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See detailPolarization-corrected electrostatic potentials of aromatic compounds
Dehareng, Dominique ULg; Dive, Georges ULg; Ghuysen, Jean-Marie ULg

in Journal of the American Chemical Society (1993), 115(15), 6877-6882

The electrostatic potentials (EPS) corrected for polarization (TPS) of the aromatic compounds benzene, aniline, chlorobenzene, nitrobenzene, phenol, benzamide, and N-phenylacetamide have been calculated ... [more ▼]

The electrostatic potentials (EPS) corrected for polarization (TPS) of the aromatic compounds benzene, aniline, chlorobenzene, nitrobenzene, phenol, benzamide, and N-phenylacetamide have been calculated at the ab initio SCF level within three basis sets: 6-31G**, MINI-1, and STO-3G. For chlorobenzene in its MINI-1-optimized geometry, the calculation was also performed within MINI-1**. By reference to 6-31G**, the MINI-1-computed EP is much more satisfactory than the STO-3G-computed EP, whereas the MINI-I and STO-3G basis sets give very similar total potentials corrected for polarization (TPs). The MINI-1** basis set appears to be miscalibrated for computing EPs. It provides qualitative results that differ from those obtained with the 6-31G** basis set. The EP has a negative well above the middle of the benzene ring, while the TP exhibits a negative crown just above the benzene carbon atoms, where electrophilic attack takes place. The TP calculated for the interaction of nitrobenzene with a hydride ion instead of a proton allowed analyzation of the effects of polarization on the positive EP above the N-C bond. [less ▲]

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See detailAnalyse des comportements d'entraîneurs de volley-ball pendant des rencontres officielles
Cloes, Marc ULg; Delhaes, Jean-Pierre; Piéron, Maurice

in Sport (1993), 141(1), 16-25

L'observation systématique des comportements des entraîneurs sportifs a connu un réel développement au cours de la dernière décennie. Les études relevées dans la littérature spécialisée peuvent se ... [more ▼]

L'observation systématique des comportements des entraîneurs sportifs a connu un réel développement au cours de la dernière décennie. Les études relevées dans la littérature spécialisée peuvent se regrouper selon leurs objectifs: (1) l'analyse descriptive des comportements d'entraîneurs et de sportifs, parfois de très haut niveau; (2) la comparaison de situations pédagogiques, notamment en observant une même personne exerçant les fonctions d'entraîner et d'enseignant; (3) la comparaison des interventions des entraîneurs en fonction du niveau d'habileté des sportifs qu'ils dirigent; (4) la comparaison du comportement des entraîneurs en fonction des succès ou des échecs de leur équipe. ... [less ▲]

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See detailEvaluation d'une technique d'injection d'insecticides dans les troncs pour la lutte intégrée contre Eupulvinaria hydrangeae Steinw. (Hom. Coccidae)
Schiffers, Bruno ULg; Tondeur, R.; Verstraeten, Ch. et al

in Proceedings A.N.P.P. - B.C.P.C. - Second Symposium International sur les Techniques d'Application des Pesticides (1993)

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See detailTuméfaction de la jambe à Neocosmospora vasinfecta chez un transplanté rénal. Premier cas d'infection humaine
Chandenier, Jacques; Hayette, Marie-Pierre ULg; de Bièvre, Claude et al

in Journal de Mycologie Médicale (1993), 3

A 46-year old man, originated from Senegal, but living in France for more than 15 years, is dialized since January 1989, because of renal insuficiency. He had undergone a kidney graft in October 1990 with ... [more ▼]

A 46-year old man, originated from Senegal, but living in France for more than 15 years, is dialized since January 1989, because of renal insuficiency. He had undergone a kidney graft in October 1990 with good initial evolution, without any graft rejection. The immunosuppressive tretment quite moderate, was prenisone 10mg/d, azathioprine 50 mg/d and ciclosporine 400mg/d. On the 8th month, a tumefaction affecting the anterior side of the left leg was discovered, which was thick, renitent and non inflammatory. It relapsed after two punctures. In both cases direct examination showed numerous hyphae and a fungus identified as Neocosmospora vasinfecta, was isolated by culture:it is the sexual form of an Ascomycete whose species name is not identified. The treatment associated a complete surgery and ketoconazole during a week (200mg/d) The tumor did not relapsed after a 30 months follow up. [less ▲]

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See detailBiological control of Botrytis cinerea and Penicillium sp. on post-harvest apples by two antagonistic yeasts.
Jijakli, Mohamed ULg; Lepoivre, Philippe ULg; Tossut, P. et al

in Mededelingen van de Faculteit Landbouwkundige en Toegepaste Biologische Wetenschappen (Rijksuniversiteit te Gent) (1993), 58(3b),

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See detailBiological control of postharvest Botrytis cinerea and Penicillium on apples
Jijakli, Haissam ULg; Lepoivre, Philippe ULg

in Bulletin OILB/SROP = IOBC/WPRS Bulletin (1993), (16), 106-110

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See detailFormulation and integrated use of two antagonistic yeasts to postharvest treatments against diseases on apples
Jijakli, Haissam ULg; Choutka, C.; Lepoivre, Philippe ULg

in Proceedings of an EC Workshop: Biological control of fruit and Foliar diseases (1993)

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See detailModélisation du bilan en oxygène dans la Moselle
Descy, Jean-Pierre; Everbecq, Etienne ULg; Gosselain, Véronique et al

Report (1993)

L'objet de ce travail était d'expliquer les diminutions de concentration en oxygène dissous rencontrées dans le secteur de la Moselle situé entre Metz et Trèves. A cette fin, un modèle déterministe de la ... [more ▼]

L'objet de ce travail était d'expliquer les diminutions de concentration en oxygène dissous rencontrées dans le secteur de la Moselle situé entre Metz et Trèves. A cette fin, un modèle déterministe de la qualité des eaux de surface initialement développé pour la Meuse a été utilisé. [less ▲]

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See detailHistoplasmose africiaine à Histoplasma duboisii (Histoplasma capsulatum var. duboisii): quatorze cas congolais observés en 10 ans (1981-1990)
Carme, Bernard; Hayette, Marie-Pierre ULg; Itoua Ngaporo, A. et al

in Journal de Mycologie Médicale (1993), 3

Fourteen cases of histoplasmosis due to Histoplasma duboisii seen in Congo from 1981 through 1990, are reported: the average age of the patients was 25 years (the youngest being 1,5 y and the oldest 50y ... [more ▼]

Fourteen cases of histoplasmosis due to Histoplasma duboisii seen in Congo from 1981 through 1990, are reported: the average age of the patients was 25 years (the youngest being 1,5 y and the oldest 50y), the M/F ratio was 2,5; most of the patients (10/14) live in a rural area. there was a rather constant frequency of one to three cases per annum from 1981 through 1990. The fisrt congolese AIDS-associated systemic histoplasmosis duboisii case was observed in 1990. Lymph node involvment and mucocutaneous lesions were the most frequent clinical manifestations. In all cases, the disgnosis was established by histological examination. When performed, direct microscopy was always positive (11/11). Isolation of H. duboisii in culture was successful in 7 out of 9 attempts. Two cases of systemic infection were rapidly fatal but a good clinical response was obtained in the other cases wih amphotericin B, which due to intolerance, was replaced by ketoconazole in 2 patients. [less ▲]

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See detailRoman Jakobson
Durand, Pascal ULg

in Sfez Lucien (Ed.) Dictionnaire critique de la communication (1993)

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See detailLa chat européen
Libois, Roland ULg

Learning material (1993)

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See detailCaracterisation de l'agent responsable de l'ascochytose de Phaseolus vulgaris en Afrique et en Amerique du Sud.
Lepoivre, Philippe ULg; Baudouin, J. P.

in Bulletin des Séances de l’Académie Royale des Sciences d’Outre-Mer = Mededelingen der Zittingen van de Koninklijke Academie voor Overzeese Wetenschappen (1993), 39(4),

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See detailEffect of the combination of seed priming and Trichoderma treatment on incidence of damping-off agents.
Jacqmin, B.; Cotes, A. M.; Lepoivre, Philippe ULg et al

in Mededelingen van de Faculteit Landbouwkundige en Toegepaste Biologische Wetenschappen (Rijksuniversiteit te Gent) (1993), 58(3b),

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See detailResistance a la secheresse et reponses a l'acide abscissique: analyse d'une approche synthetique.
El-Jaafari, S.; Paul, Roger ULg; Lepoivre, Philippe ULg et al

in Cahiers Agricultures (1993), 2(4),

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See detailDecision tree approach to power systems security assessment
Wehenkel, Louis ULg; Pavella, Mania ULg

in International Journal of Electric Power and Energy Systems (1993), 15(1), 13-36

An overview of the general decision tree approach to power system security assessment is presented. The general decision tree methodology is outlined, modifications proposed in the context of transient ... [more ▼]

An overview of the general decision tree approach to power system security assessment is presented. The general decision tree methodology is outlined, modifications proposed in the context of transient stability assessment are embedded, and further refinements are considered. The approach is then suitably tailored to handle other specifics of power systems security, relating to both preventive and emergency voltage control, in addition to transient stability. Trees are accordingly built in these various application domains, and their salient features are explored, assessed, compared. Among attractive aspects of the trees, we mention their ability to uncover the intrinsic mechanism governing physical processes, and to provide a clear description in terms of tractable system parameters. Further, their dual, 'attribute space' representation is shown to have complementary possibilities for more refined analysis and, in addition, for sensitivity assessment and control. Overall, the approach is characterized by its great flexibility with respect to tree structure, types of physical parameters driving the phenomena, and classes of potential applications. To illustrate and support the developments,real-world examples are reported, rolatin 9 to transient and voltage stability issues simulated on several power systems. [less ▲]

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See detailAn overview of the kinetic parameters of class B beta-lactamases.
Felici, A; Amicosante, G; Oratore, A et al

in Biochemical Journal (1993), 291 ( Pt 1)

The catalytic properties of three class B beta-lactamases (from Pseudomonas maltophilia, Aeromonas hydrophila and Bacillus cereus) were studied and compared with those of the Bacteroides fragilis enzyme ... [more ▼]

The catalytic properties of three class B beta-lactamases (from Pseudomonas maltophilia, Aeromonas hydrophila and Bacillus cereus) were studied and compared with those of the Bacteroides fragilis enzyme. The A. hydrophila beta-lactamase exhibited a unique specificity profile and could be considered as a rather specific 'carbapenemase'. No relationships were found between sequence similarities and catalytic properties. The problem of the repartition of class B beta-lactamases into sub-classes is discussed. Improved purification methods were devised for the P. maltophilia and A. hydrophila beta-lactamases including, for the latter enzyme, a very efficient affinity chromatography step on a Zn(2+)-chelate column. [less ▲]

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See detailMechanism of action of DD-peptidases: role of asparagine-161 in the Streptomyces R61 DD-peptidase.
Wilkin, J M; Jamin, M; Joris, Bernard ULg et al

in Biochemical Journal (1993), 293 ( Pt 1)

The role of residue Asn-161 in the interaction between the Streptomyces R61 DD-peptidase and various substrates or beta-lactam inactivators was probed by site-directed mutagenesis. The residue was ... [more ▼]

The role of residue Asn-161 in the interaction between the Streptomyces R61 DD-peptidase and various substrates or beta-lactam inactivators was probed by site-directed mutagenesis. The residue was successively replaced by serine and alanine. In the first case, acylation rates were mainly affected with the peptide and ester substrates but not with the thiol-ester substrates and beta-lactams. However, the deacylation rates were decreased 10-30-fold with the substrates yielding benzoylglycyl and benzoylalanyl adducts. The Asn161Ala mutant was more generally affected, although the acylation rates with cefuroxime and cefotaxime remained similar to those observed with the wild-type enzyme. Surprisingly, the deacylation rates of the benzoylglycyl and benzoylalanyl adducts were very close to those observed with the wild-type enzyme. The results also indicate that the interaction with the peptide substrate and the transpeptidation reaction were more sensitive to the mutations than the other reactions studied. The results are discussed and compared with those obtained with the Asn-132 mutants of a class A beta-lactamase. [less ▲]

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