailed reference viewed: 22 (3 ULg)
Full Text
Peer Reviewed
See detailCase studies of incorporation of prior information in electrical resistivity tomography: comparison of different approaches
Caterina, David; Hermans, Thomas ULg; Nguyen, Frédéric ULg

in Near Surface Geophysics (2014), 12(4), 451-465

Many geophysical inverse problems are ill-posed and their solution non-unique. It is thus important to reduce the amount of mathematical solutions to more geologically plausible models by regularizing the ... [more ▼]

Many geophysical inverse problems are ill-posed and their solution non-unique. It is thus important to reduce the amount of mathematical solutions to more geologically plausible models by regularizing the inverse problem and incorporating all available prior information in the inversion process. We compare three different ways to incorporate prior information for electrical resistivity tomography (ERT): using a simple reference model or adding structural constraints to Occam's inversion and using geostatistical constraints. We made the comparison on four real cases representing different field applications in terms of scales of investigation and level of heterogeneities. In those cases, when electromagnetic logging data are available in boreholes to control the solution, it appears that incorporating prior information clearly improves the correspondence with logging data compared to the standard smoothness constrain. However, the way to incorporate it may have a major impact on the solution. A reference model can often be used to constrain the inversion; however, it can lead to misinterpretation if its weight is too strong or the resistivity values inappropriate. When the computation of the vertical and/or horizontal correlation length is possible, the geostatistical inversion gives reliable results everywhere in the section. However, adding geostatistical constraints can be difficult when there is not enough data to compute correlation lengths. When a known limit between two layers exists, the use of structural constrain seems to be more indicated particularly when the limit is located in zones of low sensitivity for ERT. This work should help interpreters to include their prior information directly into the inversion process through an appropriate way. [less ▲]

Detailed reference viewed: 54 (30 ULg)
Full Text
See detailCrop association to improve aphid biological control
Chevalier Mendes Lopes, Thomas ULg; Bodson, Bernard ULg; Francis, Frédéric ULg

Poster (2014, August)

This research focused on the development of sustainable alternative methods to control aphids, giving special emphasis on cultural practices and plant management systems. Increasing the diversity within ... [more ▼]

This research focused on the development of sustainable alternative methods to control aphids, giving special emphasis on cultural practices and plant management systems. Increasing the diversity within crops may have several beneficial effects on pest control, creating attractive habitats for indigenous beneficial fauna and simultaneously deterring pests (“push-pull” approach). In this field study, two wheat/pea associations (mixed cropping and strip cropping) where compared to monocultures of pea and wheat. The abundance and diversity of adult aphidophagous beneficials (predators and parasitoids) were accessed weekly, using yellow traps, while aphids were observed directly on plants. All individuals were identified down to the level of species. In both crops, the percentage of aphid infestation and density of colonies were significantly higher in monocultures during the abundance periods. The mixing was particularly beneficial for the pea, while strip cropping was more efficient for the wheat. Concerning beneficials, their abundance was also significantly higher in monocultures, comparing with the other treatments. This study shows that increasing diversity within crops can prevent them from aphid infestations. However, additional methods are needed to attract more efficiently the aphidophagous beneficials, in order to promote the natural control of aphids. [less ▲]

Detailed reference viewed: 13 (3 ULg)
Full Text
See detailRevision of the tabulated methods of EN1992-1-2 for concrete columns in fire - Part 1
Gernay, Thomas ULg; Franssen, Jean-Marc ULg

Report (2014)

This report presents the results of numerical simulations conducted on reinforced concrete columns in fire for comparison of the computed fire resistance with the fire resistance obtained by the tabulated ... [more ▼]

This report presents the results of numerical simulations conducted on reinforced concrete columns in fire for comparison of the computed fire resistance with the fire resistance obtained by the tabulated methods of EN1992-1-2. The data for the studied RC columns have been provided by the CTICM in the document “CENTC250-SC2-WG1-TG5_N0037_Annex_C_studies_Jesper_Jensen”. This study is part of the research project CEN-TC250-SC2-WG1-TG5. The objective is to assess the validity of and possibly to revise the tabulated methods of EN1992-1-2. The numerical software that is used for the simulations is the non-linear finite element software SAFIR, version 2013a0. [less ▲]

Detailed reference viewed: 5 (1 ULg)
Full Text
See detailRevision of the tabulated methods of EN1992-1-2 for concrete columns in fire - Part 2
Gernay, Thomas ULg; Franssen, Jean-Marc ULg

Report (2014)

This report presents the results of numerical simulations conducted on reinforced concrete columns in fire for comparison of the computed fire resistance with the fire resistance obtained by the tabulated ... [more ▼]

This report presents the results of numerical simulations conducted on reinforced concrete columns in fire for comparison of the computed fire resistance with the fire resistance obtained by the tabulated methods of EN1992-1-2. The data for the studied RC columns have been provided by the CTICM in the document “CENTC250-SC2-WG1-TG5_N0038_Column_Calculation”. This study is part of the research project CEN-TC250-SC2-WG1-TG5. The objective is to assess the validity of and possibly to revise the tabulated methods of EN1992-1-2. The numerical software that is used for the simulations is the non-linear finite element software SAFIR, version 2013a0. [less ▲]

Detailed reference viewed: 5 (0 ULg)
Full Text
Peer Reviewed
See detailScalar triplet flavored leptogenesis: a systematic approach
Aristizabal Sierra, Diego ULg; Dhen, Mikael; Hambye, Thomas

in Journal of Cosmology and Astroparticle Physics [= JCAP] (2014), 2014

Type-II seesaw is a simple scenario in which Majorana neutrino masses are generated by the exchange of a heavy scalar electroweak triplet. When endowed with additional heavy fields, such as right-handed ... [more ▼]

Type-II seesaw is a simple scenario in which Majorana neutrino masses are generated by the exchange of a heavy scalar electroweak triplet. When endowed with additional heavy fields, such as right-handed neutrinos or extra triplets, it also provides a compelling framework for baryogenesis via leptogenesis. We derive in this context the full network of Boltzmann equations for studying leptogenesis in the flavored regime. To this end we determine the relations which hold among the chemical potentials of the various particle species in the thermal bath. This takes into account the standard model Yukawa interactions of both leptons and quarks as well as sphaleron processes which, depending on the temperature, may be classified as faster or slower than the Universe Hubble expansion. We find that when leptogenesis is enabled by the presence of an extra triplet, lepton flavor effects allow the production of the B-L asymmetry through lepton number conserving CP asymmetries. This scenario becomes dominant as soon as the triplets couple more to leptons than to standard model scalar doublets. In this case, the way the B-L asymmetry is created through flavor effects is novel: instead of invoking the effect of L-violating inverse decays faster than the Hubble rate, it involves the effect of L-violating inverse decays slower than the Hubble rate. We also analyze the more general situation where lepton number violating CP asymmetries are present and actively participate in the generation of the B-L asymmetry, pointing out that as long as L-violating triplet decays are still in thermal equilibrium when the triplet gauge scattering processes decouple, flavor effects can be striking, allowing to avoid all washout suppression effects from seesaw interactions. In this case the amount of B-L asymmetry produced is limited only by a universal gauge suppression effect, which nevertheless goes away for large triplet decay rates. [less ▲]

Detailed reference viewed: 13 (1 ULg)
Full Text
Peer Reviewed
See detailA Remark on the Poroelastic Center of Dilation
Huynen, Alexandre ULg; Detournay, Emmanuel

in Journal of Elasticity (2014), 116(2), 189-206

In the original derivation due to Dougall (1897), the center of dilation is constructed from the superposition of orthogonal force dipoles. However, it can also be built by combining dislocation dipoles ... [more ▼]

In the original derivation due to Dougall (1897), the center of dilation is constructed from the superposition of orthogonal force dipoles. However, it can also be built by combining dislocation dipoles. While the two representations are equivalent in elasticity, the different nature of the force and dislocation dipoles leads to different transient behaviors in poroelasticity, when the response evolves from undrained to drained. Indeed, we show that the poroelastic solution of a center of dilation is obtained by superposing the corresponding elastic solution and either an instantaneous fluid sink or an instantaneous fluid source, depending on whether the center of dilation is treated as a singular stress or displacement discontinuity. A simple explanation to the instantaneous injection or withdrawal of a finite volume of fluid from/to the singularity is given by adopting an exploded view of the poroelastic center of dilation. The exploration of the drained, undrained and transient responses of this singularity also requires to clarify the close relationship between an instantaneous fluid source and a continuous fluid dodecapole, an object constructed by collapsing onto a point three orthogonal pairs of fluid dipoles. [less ▲]

Detailed reference viewed: 19 (5 ULg)
Full Text
Peer Reviewed
See detailEnhancement of ray tracing method for radiative heat transfer: application to EUI space instrument
Jacques, Lionel ULg; Masset, Luc ULg; Kerschen, Gaëtan ULg

in Proceedings of the 15th International Heat Transfer Conference, IHTC-15 (2014, August)

The finite element method (FEM) is widely used in mechanical engineering, in particular for space structure design. However, FEM is not yet often used for thermal engineering of space structures where the ... [more ▼]

The finite element method (FEM) is widely used in mechanical engineering, in particular for space structure design. However, FEM is not yet often used for thermal engineering of space structures where the lumped parameter method is still dominant. Radiative exchange factors (REFs), used to calculate radiative thermal exchanges in space, are usually computed through Monte Carlo ray tracing. Due to the large number of elements composing a FE model, the computation of the REFs is prohibitively expensive. The isocell method aims at reducing the computational effort of the REFs with FEM, by decreasing the number of rays required to achieve a given accuracy. Based on Nusselt’s analogy, the ray direction sampling is carried out by sampling the unit disc to derive the ray directions. The isocell method is a special case of stratified sampling. It divides the unit disc into cells of almost same area and shape from which random points are generated. This enhances the uniformity of the ray directions and leads to faster convergence. This isocell method is associated with different surface sampling to derive the REFs. The method is benchmarked against ESARAD, the standard thermal analysis ray tracing engine used in the European aerospace industry. One entrance baffle of the Extreme Ultraviolet Imager (EUI) instrument developedat the Centre Spatial de Liège in Belgium is used as benchmarking case. Solar Orbiter is an European Space Agency mission to be launched in a Sun-centered 0.28 perihelion orbit. [less ▲]

Detailed reference viewed: 25 (6 ULg)
Full Text
Peer Reviewed
See detailThe role of segmentation and investor recognition through the lens of cross-listing activity
Mouchette, Xavier ULg; Muller, Aline ULg; Carrieri, Francesca

Conference (2014, August)

Detailed reference viewed: 10 (1 ULg)
Full Text
See detailThe Semiotic Challenge of Scientific Images. A Test Case for Visual Meaning
Dondero, Maria Giulia ULg; Fontanille, Jacques; Tabler, Julie

Book published by Legas Publishing (2014)

This book is intended to answer the question "What role and impact do images have in scientific research?". In these pages, scientific images are explored as experimental devices (in laboratories), as ... [more ▼]

This book is intended to answer the question "What role and impact do images have in scientific research?". In these pages, scientific images are explored as experimental devices (in laboratories), as instruments of proof (in mathematical logic), as argumentation (in dissemination literature), and in their interactions with other fields, like art and aesthetics. Epistemologists and language scientists will find methodologies that can be used to study the relation between images and knowledge; and scientific imaging experts will find their visualization practices being questioned in all their unique aspects. [less ▲]

Detailed reference viewed: 9 (0 ULg)
Full Text
Peer Reviewed
See detailHow to correctly determine the kinetics of a photocatalytic degradation reaction?
Pirard, Sophie ULg; Malengreaux, Charline ULg; Toye, Dominique ULg et al

in Chemical Engineering Journal (2014), 249

Detailed reference viewed: 17 (5 ULg)