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See detailConversion of visual post fire measurements into fire severity with the aid of thermo-plastic analysis for retrofitting
Molkens, Tom; Gernay, Thomas ULg; Van Coile, Ruben

in Proceedings of the 9th International Conference on Structures in Fire (2016, June 09)

At Koksijde in Belgium a severe fire took place in an apartment building in 2015, resulting in the death of a young man and visible structural damage to four balconies. Following the fire, experts were ... [more ▼]

At Koksijde in Belgium a severe fire took place in an apartment building in 2015, resulting in the death of a young man and visible structural damage to four balconies. Following the fire, experts were mandated to assess the damage and the need for structural repair. They estimated that the balconies had to be refurbished but that there were no other structural elements affected, in particular the slab inside the apartment could be left in place with only a surface treatment and new plaster finishing. However, the floor slab in the apartment located above the fire apartment exhibited several visual indications that the fire could have had a structural impact, such as residual deformations and cracks in the tiles. This paper presents a methodology to infer the fire severity based on post-fire measurements and non-linear thermo-plastic numerical simulations. Finally, knowing the fire severity, its effect on the structure is evaluated and a reliability-based assessment is made of the residual load bearing capacity of the slab. [less ▲]

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See detailCritical parameters in deriving fire fragility functions for steel gravity frames
Gernay, Thomas ULg; Elhami Khorasani, Negar; Garlock, Maria

in Proceedings of the 9th International Conference on Structures in Fire (2016, June 08)

Fire fragility functions can be used to characterize the probabilistic vulnerability of buildings to fire in the context of urban resilience assessment. A methodology has been proposed to develop such ... [more ▼]

Fire fragility functions can be used to characterize the probabilistic vulnerability of buildings to fire in the context of urban resilience assessment. A methodology has been proposed to develop such functions for multi-story steel buildings. However, a large number of parameters with uncertainties play a role in the process of constructing the fragility functions. The goal of this research is to identify the critical parameters that most affect the global fire safety by investigating the sensitivity of the fragility functions to different input parameters. Sensitivity in parameters affecting the fire model, the heat transfer process and the thermo-mechanical response is examined. The effects of different design assumptions at the system level are also studied. The presented approach is useful for selecting the prevailing parameters in a fire reliability analysis and it provides important information for modeling tools that can be used to evaluate resilience for fire scenarios. [less ▲]

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See detailFire Resistance of Reinforced Concrete Columns Subjected to Standard Fire – Comparison of an Advanced and a Simplified Method
Achenbach, Marcus; Gernay, Thomas ULg; Morgenthal, Guido

in Proceedings of the 9th International Conference on Structures in Fire (2016, June 08)

For designing concrete columns subjected to a standard fire exposure, the Eurocode permits the use of simplified or advanced calculation methods. For the designer, the question of the respective ... [more ▼]

For designing concrete columns subjected to a standard fire exposure, the Eurocode permits the use of simplified or advanced calculation methods. For the designer, the question of the respective advantages of these two types of methods arises. Which situations demand the use of an advanced method? When does a simple method provide sufficient accuracy? In this paper, laboratory tests are recalculated using Finite Element Modeling (FEM) as an advanced and Extended Zone Model (EZM) as a simple method in order to investigate these questions. The recalculations indicate that the simple EZM is of sufficient accuracy for symmetric heated columns without restraints. In contrast, the mechanical behavior of columns heated on three sides demands an advanced method such as FEM to be properly described. [less ▲]

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See detailTowards a standard measure of the ability of a structure to resist a natural fire
Gernay, Thomas ULg; Franssen, Jean-Marc ULg

in Proceedings of the 9th International Conference on Structures in Fire (2016, June 08)

Fire brigades face a major threat when intervening in a building in fire: the possibility of structural collapse during the cooling phase of the fire, or soon thereafter. In the current approaches to ... [more ▼]

Fire brigades face a major threat when intervening in a building in fire: the possibility of structural collapse during the cooling phase of the fire, or soon thereafter. In the current approaches to structural fire engineering, the fire resistance rating (R) is generally the only measure taken into consideration to characterize the fire performance of structural elements, although this measure does not reflect the response in real fire conditions. In this work, a standard measure is proposed to characterize the ability of structural members to resist a natural fire including the decay phases. This measure yields information about the potential occurrence of delayed failure as a function of the duration of the fire before it started to decrease, whether by self-extinction or due to the action of the fire fighters. The paper presents the method to derive this new standard measure as well as results for different typologies of structural elements. Finally, the interpretation and practical consequences are discussed, in particular regarding the safety of fire fighters during an intervention. [less ▲]

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See detailFire fragility functions for community resilience assessment
Elhami Khorasani, Negar; Gernay, Thomas ULg; Garlock, Maria

in Proceedings of the 9th International Conference on Structures in Fire (2016, June 08)

This work provides a framework to evaluate the response of buildings in a community to fire following earthquake. As part of the framework, the paper discusses two methodologies: (1) how to develop fire ... [more ▼]

This work provides a framework to evaluate the response of buildings in a community to fire following earthquake. As part of the framework, the paper discusses two methodologies: (1) how to develop fire fragility functions; (2) how the fire fragility functions can be used in conjunction with an original fire ignition model to estimate the potential losses in a community from fire following earthquake. The paper focuses in particular on the development of fire fragility functions for an entire building to measure the probability of reaching a damage state given a fire scenario. Next, the paper proposes an ignition model to evaluate the probability of fire ignition after an earthquake. The ignition model together with fragility functions measure the probability of damage from fire following earthquake given an earthquake scenario. [less ▲]

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See detailStability in Hybrid Fire Testing
Sauca, Ana ULg; Gernay, Thomas ULg; Robert, Fabienne et al

in Proceedings of the 9th International Conference on Structures in Fire (2016, June 08)

Hybrid testing is an appealing technique to observe the behavior of an element in an experimental test while taking into account the interaction with the rest of the structure which is modelled ... [more ▼]

Hybrid testing is an appealing technique to observe the behavior of an element in an experimental test while taking into account the interaction with the rest of the structure which is modelled numerically. Being widely used in the seismic field, this technique has been recently proposed in the fire field. The purpose of this paper is to demonstrate that the loading control process may be unstable during the hybrid testing when using the methodology applied in former tests presented in the literature. The stability in the latter method depends on the stiffness ratio between the two substructures. For the purpose of discussion, a one degree-of-freedom elastic system is studied. To overcome the stability issues, a new method is presented, independent on the stiffness ratio. Finally, the hybrid testing of a 2D beam being part of a moment resisting frame is analyzed in a virtual environment (both parts being modeled numerically) using the “first generation method” and the new proposed method. [less ▲]

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See detailMOISTURE CONTENT DETERMINATION OF FREEZE-DRIED PRODUCTS BY NEAR-INFRARED SPECTROSCOPY: A CASE STUDY FOR UNIVERSAL REGRESSION MODEL
Clavaud, Matthieu ULg; Roggo, Yves; Degardin, Klara et al

Poster (2016, June 06)

Karl Fischer titration is the reference method for moisture content determination in the pharmaceutical industry. Near-infrared spectroscopy is considered the most suitable alternative technique. Indeed ... [more ▼]

Karl Fischer titration is the reference method for moisture content determination in the pharmaceutical industry. Near-infrared spectroscopy is considered the most suitable alternative technique. Indeed, NIRS is a safe and fast method which does not require sample preparation. Nevertheless, the development and validation phases are time-consuming. In addition, the NIRS methods presented so far were mostly product specific. The main objective of this study is to highlight that an universal calibration model can be validated for several freeze-dried products in order to speed up the validation time. This objective was led in two steps. A universal model was first evaluated. A calibration set and a validation set were built up with three freeze-dried products. An antibody drug conjugate, a large molecule and a small molecule all packed in sealed vials were used to introduce more variability. Regression methods were then compared in order to optimize the prediction values. [less ▲]

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See detailScreening study of SFC critical method parameters for the determination of pharmaceutical compounds
Dispas, Amandine ULg; Lebrun, Pierre ULg; Sacre, Pierre-Yves ULg et al

in Journal of Pharmaceutical & Biomedical Analysis (2016), 125

Nowadays, supercritical fluid chromatography is commonly presented as a promising alternative technique in the field of separation sciences. Nevertheless the selection of chromatographic conditions and ... [more ▼]

Nowadays, supercritical fluid chromatography is commonly presented as a promising alternative technique in the field of separation sciences. Nevertheless the selection of chromatographic conditions and sample preparation of pharmaceutical compounds remain a challenge and peak distortion was previously highlighted. The main objective of the present work was to evaluate the impact of different critical method parameters (CMPs), i.e. stationary phase, mobile phase composition and injection solvent nature. The experiments were performed considering two groups of antimalarial molecules: one group with neutral/apolar compounds and the other one with salt form of polar compounds. In this context, another objective was to propose a suitable sample solvent for quantitative analysis. The interest of new generation stationary phase to obtain good peak shape and the interest to tune the mobile phase composition were demonstrated. During this study, design of experiments and desirability function approach enabled to highlight optimal chromatographic conditions in order to maximise peak capacity and to get acceptable value of symmetry factor. Regarding sample injection solvent composition, some counterintuitive results were observed: solvents closer to the mobile phase polarity (i.e heptane or 2-propanol/heptane mixture) did not provide best results in terms of peak symmetry. In addition, acetonitrile and short aliphatic alcohols offered an interesting alternative as injection solvent: toxicity of solvents used is clearly reduced and better quantitative performances could be expected while keeping high peak capacity and symmetric sharp peaks. Finally, the quantitative performances were evaluated by the method validation for the quantitative determination of quinine sulfate in a pharmaceutical formulation. These better understandings on critical method parameters led SFC to be an even more promising technique in the field of the analysis of pharmaceutical compounds. [less ▲]

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See detailLe gisement paléolithique multistratifié d'Ormesson (Seine-et-Marne) : Palethnologie ou pâle ethnologie ?
Bodu, Pierre; Ballinger, Michèle; Dumarçay, Gaëlle et al

Conference (2016, June 01)

Il est exceptionnel de pouvoir appliquer la démarche palethnologique, si fréquemment développée pour le Magdalénien, aux gisement du Paléolithique supérieur ancien dans le Bassin parisien, dans la mesure ... [more ▼]

Il est exceptionnel de pouvoir appliquer la démarche palethnologique, si fréquemment développée pour le Magdalénien, aux gisement du Paléolithique supérieur ancien dans le Bassin parisien, dans la mesure où ils sont rares, c'est indéniable, mais aussi en raison d'un état de conservation généralement médiocre de la plupart d'entre eux. Le site d'Ormesson, situé en Seine-et-Marne, à proximité de la vallée du Loing et de la ville de Nemours, constitue depuis 2009, année de la première fouille, un gisement-laboratoire pour l'approche palethnographique de différentes populations de la fin du Paléolithique moyen au Badegoulien. A travers cet exemple devenu désormais une référence pour le Paléolithique supérieur ancien, nous nous poserons la question suivante : Palethnologie ou pâle ethnologie ? [less ▲]

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See detailAn Exact Method for Designing Shewhart X ̅ and S2 Control Charts to Guarantee the In-Control Performance
Faraz, Alireza ULg; Heuchenne, Cédric ULg

in Journal of Quality Technology (2016)

The in-control performance of the Shewhart X ̅ and S2 control charts with estimated in-control parameters has been evaluated by a number of authors. Results indicate an unrealistically large amount of ... [more ▼]

The in-control performance of the Shewhart X ̅ and S2 control charts with estimated in-control parameters has been evaluated by a number of authors. Results indicate an unrealistically large amount of Phase I data is needed to have the desired in-control average run length (ARL) value in Phase II. To overcome this problem, it has been recommended that the control limits be adjusted based on a bootstrap method to guarantee that the in-control ARL is at least a specified value with a certain specified probability. In our paper we present simple formulas for the required control limits so that practitioners do not have to use the bootstrap method. An assumption of normality is required. The advantage of our proposed method is in its simplicity; there is no bootstrapping and the control chart constants do not depend on the Phase I sample data. [less ▲]

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See detailL'Année sartrienne, n° 30
Cormann, Grégory ULg

Book published by GES (2016)

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See detailLaboratory idenification of anaerobic bacteria isolated on Clostridium difficile selective medium
Rodriguez Diaz, Cristina ULg; Warszawski, Nathalie; Korsak Koulagenko, Nicolas ULg et al

in Acta Microbiologica et Immunologica Hungarica (2016)

Despite increasing interest in the bacterium, the methodology for Clostridium difficile recovery has not yet been standardised. Cycloserine cefoxitin fructose taurocholate (CCFT) has historically been the ... [more ▼]

Despite increasing interest in the bacterium, the methodology for Clostridium difficile recovery has not yet been standardised. Cycloserine cefoxitin fructose taurocholate (CCFT) has historically been the most used medium for C. difficile isolation from human, animal, environmental and food samples, and presumptive identification is usually based on colony morphologies. However, CCFT is not totally selective. This study describes the recovery of 24 bacteria species belonging to 10 different genera other than C. difficile, present in the environment and foods of a retirement establishment that were not inhibited in the C. difficile selective medium. These findings provide insight for further environmental and food studies as well as for isolation of C. difficile on supplemented CCFT. [less ▲]

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See detailDoes sector-specific experience matter? The case of European higher education ministers
Jacqmin, Julien ULg; Lefebvre, Mathieu ULg

in Research Policy (2016), 45(5), 987998

This paper looks at the relationship between higher education ministers and the performance of the sector that they govern. Using an original panel dataset with the characteristics of European higher ... [more ▼]

This paper looks at the relationship between higher education ministers and the performance of the sector that they govern. Using an original panel dataset with the characteristics of European higher education ministers, we find that having a past experience in the sector leads to a higher level of performance, as measured by ranking data. Making a parallel with the literature about the impact of education on the educated, we discuss potential explanations behind the impact of this on-the-job learning experience. As we find that this characteristic has no impact on the spendings of the sector, we argue that this academic experience makes them more prone to introduce adequate reforms that makes the sector more attractive for top-researchers. Furthermore, we find that this result is driven by ministers with both sector-specific and electoral experience, the latter measured by a successful election at the regional or national level. This tends to show that political credibility should not be overshadowed by the importance of the sector-specific experience of ministers. [less ▲]

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See detailDelivering Bad News to Customers: An Employee Perspective
Delcourt, Cécile ULg; Gremler, Dwayne; Greer, Dominique

in Conferences proceedings of SERVSIG 2016 (2016, June)

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See detailWelfare and the creation of Undocumented EU migrants in Belgium
Mescoli, Elsa ULg; Lafleur, Jean-Michel ULg

Conference (2016, June)

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See detailThe influence of customer characteristics on the customer need knowledge of frontline employees
Hüttel, Björn; Schumann, Jan Hendrik; Büttgen, Marion et al

Conference (2016, June)

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See detailExplaining the diversity of motivations behind community renewable energy
Bauwens, Thomas ULg

in Energy Policy (2016), 93

Community-based renewable energy initiatives may be important actors in the transition toward low-carbon energy systems. In turn, stimulating investments in renewable energy production at the community ... [more ▼]

Community-based renewable energy initiatives may be important actors in the transition toward low-carbon energy systems. In turn, stimulating investments in renewable energy production at the community level requires a better understanding of investors’ motives. This paper aims to study the heterogeneity of motivations that drive individuals to participate in community renewable energy projects and the underlying explanatory factors behind this, as well as the implications for their level of engagement in initiatives. Based on quantitative data from an original survey conducted with two renewable energy cooperatives in Flanders, the statistical analysis shows that cooperative members should not be considered as one homogeneous group. Several categories of members with different motives and levels of engagement can be distinguished. This heterogeneity is explained by contrasts in terms of institutional settings, spatial patterns and attitudes to the diffusion of institutional innovations. Regarding policy implications, the findings suggest that this heterogeneity should be taken into account in designing more effective supporting policies to stimulate investments at the community level. The activation of social norms is also shown to be a promising mechanism for triggering investment decisions, although the implications of its interplay with economic incentives should be further explored. [less ▲]

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See detailPolyphosphoesters as a new platform for the design of particulate drug delivery systems
Vanslambrouck, Stéphanie; Ergul Yilmaz, Zeynep; Debuigne, Antoine ULg et al

Conference (2016, June)

Thanks to their biocompatibility and degradability properties, polyphosphates are appealing polymers for biomedical applications. In contrast to aliphatic polyesters, such as poly(ε-caprolactone) and poly ... [more ▼]

Thanks to their biocompatibility and degradability properties, polyphosphates are appealing polymers for biomedical applications. In contrast to aliphatic polyesters, such as poly(ε-caprolactone) and poly(lactide), the pentavalency of the phosphorus atom allows the easy modification of the polyphosphate properties by simply adjusting the nature, the length and the functionality of the polyphosphate pendant groups. Therefore, macromolecular engineering of polyphosphoesters was applied to design well-defined architectures and functionalities adapted to drug nanocarriers. In a first approach, amphiphilic block copolymers are synthesized by organo-catalyzed ring-opening polymerization process for the synthesis of a range of PEO-b-polyphosphate bearing various pendant groups. Post-polymerization thiol-ene click reactions preformed on PEO-b-polyphosphate copolymers was also investigated to improve the hydrophobicity of the polyphosphate. The self-assembly of these PEO-b-polyphosphate copolymers into micelles was investigated, particularly, the effect of the nature of the polyphosphate pendant groups (i) on the micelles characteristics, (ii) on the encapsulation of a poorly soluble drug and (iii) on the drug release profile. The toxicity of the different amphiphilic block copolymers was also evaluated by live/dead cell viability assays. In a second approach, double hydrophilic copolymers based on polyphosphoesters have been used as templating agent for the synthesis of calcium carbonate particles. Indeed, the use of such microparticles is becoming more and more attractive in many fields especially for biomedical applications for which fine tuning of size, morphology and crystalline form of CaCO3 particles is crucial. Although some structuring compounds, like hyaluronic acid, give satisfying results, the control of the particle structure still has to be improved. To this end, we evaluated the CaCO3 structuring capacity of the well-defined double hydrophilic block copolymers composed of poly(ethylene oxide) and of a polyphosphoester segment with affinity for calcium like poly(phosphotriester)s bearing pendant carboxylic acids or poly(phosphodiester)s with a negatively charged oxygen atom on each repeating monomer unit. [less ▲]

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See detailCaractérisation des forêts à l’aide de la technologie lidar
Michez, Adrien ULg; Bauwens, Sébastien ULg; Bonnet, Stéphanie ULg et al

in Baghdadi, Nicolas; Zribi, Mehrez (Eds.) Observation des Surfaces Continentales par Télédétection: Agriculture et Forêt (2016)

Detailed reference viewed: 37 (18 ULg)