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See detailDirect route to well-defined poly(ionic liquid)s by controlled radical polymerization in water
Cordella, Daniela ULg; Kermagoret, Anthony ULg; Debuigne, Antoine ULg et al

in ACS Macro Letters (2014), 3

The precision synthesis of poly(ionic liquid)s (PILs) in water is achieved for the first time by the cobalt-mediated radical polymerization (CMRP) of N-vinyl-3-alkylimidazolium-type monomers following two ... [more ▼]

The precision synthesis of poly(ionic liquid)s (PILs) in water is achieved for the first time by the cobalt-mediated radical polymerization (CMRP) of N-vinyl-3-alkylimidazolium-type monomers following two distinct protocols. The first involves the CMRP of various 1-vinyl-3-alkylimidazolium bromides conducted in water in the presence of an alkyl–cobalt(III) complex acting as a monocomponent initiator and mediating agent. Excellent control over molar mass and dispersity is achieved at 30 °C. Polymerizations are complete in a few hours, and PIL chain-end fidelity is demonstrated up to high monomer conversions. The second route uses the commercially available bis(acetylacetonato)cobalt(II) (Co(acac)2) in conjunction with a simple hydroperoxide initiator (tert-butyl hydroperoxide) at 30, 40, and 50 °C in water, facilitating the scaling-up of the technology. Both routes prove robust and straightforward, opening new perspectives onto the tailored synthesis of PILs under mild experimental conditions in water. [less ▲]

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See detailEtude de la flore spontanée de la carrière de Loën pour de futures restaurations - Résultats
Pitz, Carline ULg; Mahy, Grégory ULg; Monty, Arnaud ULg et al

Conference given outside the academic context (2014)

Ce projet a pour objectif de caractériser la flore recolonisant spontanément les zones xériques non exploitées récemment de la carrière de Loën, du point de vue de la diversité spécifique et de la ... [more ▼]

Ce projet a pour objectif de caractériser la flore recolonisant spontanément les zones xériques non exploitées récemment de la carrière de Loën, du point de vue de la diversité spécifique et de la fonctionnalité écologique. Les communautés végétales ont été caractérisées au sein du site de Loën (diversité alpha) et d’un ensemble d’autres carrières représentatives de la diversité des contextes géographiques des carrières calcaires en Région Wallonne (diversité béta). L’étude a montré que, sur des laps de temps de plusieurs décennies, un processus de succession écologique s’est mis en place au sein du site de Loën, mais que cette succession ne tend pas vers une formation typique de pelouse sèche. Les explications peuvent être d’une part, que la disponibilité et l’apport de graines de pelouses sèches avoisinantes est insuffisant, et d’autre part, que le contexte abiotique pourrait être plus favorable à d’autres types de végétations herbacées. Cette étude illustre que des expériences de semis seraient souhaitable afin de définir les objectifs de restauration de la carrière de Loën et des carrières qui se trouvent dans des situations comparables. [less ▲]

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See detailFirst-line crizotinib versus chemotherapy in ALK-positive lung cancer.
Solomon, Benjamin J.; Mok, Tony; Kim, Dong-Wan et al

in The New England journal of medicine (2014), 371(23), 2167-77

BACKGROUND: The efficacy of the ALK inhibitor crizotinib as compared with standard chemotherapy as first-line treatment for advanced ALK-positive non-small-cell lung cancer (NSCLC) is unknown. METHODS: We ... [more ▼]

BACKGROUND: The efficacy of the ALK inhibitor crizotinib as compared with standard chemotherapy as first-line treatment for advanced ALK-positive non-small-cell lung cancer (NSCLC) is unknown. METHODS: We conducted an open-label, phase 3 trial comparing crizotinib with chemotherapy in 343 patients with advanced ALK-positive nonsquamous NSCLC who had received no previous systemic treatment for advanced disease. Patients were randomly assigned to receive oral crizotinib at a dose of 250 mg twice daily or to receive intravenous chemotherapy (pemetrexed, 500 mg per square meter of body-surface area, plus either cisplatin, 75 mg per square meter, or carboplatin, target area under the curve of 5 to 6 mg per milliliter per minute) every 3 weeks for up to six cycles. Crossover to crizotinib treatment after disease progression was permitted for patients receiving chemotherapy. The primary end point was progression-free survival as assessed by independent radiologic review. RESULTS: Progression-free survival was significantly longer with crizotinib than with chemotherapy (median, 10.9 months vs. 7.0 months; hazard ratio for progression or death with crizotinib, 0.45; 95% confidence interval [CI], 0.35 to 0.60; P<0.001). Objective response rates were 74% and 45%, respectively (P<0.001). Median overall survival was not reached in either group (hazard ratio for death with crizotinib, 0.82; 95% CI, 0.54 to 1.26; P=0.36); the probability of 1-year survival was 84% with crizotinib and 79% with chemotherapy. The most common adverse events with crizotinib were vision disorders, diarrhea, nausea, and edema, and the most common events with chemotherapy were nausea, fatigue, vomiting, and decreased appetite. As compared with chemotherapy, crizotinib was associated with greater reduction in lung cancer symptoms and greater improvement in quality of life. CONCLUSIONS: Crizotinib was superior to standard first-line pemetrexed-plus-platinum chemotherapy in patients with previously untreated advanced ALK-positive NSCLC. (Funded by Pfizer; PROFILE 1014 ClinicalTrials.gov number, NCT01154140.). [less ▲]

Detailed reference viewed: 11 (1 ULg)
See detailPropriété immobilière et superficie
Lecocq, Pascale ULg

Scientific conference (2014, December 04)

Modification de la loi du 10 janvier 1824 en matière de superficie et question des volumes

Detailed reference viewed: 19 (1 ULg)
See detailTrophic connectivity between two ecosystems: supplies of kelp litter to coastal soft substrata
Vandenbosch, François; Davoult, Dominique; Dauby, Patrick ULg et al

Scientific conference (2014, December 04)

Detailed reference viewed: 6 (0 ULg)
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See detailUne nouvelle menace pour la couche d'ozone ?
Franco, Bruno ULg

Scientific conference (2014, December 04)

Detailed reference viewed: 9 (0 ULg)
See detailAvril 1917. Oncle Sam sur le pied de guerre
Genin, Vincent ULg

Article for general public (2014)

Detailed reference viewed: 25 (0 ULg)
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See detailOutline of ULg chemical sensors applications for IAQ evaluation
Romain, Anne-Claude ULg

Conference (2014, December 04)

The arrival of the European and National laws* concerning the official labelling of building materials (CE marking) and the respect of concentration values for some compounds regulations in public ... [more ▼]

The arrival of the European and National laws* concerning the official labelling of building materials (CE marking) and the respect of concentration values for some compounds regulations in public buildings as for instance schools, the emergence of the Environmental Assessments of buildings (Breeam, HQE,…) beside the energy performance, as well as the awareness increase of the impact of indoor air quality on the wellness and health (ie ENVIE and Healthvent projects [1]) lead inevitably to the development of new sensing technologies related to the IAQ evaluation. Among the numerous existing measurement devices, electrochemical cells, NDIR and PID ones are the most encountered sensors on the market. The major uses are real time monitoring (CO2) and “friendly” handheld devices. Other applications are also studied in several research labs. Few years ago, the ULg research team investigated the interest of MOS chemical sensors arrays for IAQ evaluation. This presentation aims to review some of the results of those projects. A first is the fast and simple diagnosis of moulds on building materials. The identification of contaminated materials among uncontaminated ones was successful [2-4]. However, the low concentration of the MVOC markers compounds (below 10 µg/m³) and the complexity of the background (material emissions, and VOC content of the indoor air) curbed the use of MOS sensors. Specific preconcentrations have to be developed to improve the diagnosis. Nowadays, with the emergence of new sensing materials and new measurement principles (eg IMS-ion mobility spectrometry [5]), perspectives are again opened. Another project (HEMICPD, Belgian project “Horizontal evaluation method for the implementation of the Construction Products Directive”-Emissions to indoor air [6]) concerned the marking of building materials and one of the tasks was to test the sensors array principle to monitor the compounds emanation from different building material, during 28 days, in emission test chambers. Another goal was to investigate a classification of the materials including their odour level. The results on the use of sensors to evaluate the efficiency of “masking” products pulverised in wallpapers and to manage their use are also explained. [less ▲]

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See detailjob day ulg
Bruyère, Eric ULg

Diverse speeche and writing (2014)

Detailed reference viewed: 22 (0 ULg)
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See detailAdvances in proteomics for the FP7 Venomics project
Degueldre, Michel ULg; Quinton, Loïc ULg; De Pauw, Edwin ULg

Conference (2014, December 03)

Detailed reference viewed: 6 (0 ULg)
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See detailFirst principles study of the structural, electronic and thermoelectric properties of misfit cobaltite
Lemal, Sébastien ULg; Varignon, Julien ULg; Bilc, Daniel ULg et al

Poster (2014, December 03)

In the context of environmental issues that become more and more prevalent in our society, there has been recently an increase of interest for thermoelectric (TE) materials, which have the property to ... [more ▼]

In the context of environmental issues that become more and more prevalent in our society, there has been recently an increase of interest for thermoelectric (TE) materials, which have the property to convert heat into electricity, and vice-versa. Although they do not display exceptional thermopower (in comparison to best thermoelectric like bismuth telluride), oxide materials have attracted some attention for high-temperature TE applications, due to their high stability. Amongst them, CoO2-layered compounds were proposed as good p-type TE candidates. Still, these compounds have been only poorly characterized both theoretically and experimentally. In this work we report a first-principles study of misfit calcium cobaltite (Ca2CoO3)(CoO2)1.618 based on density functional theory and an hybrid functional. The computed structural, electronic and magnetic properties match well the avalaible experimental data. Then the thermoelectric properties can be deduced using the Boltzmann transport formalism within the constant relaxation time approximation and will be discussed. [less ▲]

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See detailDetecting microbial patterns in relation to soil agricultural practices and the plant development stage
Degrune, Florine ULg; Dufrêne, Marc ULg; Taminiau, Bernard ULg et al

Poster (2014, December 02)

Agricultural practices have a strong impact on soil bacteria and fungi. Furthermore, microbial community composition can change with the stage of plant development. We are interested in exploring these ... [more ▼]

Agricultural practices have a strong impact on soil bacteria and fungi. Furthermore, microbial community composition can change with the stage of plant development. We are interested in exploring these effects in relation to changes induced by agriculture and plant stage in soil conditions. Some bacteria are influenced only by the plant stage, which induces changes in soil humidity, pH, nitrates, and carbon. We would thus expect these bacteria to be highly sensitive to these parameters. Other bacteria are affected only by the tillage practice applied. Further study is needed to identify the soil parameters responsible for this effect. The plant stage also has a great impact on fungal community composition. [less ▲]

Detailed reference viewed: 67 (5 ULg)
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See detailPsychometrics and bibliometrics: Overview of future possible interactions
Magis, David ULg

Scientific conference (2014, December 02)

Bibliometrics is a growing research field with the main aim of collecting bibliometric information (citations, publications, awards...) to infer valuable rankings or to predict future academic performance ... [more ▼]

Bibliometrics is a growing research field with the main aim of collecting bibliometric information (citations, publications, awards...) to infer valuable rankings or to predict future academic performance. However, most bibliometric approaches are based either on pairwise comparisons of "objects" (authors, funding applications, academics...) with respect to selected "criteria" (publications, citation rate, h-index...), or on modeling observable academic outcomes using observed such criteria. The purpose of this talk is twofold. First, an improvement of the pairwise comparison approach will be outlined on the basis of so-called multicriteria decision aid (MCDA) routines, which will imply an increased flexibility and added freedom for the decision process. Second, we will start a deeper reflexion on possible connections between bibliometrics and psychometrics. Among others, the possibility of modeling latent "academic ability" as outcome of interest, given manifest criteria, will be put to an open discussion and exchange with the listeners [less ▲]

Detailed reference viewed: 27 (1 ULg)
See detailAtelier ENMG pratique membre supérieur
WANG, François-Charles ULg

Scientific conference (2014, December 02)

Detailed reference viewed: 12 (2 ULg)
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See detailMid-winter freeze experiment in the Arctic Ocean: Norwegian Young sea ICE cruise (N-ICE2015)
Nomura, Daiki; Granskog, Mats A.; Fransson, Agneta et al

Poster (2014, December 02)

In mid-January 2015, RV Lance will freeze into the ice north of Svalbard, Arctic Ocean at around 83.25°N 30°E, and passively drift with the ice as part of the Norwegian Young sea ICE cruise (N-ICE2015 ... [more ▼]

In mid-January 2015, RV Lance will freeze into the ice north of Svalbard, Arctic Ocean at around 83.25°N 30°E, and passively drift with the ice as part of the Norwegian Young sea ICE cruise (N-ICE2015). Judging from historic sea ice drift trajectories, it is likely that RV Lance will drift in a SW direction and the ship will probably be freed from the ice in mid spring after about two to three months of drift. Thereafter, RV Lance will return to her starting position and start a new drift. Under all circumstances, the ice drift project will end in late June 2015. Throughout the cruise the focus will be on the interaction of the atmosphere-ice-ocean system and the response of the marine ecosystem to the thinner ice regime. The overall goal of the project team is to improve our understanding of the role of the younger ice pack in the Arctic on greenhouse gas fluxes and to ultimately assess whether the Arctic Ocean is a sink or source of greenhouse gases. We plan to conduct long-term synchronous observations of Arctic snow and sea ice biogeochemistry and physics and fluxes of carbon dioxide, methane, nitrous oxide and bromoform. This work targets at filling a crucial gap in our understanding of the role of Arctic sea ice in the climate system. This is done by conducting state of the art observations on Arctic sea ice in the polar night, when observations are basically non-existent. Further we are focusing on the new thinner ice regime, which is even less documented. We aim to understand how the thinner sea ice in the Arctic basin contributes (i) to important greenhouse gas exchange between the atmosphere and ocean and (ii) to aerosol formation, that contribute to the radiative balance of the planet. This work will increase direct collaboration between Japanese and European scientists in the Arctic, and combines complimentary expertise and experience from several international partners to carry out the interdisciplinary work proposed. [less ▲]

Detailed reference viewed: 55 (2 ULg)