Publications and communications of Antoine Debuigne

Book chapters or contributions to a collective book as author or co-author

Stiernet, P., Dréan, M., Jérôme, C., Midoux, P., Guégan, P., Rieger, J., & Debuigne, A. (2018). Tailor-made poly(vinylamine)s via thermal or photochemical organometallic mediated radical polymerization. In K. Matyjaszewski, H. Gao, B. S. Sumerlin, ... N. V. Tsarevsky (Eds.), ACS Symposium Series (pp. 349-363). United States: American Chemical Society. doi:10.1021/bk-2018-1284.ch017

Demarteau, J., Kermagoret, A., Jérôme, C., Detrembleur, C., & Debuigne, A. (2015). Controlled synthesis of ethylene-vinyl acetate based copolymers by organometallic mediated radical polymerization. In K. Matyjaszewski, B. S. Sumerlin, N. V. Tsarevsky, ... J. Chiefari (Eds.), Controlled Radical Polymerization: Materials (pp. 47-61). American Chemical Society. doi:10.1021/bk-2015-1188.ch004

Debuigne, A., Hurtgen, M., Jérôme, C., & Detrembleur, C. (2012). Radical coupling of polymers formed by cobalt-mediated radical polymerization. In K. Matyjaszewski, B. Sumerlin, ... N. V. Tsarevsky (Eds.), Progress in controlled radical polymerization: mechanisms and techniques (pp. 217-230). The American Chemical Society, Division Polymer Chemistry. doi:10.1021/bk-2012-1100.ch014

Debuigne, A., Jérôme, R., Jérôme, C., & Detrembleur, C. (2012). Cobalt-mediated radical polymerization. In D. A. Schlüter, C. Hawker, ... J. Sakamoto (Eds.), Synthesis of polymers: new structures and methods (pp. 67-79). Wiley.

Debuigne, A., Poli, R., Jérôme, R., Jérôme, C., & Detrembleur, C. (2009). Key role of metal-coordination in cobalt-mediated radical polymerization of vinyl acetate. In K. Matyjaszewski (Ed.), Controlled/living radical polymerization: progress in RAFT, DT, NMP & OMRP (pp. 131-147). The American Chemical Society, Division Polymer Chemistry. doi:10.1021/bk-2009-1024.ch009

Debuigne, A., Detrembleur, C., Bryaskova, R., Caille, J.-R., & Jérôme, R. (2006). Cobalt-mediated radical polymerization of vinyl acetate: a new tool for macromolecular engineering. In K. Matyjaszewski (Ed.), Controlled/living radical polymerization: from synthesis to materials (The American Chemical Society, pp. 372-386). doi:10.1021/bk-2006-0944.ch026

Articles accepted in reviewed journal

Toussaint, F., Lepeltier, E., Franconi, F., Pautu, V., Jérôme, C., Passirani, C., & Debuigne, A. (March 2024). Diversely substituted poly(N-vinyl amide) derivatives towards non-toxic, stealth and pH-responsive lipid nanocapsules. Colloids and Surfaces B: Biointerfaces, 235, 113788. doi:10.1016/j.colsurfb.2024.113788

Berger, M.* , Toussaint, F.* , Djemaa, S. B.* , Maquoi, E., Pendeville-Samain, H., Evrard, B., Jérôme, C., Chain, J. L., Lechanteur, A., Mottet, D.* , Debuigne, A.* , & Piel, G.*. (2023). Poly(N-methyl‐N‐vinylacetamide): a strong alternative to PEG for lipid‐based nanocarriers delivering siRNA. Advanced Healthcare Materials, 2302712. doi:10.1002/adhm.202302712
* These authors have contributed equally to this work.

Berger, M.* , Toussaint, F.* , Djemaa, S. B.* , Laloy, J., Pendeville-Samain, H., Evrard, B., Jérôme, C., Lechanteur, A., Mottet, D.* , Debuigne, A.* , & Piel, G.*. (02 August 2023). Poly(vinyl pyrrolidone) derivatives as PEG alternatives for stealth, non-toxic and less immunogenic siRNA-containing lipoplex delivery. Journal of Controlled Release, 361, 87 - 101. doi:10.1016/j.jconrel.2023.07.031
* These authors have contributed equally to this work.

Wang, Z., & Debuigne, A. (21 February 2023). Radical Polymerization of Methylene Heterocyclic Compounds: Functional Polymer Synthesis and Applications. Polymer Reviews, 63 (4), 805-851. doi:10.1080/15583724.2023.2181819

Wang, Z., & Debuigne, A. (28 September 2022). Multi-responsive γ-Methylene-γ-Butyrolactone/<i>N</i>-Vinyl Caprolactam Copolymers Involving pH-depend Reversible Lactonization. Polymer Chemistry, 13 (36), 5212-5225. doi:10.1039/d2py00713d

Stiernet, P., & Debuigne, A. (May 2022). Imine-Based Multicomponent Polymerization: Concepts, Structural Diversity and Applications. Progress in Polymer Science, 128, 101528. doi:10.1016/j.progpolymsci.2022.101528

Stiernet, P., Mazaj, M., Kovačič, S., & Debuigne, A. (2022). Bifunctional Imidazolium/Amine Polymer Foams: One-pot Synthesis and Synergistic Promotion of CO2 Sorption. Chemical Engineering Journal, 446 (1), 137012. doi:10.1016/j.cej.2022.137012

Wang, Z., Vertruyen, B., Taghipour, H., Detrembleur, C., & Debuigne, A. (23 November 2021). CO2-Derived methylene oxazolidinone: a platform building block for functionalizing ethylene–vinyl alcohol copolymers. Macromolecules, 54 (22), 10415-10427. doi:10.1021/acs.macromol.1c01895

Pautu, V., Lepeltier, E., Mellinger, A., Riou, J., Debuigne, A., Jérôme, C., Clere, N., & Passirani, C. (01 May 2021). pH‐Responsive lipid nanocapsules: a promising strategy for improved resistant melanoma cell internalization. Cancers, 13 (9), 2028. doi:10.3390/cancers13092028

Stiernet, P., Couturaud, B., Bertrand, V., Eppe, G., De Winter, J., & Debuigne, A. (14 April 2021). Ugi four-component polymerization of amino acid derivatives: a combinatorial tool for the design of polypeptoids. Polymer Chemistry, 12 (14), 2141-2151. doi:10.1039/D1PY00109D

Scholten, P. B. V., Cartigny, G., Grignard, B., Debuigne, A., Cramail, H., Meier, M. A. R., & Detrembleur, C. (16 March 2021). Functional polyethylenes by organometallic-mediated radical polymerization of biobased carbonates. ACS Macro Letters, 10 (3), 313-320. doi:10.1021/acsmacrolett.1c00037

Falireas, P., Thomassin, J.-M., & Debuigne, A. (15 March 2021). Imidazolium-catalyzed Dynamic ester cross-links towards reprocessable epoxy vitrimers. European Polymer Journal, 147, 110296. doi:10.1016/j.eurpolymj.2021.110296

Jurjevec, S., Debuigne, A., Žagar, E., & Kovačič, S. (28 February 2021). An environmentally benign post-polymerization functionalization strategy towards unprecedented poly(vinylamine) polyHIPEs. Polymer Chemistry, 12 (8), 1155-1164. doi:10.1039/d0py01677b

Wang, Z., Detrembleur, C., & Debuigne, A. (07 December 2020). Reversible deactivation radical (co)polymerization of dimethyl methylene oxazolidinone towards responsive vicinal aminoalcohol-containing copolymers. Polymer Chemistry, 11 (45), 7207-7220. doi:10.1039/D0PY01255F

Thangaraj, V., Dewalque, J., Maho, A., Spronck, G., Malherbe, C., Aqil, A., Cloots, R., Colson, P., Jérôme, C., & Debuigne, A. (05 December 2020). Carbon-coated porous TiO2 layers templated by core-shell polymer particles: film processing and charge transfer resistance assessment. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 606, 125390. doi:10.1016/j.colsurfa.2020.125390

Stiernet, P., Aqil, A., Zhu, X., & Debuigne, A. (21 January 2020). Multicomponent Radziszewski emulsion polymerization towards macroporous poly(ionic liquid)s catalysts. ACS Macro Letters, 9 (1), 134-139. doi:10.1021/acsmacrolett.9b00942

Demarteau, J., Scholten, P., Kermagoret, A., De Winter, J., Meier, M. A., Monteil, V., Debuigne, A., & Detrembleur, C. (26 November 2019). Functional polyethylene (PE) and PE-basedl block copolymers by organometallic-mediated radical polymerization. Macromolecules, 52 (22), 9053-9063. doi:10.1021/acs.macromol.9b01741

Wang, Z., Poli, R., Detrembleur, C., & Debuigne, A. (26 November 2019). Organometallic-mediated radical (co)polymerization of γ‑methylene-γ-butyrolactone: access to pH-responsive poly(vinyl alcohol) derivatives. Macromolecules, 52 (22), 8976-8988. doi:10.1021/acs.macromol.9b01838

Demarteau, J., Debuigne, A., & Detrembleur, C. (26 June 2019). Organocobalt complexes as sources of carbon-centered radicals for organic and polymer chemistries. Chemical Reviews, 119 (12), 6906-6955. doi:10.1021/acs.chemrev.8b00715

Stiernet, P., Jérôme, C., & Debuigne, A. (21 June 2019). Precision design of vinyl amine and vinyl alcohol-based copolymers via cobalt-mediated radical polymerization. Polymer Chemistry, 10 (23), 3055-3065. doi:10.1039/c9py00020h

Falireas, P., Ladmiral, V., Debuigne, A., Detrembleur, C., Poli, R., & Ameduri, B. (12 February 2019). Straightforward synthesis of well-defined poly(vinylidene fluoride) and its block copolymers by cobalt-mediated radical polymerization. Macromolecules, 52 (3), 1266-1276. doi:10.1021/acs.macromol.8b02252

Stiernet, P., Lecomte, P., De Winter, J., & Debuigne, A. (2019). Ugi three-component polymerization toward poly(α-amino amide)s. ACS Macro Letters, 8, 427-434. doi:10.1021/acsmacrolett.9b00182

Scholten, P., Demarteau, J., Gennen, S., De Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (08 May 2018). Merging CO2‑based building blocks with cobalt-mediated radical polymerization for the synthesis of functional poly(vinyl alcohol)s. Macromolecules, 51 (9), 3379-3393. doi:10.1021/acs.macromol.8b00492

Dréan, M., Debuigne, A., Jérôme, C., Goncalves, C., Midoux, P., Rieger, J., & Guégan, P. (April 2018). Poly(N-methylvinylamine)-based copolymers for improved gene transfection. Macromolecular Bioscience, 18 (4), 1700353. doi:10.1002/mabi.201700353

Banerjee, S., Ladmiral, V., Debuigne, A., Detrembleur, C., Poli, R., & Améduri, B. (05 March 2018). Organometallic mediated radical polymerization of vinylidene fluoride. Angewandte Chemie International Edition, 57 (11), 2934-2937. doi:10.1002/anie.201712347

Mathieu, K., Jérôme, C., & Debuigne, A. (28 January 2018). Macroporous poly(ionic liquid)/ionic liquid gels via CO2-based emulsion-templating polymerization. Polymer Chemistry, 9 (4), 428-437. doi:10.1039/C7PY01952A

Demarteau, J., De Winter, J., Detrembleur, C., & Debuigne, A. (21 January 2018). Ethylene/vinyl acetate-based macrocycles via organometallic-mediated radical polymerization and CuAAC ‘click’ reaction. Polymer Chemistry, 9 (3), 273-278. doi:10.1039/C7PY01891F

Banerjee, S., Bellan, E. V., Gayet, F., Debuigne, A., Detrembleur, C., Poli, R., Améduri, B., & Ladmiral, V. (December 2017). Bis(formylphenolato)cobalt(II)-mediated alternating radical copolymerization of tert-butyl 2-trifluoromethylacrylate with vinyl acetate. Polymers, 9 (12), 705. doi:10.3390/polym9120702

Al Samad, A., De Winter, J., Gergaux, P., Jérôme, C., & Debuigne, A. (21 November 2017). Unique alternating peptide-peptoid copolymers from dipeptides via Ugi reaction in water. Chemical Communications, 53 (90), 12240-12243. doi:10.1039/C7CC06463B

Liu, X., Wang, M., Harrisson, S., Debuigne, A., Marty, J.-D., & Destarac, M. (06 November 2017). Enhanced stabilization of water-scCO2 interface by block-like spontaneous gradient copolymers. ACS Sustainable Chemistry and Engineering, 5 (11), 9645-9650. doi:10.1021/acssuschemeng.7b02779

Banerjee, S., Ladmiral, V., Debuigne, A., Detrembleur, C., Rahaman S. M., W., Poli, R., & Améduri, B. (August 2017). Organometallic-mediated alternating radical copolymerization of tert-butyl-2- trifluoromethacrylate with vinyl acetate and synthesis of block copolymers thereof. Macromolecular Rapid Communications, 38 (15), 1700203. doi:10.1002/marc.201700203

Demarteau, J., Améduri, B., Ladmiral, V., Mees, M. A., Hoogenboom, R., Debuigne, A., & Detrembleur, C. (23 May 2017). Controlled synthesis of fluorinated copolymers via cobalt-mediated radical copolymerization of perfluorohexylethylene and vinyl acetate. Macromolecules, 50 (10), 3750-3760. doi:10.1021/acs.macromol.7b00578

Debuigne, A., Jérôme, C., & Detrembleur, C. (21 April 2017). Organometallic-mediated radical polymerization of 'less activated monomers': fundamentals, challenges and opportunities. Polymer, 115, 285-307. doi:10.1016/j.polymer.2017.01.008

Mathieu, K., De Winter, J., Jérôme, C., & Debuigne, A. (21 March 2017). Simultaneous synthesis and chemical functionalization of emulsion-templated porous polymers using nitroxide-terminated macromolecular surfactants. Polymer Chemistry, 8 (11), 1850-1861. doi:10.1039/C7PY00128B

Dréan, M., Debuigne, A., Gonçalves, C., Jérôme, C., Midoux, P., Rieger, J., & Guégan, P. (13 February 2017). Use of primary and secondary polyvinylamines for efficient gene transfection. Biomacromolecules, 18 (2), 440-441. doi:10.1021/acs.biomac.6b01526

Ergül, Z., Cordonnier, T., Debuigne, A., Clavignac, B., Jérôme, C., & Boury, F. (20 November 2016). Protein encapsulation and release from PEO-b-polyphosphoester templated calcium carbonate particles. International Journal of Pharmaceutics, 513, 130-1. doi:10.1016/j.ijpharm.2016.09.007

Patil, N., Cordella, D., Aqil, A., Debuigne, A., Admassie, S., Jérôme, C., & Detrembleur, C. (25 October 2016). Surface- and redox-active multifunctional polyphenol-derived poly(ionic liquid)s: controlled synthesis and characterization. Macromolecules, 49 (20), 7676-7691. doi:10.1021/acs.macromol.6b01857

Mathieu, K., Jérôme, C., & Debuigne, A. (02 September 2016). Macro- and near-mesoporous monoliths by medium internal phase emulsion polymerization: a systematic study. Polymer, 99, 157-165. doi:10.1016/j.polymer.2016.07.012

Dréan, M., Guégan, P., Detrembleur, C., Jérôme, C., Rieger, J., & Debuigne, A. (28 June 2016). Controlled synthesis of poly(vinylamine)-based copolymers by organometallic-mediated radical polymerization. Macromolecules, 49 (13), 4817-4827. doi:10.1021/acs.macromol.6b00992

Kermagoret, Chau, N. D. Q., Grignard, B., Cordella, D., Debuigne, A., Jérôme, C., & Detrembleur, C. (March 2016). Cobalt-mediated radical polymerization of vinyl acetate and acrylonitrile in supercritical carbon dioxide. Macromolecular Rapid Communications, 39 (6), 539-544. doi:10.1002/marc.201500629

Dréan, M., Guégan, P., Jérôme, C., Rieger, J., & Debuigne, A. (07 January 2016). Far beyond primary poly(vinylamine)s through free radical copolymerization and amide hydrolysis. Polymer Chemistry, 7 (1), 69-78. doi:10.1039/C5PY01325A

Cordella, D., Debuigne, A., Jérôme, C., Kochovski, Z., Taton, D., & Detrembleur, C. (2016). One-pot synthesis of double poly(ionic liquid) block copolymers by cobalt-mediated radical polymerization-induced self assembly (CMR-PISA) in water. Macromolecular Rapid Communications, 37 (14), 1181-1187. doi:10.1002/marc.201600039

Ergül, Z., Vanslambrouck, S., Cajot, S., Thiry, J., Debuigne, A., Lecomte, P., Jérôme, C., & Riva, R. (2016). Core cross-linked micelles of polyphosphoester containing amphiphilic block copolymers as drug nanocarriers. RSC Advances, 6 (48), 42081-42088. doi:10.1039/C6RA07422G

Demarteau, J., Kermagoret, A., German, I., Cordella, D., Robeyns, K., De Winter, J., Gerbaux, P., Jérôme, C., Debuigne, A., & Detrembleur, C. (01 October 2015). Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers. Chemical Communications, 51 (76), 14334-14337. doi:10.1039/C5CC04714E

Ergül, Z., Debuigne, A., Calvignac, B., Boury, F., & Jérôme, C. (28 September 2015). Double hydrophilic polyphosphoester containing copolymers as efficient templating agents for calcium carbonate microparticles. Journal of Materials Chemistry B, 3 (36), 7227-7236. doi:10.1039/c5tb00887e

Mathieu, K., Jérôme, C., & Debuigne, A. (22 September 2015). Influence of the macromolecular surfactant features and reactivity on morphology and surface properties of emulsion-templated porous polymers. Macromolecules, 48 (18), 6489-6498. doi:10.1021/acs.macromol.5b00858

Cordella, D., Kermagoret, A., Debuigne, A., Jérôme, C., Mecerreyes, D., Isik, M., Taton, D., & Detrembleur, C. (11 August 2015). All Poly(ionic liquid)-based block copolymers by sequential controlled radical copolymerization of vinylimidazolium monomers. Macromolecules, 48 (15), 5230-5243. doi:10.1021/acs.macromol.5b01013

Thomassin, J.-M., Mathieu, K., Kermagoret, A., Fustin, C.-A., Jérôme, C., & Debuigne, A. (14 March 2015). Double thermo-responsive hydrogels from poly(vinylcaprolactam) containing diblock and triblock copolymers. Polymer Chemistry, 6 (10), 1856-1864. doi:10.1039/C4PY01606H

Obadia, M. M., Colliat-Dangus, G., Debuigne, A., Serghei, A., Detrembleur, C., & Drockenmuller, E. (25 February 2015). Poly(vinyl ester 1,2,3-triazolium)s: a new member of the poly(ionic liquid)s family. Chemical Communications, 51 (16), 3332-3335. doi:10.1039/c4cc08847f

Alaimo, D., Hermida Merino, D., Grignard, B., Bras, W., Jérôme, C., Debuigne, A., & Gommes, C. (2015). Small Angle X-ray Scattering Insights into the Architecture-Dependent Emulsifying Properties of Amphiphilic Copolymers in Supercritical Carbon Dioxide. Journal of Physical Chemistry B, 119, 1706-1716. doi:10.1021/jp5086558

Kermagoret, A., Jérôme, C., Detrembleur, C., & Debuigne, A. (January 2015). In situ bidentate to tetradentate ligand exchange reaction in cobalt-mediated radical polymerization. European Polymer Journal, 62, 312-321. doi:10.1016/j.eurpolymj.2014.08.003

Kermagoret, A., Wenn, B., Debuigne, A., Jérôme, C., Junkers, T., & Detrembleur, C. (2015). Improved photo-induced cobalt-mediated radical polymerization in continuous flow photoreactors. Polymer Chemistry, 6, 3847-3857. doi:10.1039/C5PY00299K

Poggi, E., Guerlain, C., Debuigne, A., Detrembleur, C., Gigmes, D., Hoeppener, S., Schubert, U. S., Fustin, C.-A., & Gohy, J.-F. (January 2015). Stimuli-responsive behavior of micelles prepared from a poly(vinyl alcohol)-block-poly(acrylic acid)-block-poly(4-vinylpyridine) triblock terpolymer. European Polymer Journal, 62, 418-425. doi:10.1016/j.eurpolymj.2014.06.026

Cordella, D., Kermagoret, A., Debuigne, A., Riva, R., German, I., Isik, M., Jérôme, C., Meccereyes, D., Taton, D., & Detrembleur, C. (05 December 2014). Direct route to well-defined poly(ionic liquid)s by controlled radical polymerization in water. ACS Macro Letters, 3, 1276-1280. doi:10.1021/mz500721r

Boyère, C., Jérôme, C., & Debuigne, A. (December 2014). Input of supercritical carbon dioxide to polymer synthesis: an overview. European Polymer Journal, 61, 45-63. doi:10.1016/j.eurpolymj.2014.07.019

Liu, J., Debuigne, A., Detrembleur, C., & Jérôme, C. (December 2014). Poly( N-vinylcaprolactam): A thermoresponsive macromolecule with promising future in biomedical field. Advanced Healthcare Materials, 3 (12), 1941-1968. doi:10.1002/adhm.201400371

Kermagoret, A., Mathieu, K., Thomassin, J.-M., Fustin, C.-A., Duchëne, R., Jérôme, C., Detrembleur, C., & Debuigne, A. (21 November 2014). Double thermoresponsive di- and triblock copolymers based on N-vinylcaprolactam and N-vinylpyrrolidone: synthesis and comparative study of solution behaviour. Polymer Chemistry, 5 (22), 6534-6544. doi:10.1039/C4PY00852A

Liu, J., Detrembleur, C., Hurtgen, M., Debuigne, A., De Pauw-Gillet, M.-C., Mornet, S., Duguet, E., & Jérôme, C. (21 September 2014). Thermo-responsive gold/poly(vinyl alcohol)-b-poly(N-vinylcaprolactam) core–corona nanoparticles as a drug delivery system. Polymer Chemistry, 5 (18), 5289-5299. doi:10.1039/C4PY00352G

Allaoua, I., Eleuterio, B., Obadia, M. M., Debuigne, A., Detrembleur, C., & Drockenmuller, E. (21 April 2014). (Co)Polymerization of vinyl levulinate by cobalt-mediated radical polymerization and functionalization by ketoxime click chemistry. Polymer Chemistry, 5 (8), 2973-2979. doi:10.1039/c3py01505j

Boyère, C., Duhem, N., Debuigne, A., Préat, V., Jérôme, C., & Riva, R. (21 April 2014). Elaboration of drug nanocarriers based on a glucosamine labeled amphiphilic polymer. Polymer Chemistry, 5 (8), 3030-3037. doi:10.1039/c3py01730c

Kermagoret, A., Debuigne, A., Jérôme, C., & Detrembleur, C. (March 2014). Precision design of ethylene- and polar-monomer-based copolymers by organometallic-mediated radical polymerization. Nature Chemistry, 6 (3), 179-187. doi:10.1038/nchem.1850

Liu, J., Detrembleur, C., Debuigne, A., De Pauw-Gillet, M.-C., Mornet, S., Vander Elst, L., Laurent, S., Duguet, E., & Jérôme, C. (28 February 2014). Glucose-, pH- and thermo-responsive nanogels crosslinked by functional superparamagnetic maghemite nanoparticles as innovative drug delivery systems. Journal of Materials Chemistry B, 2 (8), 1009-1023. doi:10.1039/c3tb21272f

Coupillaud, P., Fèvre, M., Wirotius, A.-L., Aissou, K., Fleury, G., Debuigne, A., Detrembleur, C., Mecerreyes, D., Vignolle, J., & Taton, D. (February 2014). Precision synthesis of poly(ionic liquid)-based block copolymers by cobalt-mediated radical polymerization and preliminary study of their self-assembling properties. Macromolecular Rapid Communications, 35 (4), 422-430. doi:10.1002/marc.201300776

Liu, J., Detrembleur, C., Hurtgen, M., Debuigne, A., De Pauw-Gillet, M.-C., Mornet, S., Duguet, E., & Jérôme, C. (07 January 2014). Reversibly crosslinked thermo- and redox-responsive nanogels for controlled drug release. Polymer Chemistry, 5 (1), 77-88. doi:10.1039/c3py00839h

Kermagoret, A., Nakamura, Y., Bourguignon, M., Detrembleur, C., Jérôme, C., Yamago, S., & Debuigne, A. (06 January 2014). Expanding the scope of controlled radical polymerization via cobalt–tellurium radical exchange reaction. ACS Macro Letters, 3 (1), 114-118. doi:10.1021/mz400635h

Liu, J., Detrembleur, C., Debuigne, A., De Pauw-Gillet, M.-C., Mornet, S., Vander Elst, L., Laurent, S., Labrugère, C., Duguet, E., & Jérôme, C. (07 December 2013). Poly(acrylic acid)-block-poly(vinyl alcohol) anchored maghemite nanoparticles designed for multi-stimuli triggered drug release. Nanoscale, 5 (23), 11464-11477. doi:10.1039/c3nr02861e

Debuigne, A., Detrembleur, C., Jérôme, C., & Junkers, T. (26 November 2013). Straightforward synthesis of symmetrical multiblock copolymers by simultaneous block extension and radical coupling reactions. Macromolecules, 46 (22), 8922-8931. doi:10.1021/ma401918t

Boyère, C., Broze, G., Blecker, C., Jérôme, C., & Debuigne, A. (18 October 2013). Monocatenary, branched, double-headed and bolaform surface active carbohydrate esters via photochemical thiol-ene/-yne reactions. Carbohydrate Research, 380, 29-36. doi:10.1016/j.carres.2013.07.003

Boyère, C., Favrelle, A., Léonard, A., Boury, F., Jérôme, C., & Debuigne, A. (07 August 2013). Macroporous poly(ionic liquid)s and poly(acrylamide)s monoliths from CO2-in-water emulsion templates stabilized by sugar-based surfactants. Journal of Materials Chemistry A, 1 (29), 8479-8487. doi:10.1039/c3ta11073g

Morin, A. N., Detrembleur, C., Jérôme, C., De Tullio, P., Poli, R., & Debuigne, A. (11 June 2013). Effect of head-to-head addition in vinyl acetate controlled radical polymerization: why is Co(acac)2-mediated polymerization so much better? Macromolecules, 46 (11), 4303-4312. doi:10.1021/ma400651a

Favrelle, A., Boyère, C., Tran, K. M., Alaimo, D., Calvignac, B., Paquot, M., Boury, F., Jérôme, C., & Debuigne, A. (15 May 2013). Surface activity of a fluorinated carbohydrate ester in water/carbon dioxide emulsions. Journal of Colloid and Interface Science, 398, 273-275. doi:10.1016/j.jcis.2013.02.023

Kermagoret, A., Fustin, C.-A., Bourguignon, M., Detrembleur, C., Jérôme, C., & Debuigne, A. (21 April 2013). One-pot controlled synthesis of double thermoresponsive N-vinylcaprolactam-based copolymers with tunable LCSTs. Polymer Chemistry, 4 (8), 2575-2583. doi:10.1039/c3py00134b

Galonde, N., Nott, K., Richard, G., Debuigne, A., Nicks, F., Jérôme, C., & Fauconnier, M.-L. (April 2013). Study of the Influence of Pure Ionic Liquids on the Lipase-catalyzed (Trans)esterification of Mannose Based on their Anion and Cation Nature. Current Organic Chemistry, 17 (7), 763-770. doi:10.2174/1385272811317070010

Hurtgen, M., Debuigne, A., Hoebeke, M., Passirani, C., Lautram, N., Mouithys-Mickalad, A., Guelluy, P.-H., Jérôme, C., & Detrembleur, C. (January 2013). Photochemical properties and activity of water-soluble polymer/C60 nanohybrids for photodynamic therapy. Macromolecular Bioscience, 13 (1), 106-115. doi:10.1002/mabi.201200251

Piette, Y., Debuigne, A., Bodart, V., Willet, N., Duwez, A.-S., Jérôme, C., & Detrembleur, C. (2013). Synthesis of poly(vinyl acetate)-b-poly(vinyl chloride) block copolymers by cobalt-mediated radical polymerization (CMRP). Polymer Chemistry, 4 (5), 1685-1693. doi:10.1039/c2py20965a

Piette, Y., Debuigne, A., Jérôme, C., Bodart, V., Poli, R., & Detrembleur, C. (October 2012). Cobalt-mediated radical (co)polymerization of vinyl chloride and vinyl acetate. Polymer Chemistry, 3 (10), 2880-2891. doi:10.1039/c2py20413d

Hurtgen, M., Debuigne, A., Gigmes, D., Jérôme, C., & Detrembleur, C. (12 September 2012). Mechanistic investigation and selectivity of the grafting onto C60 of macroradicals prepared by cobalt-mediated radical polymerization. Polymer, 53 (20), 4353-4358. doi:10.1016/j.polymer.2012.07.018

Boyère, C., Léonard, A., Grignard, B., Favrelle, A., Pirard, J.-P., Paquot, M., Jérôme, C., & Debuigne, A. (28 August 2012). Synthesis of microsphere-loaded porous polymers by combining emulsion and dispersion polymerisations in supercritical carbon dioxide. Chemical Communications, 48 (67), 8356-8358. doi:10.1039/c2cc33978a

Debuigne, A., Hurtgen, M., Detrembleur, C., Jérôme, C., Barner-Kowollik, C., & Junkers, T. (July 2012). Interpolymer radical coupling: A toolbox complementary to controlled radical polymerization. Progress in Polymer Science, 37 (7), 1004-1030. doi:10.1016/j.progpolymsci.2012.01.003

Detrembleur, C., Versace, D.-L., Piette, Y., Hurtgen, M., Jérôme, C., Lalevée, J., & Debuigne, A. (July 2012). Synthetic and mechanistic inputs of photochemistry into the bisacetylacetonatocobalt- mediated radical polymerization of n-butyl acrylate and vinyl acetate. Polymer Chemistry, 3 (7), 1856-1866. doi:10.1039/c1py00443c

Galonde, N., Nott, K., Debuigne, A., Deleu, M., Jérôme, C., Paquot, M., & Wathelet, J.-P. (April 2012). Use of ionic liquids for biocatalytic synthesis of sugar derivatives. Journal of Chemical Technology and Biotechnology, 87 (4), 451-471. doi:10.1002/jctb.3745

Hurtgen, M., Liu, J., Debuigne, A., Jérôme, C., & Detrembleur, C. (15 January 2012). Synthesis of thermo-responsive poly(N-vinylcaprolactam)-containing block copolymers by cobalt-mediated radical polymerization. Journal of Polymer Science. Part A, Polymer Chemistry, 50 (2), 400-408. doi:10.1002/pola.25045

Debuigne, A., Morin, A., Kermagoret, A., Piette, Y., Detrembleur, C., Jérôme, C., & Poli, R. (2012). Key role of intramolecular metal chelation and hydrogen bonding in the cobalt-mediated radical polymerization of N-vinyl amides. Chemistry, 18, 12834-12844. doi:10.1002/chem.201201456

Detrembleur, C., Debuigne, A., Altintas, O., Conradi, M., Wong, E. H. H., Jérôme, C., Barner-Kowollik, C., & Junkers, T. (January 2012). Synthesis of star and H-shape polymers via a combination of cobalt-mediated radical polymerization and nitrone mediated radical coupling reactions. Polymer Chemistry, 3 (1), 135-147. doi:10.1039/c1py00297j

Debuigne, A., Schoumacher, M., Willet, N., Riva, R., Zhu, X., Rütten, S., Jérôme, C., & Detrembleur, C. (28 October 2011). New functional poly(N-vinylpyrrolidone) based (co)polymers via photoinitiated cobalt-mediated radical polymerization. Chemical Communications, 47 (47), 12703-12705. doi:10.1039/c1cc15471k

Boyère, C., Favrelle, A., Broze, G., Laurent, P., Nott, K., Paquot, M., Blecker, C., Jérôme, C., & Debuigne, A. (18 October 2011). Lipase catalysis and thiol-Michael addition: a relevant association for the synthesis of new surface active carbohydrate esters. Carbohydrate Research, 346 (14), 2121-2125. doi:10.1016/j.carres.2011.07.011

Detrembleur, C., Debuigne, A., Hurtgen, M., Jérôme, C., Pinaud, J., Fèvre, M., Coupillaud, P., Vignolle, J., & Taton, D. (23 August 2011). Synthesis of 1-vinyl-3-ethylimidazolium-based ionic liquid (co)polymers by cobalt-mediated radical polymerization. Macromolecules, 44 (16), 6397-6404. doi:10.1021/ma201041s

Favrelle, A., Boyère, C., Laurent, P., Broze, G., Blecker, C., Paquot, M., Jérôme, C., & Debuigne, A. (01 July 2011). Enzymatic synthesis and surface active properties of novel hemifluorinated mannose esters. Carbohydrate Research, 346 (9), 1161-1164. doi:10.1016/j.carres.2011.04.004

Hurtgen, M., Debuigne, A., Fustin, C.-A., Jérôme, C., & Detrembleur, C. (28 June 2011). Organometallic-mediated radical polymerization: unusual route toward (quasi-) diblock graft copolymers starting from a mixture of monomers of opposed reactivity. Macromolecules, 44 (12), 4623-4631. doi:10.1021/ma200845m

Hurtgen, M., Detrembleur, C., Jérôme, C., & Debuigne, A. (29 April 2011). Insight into organometallic-mediated radical polymerization. Polymer Reviews, 51 (2), 188-213. doi:10.1080/15583724.2011.566401

Thomassin, J.-M., Debuigne, A., Jérôme, C., & Detrembleur, C. (24 June 2010). Design of mesoporous carbon fibers from a poly(acrylonitrile) based block copolymer by a simple templating compression moulding process. Polymer, 51 (14), 2965-2971. doi:10.1016/j.polymer.2010.05.010

Georgieva, N., Bryaskova, R., Debuigne, A., & Detrembleur, C. (05 June 2010). Cadmium and copper absorption mediated by a poly(vinyl alcohol)-b-polyacrylonitrile based micelle/Trichosporon cutaneum cell system. Journal of Applied Polymer Science, 116 (5), 2970-2975. doi:10.1002/app.31812

Bryaskova, R., Pencheva, D., Kyulavska, M., Bozukova, D., Debuigne, A., & Detrembleur, C. (15 April 2010). Antibacterial activity of poly(vinyl alcohol)-b-poly(acrylonitrile) based micelles loaded with silver nanoparticles. Journal of Colloid and Interface Science, 344 (2), 424-448. doi:10.1016/j.jcis.2009.12.040

Thomassin, J.-M., Molenberg, I., Huynen, I., Debuigne, A., Alexandre, M., Jérôme, C., & Detrembleur, C. (12 April 2010). Locating carbon nanotubes (CNTs) at the surface of polymer microspheres using poly(vinyl alcohol) grafted CNTs as dispersion co-stabilizers. Chemical Communications, 46 (3330), 3332. doi:10.1039/c000125b

Hurtgen, M., Debuigne, A., Mouithys-Mickalad, A., Jérôme, R., Jérôme, C., & Detrembleur, C. (01 April 2010). Synthesis of poly(vinyl alcohol)/C60 and poly(N-vinylpyrrolidone)/C60 nanohybrids as potential photodynamic cancer therapy agents. Chemistry: An Asian Journal, 5 (4), 859-868. doi:10.1002/asia.200900277

Debuigne, A., Poli, R., De Winter, J., Laurent, P., Gerbaux, P., Wathelet, J.-P., Jérôme, C., & Detrembleur, C. (23 March 2010). Effective cobalt-mediated radical coupling (CMRC) of poly(vinylacetate) and poly(N-vinylpyrrolidone) (co)polymer precursors. Macromolecules, 43 (6), 2801-2813. doi:10.1021/ma902610m

Debuigne, A., Poli, R., De Winter, J., Laurent, P., Gerbaux, P., Dubois, P., Wathelet, J.-P., Jérôme, C., & Detrembleur, C. (01 February 2010). Cobalt mediated radical coupling (CMRC) : an unusual route to midchain-functionalized symmetrical macromolecules. Chemistry, 16 (5), 1799-1811. doi:10.1002/chem.200902618

Hurtgen, M., Debuigne, A., Jérôme, C., & Detrembleur, C. (26 January 2010). Solving the problem of bis(acetylacetonato)cobalt(II)-mediated radical polymerization (CMRP) of acrylic esters. Macromolecules, 43 (2), 886-894. doi:10.1021/ma902310c

Detrembleur, C., Debuigne, A., Jérôme, C., Phan, T. N. T., Bertin, D., & Gigmes, D. (24 November 2009). Joining efforts of nitroxide-mediated polymerization (NMP) and cobalt-mediated radical polymerization (CMRP) for the preparation of novel ABC triblock Copolymers. Macromolecules, 42 (22), 8604-8607. doi:10.1021/ma901839v

Voets, I. K., de Keizer, A., Leermakers, F. A. M., Debuigne, A., Jérôme, R., Detrembleur, C., & Cohen Stuart, M. A. (October 2009). Electrostatic hierarchical co-assembly in aqueous solutions of two oppositevely charged double hydrophilic diblock copolymers. European Polymer Journal, 45 (10), 2913-2925. doi:10.1016/j.eurpolymj.2009.06.020

Bryaskova, R., Willet, N., Duwez, A.-S., Debuigne, A., Lepot, L., Gilbert, B., Jérôme, C., Jérôme, R., & Detrembleur, C. (03 August 2009). Gold-loaded carbon nanoparticles from poly(vinyl alcohol)-b-poly(acrylonitrile) non-shell-cross-linked micelles. Chemistry: An Asian Journal, 4 (8), 1338-1345. doi:10.1002/asia.200900130

Debuigne, A., Poli, R., Jérôme, C., Jérôme, R., & Detrembleur, C. (March 2009). Overview of cobalt-mediated radical polymerization: roots, state of the art and future prospects. Progress in Polymer Science, 34 (3), 211-239. doi:10.1016/j.progpolymsci.2008.11.003

Debuigne, A., Jérôme, C., & Detrembleur, C. (09 February 2009). Isoprene-assisted radical coupling of (co)polymers prepared by cobalt-mediated radical polymerization. Angewandte Chemie International Edition, 48 (8), 1422-1424. doi:10.1002/anie.200804880

Debuigne, A., Michaux, C., Jérôme, C., Jérôme, R., Poli, R., & Detrembleur, C. (28 August 2008). Cobalt-mediated radical polymerization of acrylonitrile: Kinetics investigations and DFT calculations. Chemistry, 14 (25), 7623-7637. doi:10.1002/chem.200800371

Debuigne, A., Warnant, J., Jérôme, R., Voets, I., de Keizer, A., Cohen Stuart, M. A., & Detrembleur, C. (08 April 2008). Synthesis of novel well-defined poly(vinyl acetate)-b-poly(acrylonitrile) and derivatized water-soluble poly(vinyl alcohol)-b-poly(acrylic acid) block copolymers by cobalt-mediated radical polymerization. Macromolecules, 41 (7), 2353-2360. doi:10.1021/ma702341v

Debuigne, A., Champouret, Y., Jérôme, R., Poli, R., & Detrembleur, C. (03 March 2008). Mechanistic Insights into the Cobalt-Mediated Radical Polymerization (CMRP) of Vinyl Acetate with Cobalt(Iii) Adducts as Initiators. Chemistry, 14 (13), 4046-4059. doi:10.1002/chem.200701867

Debuigne, A., Willet, N., Jérôme, R., & Detrembleur, C. (02 October 2007). Amphiphilic poly(vinyl acetate)-b-poly(N-vinylpyrrolidone) and novel double hydrophilic poly(vinyl alcohol)-b-poly(N-vinylpyrrolidone) block copolymers prepared by cobalt-mediated radical polymerization. Macromolecules, 40 (20), 7111-7118. doi:10.1021/ma0712908

Debuigne, A., Chan-Seng, D., Li, L., Hamer, G. K., & Georges, M. K. (21 August 2007). Synthesis and evaluation of sterically hindered 1,1-diamantyl nitroxide as a low-temperature mediator for the stable free radical polymerization process. Macromolecules, 40 (17), 6224-6232. doi:10.1021/ma070691k

Bryaskova, R., Willet, N., Debuigne, A., Jérôme, R., & Detrembleur, C. (01 January 2007). Synthesis of poly(vinyl acetate)-b-polystyrene and poly(vinyl alcohol)-b-polystyrene copolymers by cobalt-mediated radical polymerization. Journal of Polymer Science. Part A, Polymer Chemistry, 45 (1), 81-89. doi:10.1002/pola.21806

Chan-Seng, D., Debuigne, A., & Georges, M. K. (January 2007). Stable free radical polymerization of n-butyl acrylate in the presence of high temperature initiators. European Polymer Journal, 45 (1), 211-216. doi:10.1016/j.eurpolymj.2008.10.017

Bryaskova, R., Detrembleur, C., Debuigne, A., & Jérôme, R. (28 November 2006). Cobalt-mediated radical polymerization (CMRP) of vinyl acetate initiated by redox systems: Toward the scale-up of CMRP. Macromolecules, 39 (24), 8263-8268. doi:10.1021/ma060339r

Sciannamea, V., Debuigne, A., Piette, Y., Jérôme, R., & Detrembleur, C. (2006). Supported cobalt mediated radical polymerization (SCMRP) of vinyl acetate and recycling of the cobalt complex. Chemical Communications, (40), 4180-4182. doi:10.1039/b610455j

Debuigne, A., Radhakrishnan, T., & Georges, M. K. (08 August 2006). Stable free radical polymerization of acrylates promoted by α-hydroxycarbonyl compounds. Macromolecules, 39 (16), 5359-5363. doi:10.1021/ma060288y

Detrembleur, C., Stoilova, O., Bryaskova, R., Debuigne, A., Mouithys-Mickalad, A., & Jérôme, R. (03 April 2006). Preparation of well-defined PVOH/C60 nanohybrids by cobalt-mediated radical polymerization of vinyl acetate. Macromolecular Rapid Communications, 27 (7), 498-504. doi:10.1002/marc.200500871

Li, H., Debuigne, A., Jérôme, R., & Lecomte, P. (27 March 2006). Synthesis of macrocyclic poly(epsilon-caprolactone) by intramolecular cross-linking of unsaturated end groups of chains precyclic by the initiation. Angewandte Chemie International Edition, 45 (14), 2264-2267. doi:10.1002/anie.200503961

Debuigne, A., Caille, J.-R., & Jérôme, R. (01 February 2006). Quinone transfer radical polymerization of styrene: Synthesis of the actual initiator. Journal of Polymer Science. Part A, Polymer Chemistry, 44 (3), 1233-1244. doi:10.1002/pola.21234

Detrembleur, C., Debuigne, A., Bryaskova, R., Charleux, B., & Jérôme, R. (03 January 2006). Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion: Very fast formation of stable poly(vinyl acetate) latexes at low temperature. Macromolecular Rapid Communications, 27 (1), 37-41. doi:10.1002/marc.200500645

Debuigne, A., Caille, J.-R., Willet, N., & Jérôme, R. (15 November 2005). Synthesis of poly(vinyl acetate) and poly(vinyl alcohol) containing block copolymers by combination of cobalt-mediated radical polymerization and ATRP. Macromolecules, 38 (23), 9488-9496. doi:10.1021/ma051246x

Debuigne, A., Caille, J.-R., & Jérôme, R. (25 July 2005). Quinone transfer radical polymerization of styrene catalyzed by metal complexes in the presence of various o-quinones. Macromolecules, 38 (15), 6310-6315. doi:10.1021/ma050076l

Caille, J.-R., Debuigne, A., & Jérôme, R. (01 July 2005). Quinone transfer radical polymerization (QTRP) of styrene: Catalysis by different metal complexes. Journal of Polymer Science. Part A, Polymer Chemistry, 43 (13), 2723-2733. doi:10.1002/pola.20740

Debuigne, A., Caille, J.-R., & Jérôme, R. (28 June 2005). Synthesis of end-functional poly(vinyl acetate) by cobalt-mediated radical polymerization. Macromolecules, 38 (13), 5452-5458. doi:10.1021/ma047726q

Debuigne, A., Caille, J.-R., Detrembleur, C., & Jérôme, R. (11 May 2005). Effective cobalt mediation of the radical polymerization of vinyl acetate in suspension. Angewandte Chemie International Edition, 44 (22), 3439-3442. doi:10.1002/anie.200500112

Debuigne, A., Caille, J.-R., & Jérôme, R. (10 February 2005). Highly efficient cobalt-mediated radical polymerization of vinyl acetate. Angewandte Chemie International Edition, 44 (7), 1101-1104. doi:10.1002/anie.200461333

Caille, J.-R., Debuigne, A., & Jérôme, R. (11 January 2005). Controlled radical polymerization of styrene by quinone transfer radical polymerization (QTRP). Macromolecules, 38 (1), 27-32. doi:10.1021/ma048561o

Debuigne, A., Gérard, J., & Hevesi, L. (06 August 1999). Electrophile induced rearrangement of 1-alkynylaluminium ate complexes. Tetrahedron Letters, 40 (32), 5943-5944. doi:10.1016/S0040-4039(99)01179-X

Articles accepted in journal without reviewing

Debuigne, A., Jérôme, C., & Detrembleur, C. (2011). Polymer design by organometallic-mediated radical polymerization (OMRP). Polymer Preprints of Japan, 60 (2), 2565-2567.

Detrembleur, C., Hurtgen, M., Piette, Y., Jérôme, C., & Debuigne, A. (2011). Advances in cobalt-mediated radical polymerization using Co(acac)2: new reactivities for the design of novel (co)polymers and nanohybrids. Polymer Preprints, 52 (2), 442-443.

Hurtgen, M., Debuigne, A., Fustin, C.-A., Jérôme, C., & Detrembleur, C. (2011). Cobalt-mediated radical copolymerization of conjugated and non-conjugated monomers. Polymer Preprints, 52 (2), 626-627.

Debuigne, A., Jérôme, C., Jérôme, R., Poli, R., & Detrembleur, C. (2008). Metal-coordination: an effective lever for cobalt-mediated radical polymerization. Polymer Preprints, 49 (27), 193-194.

Debuigne, A., Detrembleur, C., Bryaskova, R., Caille, J.-R., & Jérôme, R. (28 August 2005). A new system for the controlled radical polymerization of vinyl acetate. Polymer Preprints, 46 (2), 313-314.

Debuigne, A., Detrembleur, C., Caille, J.-R., Momtaz, A., & Jérôme, R. (2005). Controlled radical polymerization of vinyl acetate based on cobalt(II) acetyl acetonate. Chimie Nouvelle.

Patents

Debuigne, A., Piel, G., Mottet, D., Toussaint, F., Berger, M., Ben Djemaa, S., & Lechanteur, A. (2023). Polymer Derivative and their use as lipid nanoparticle modifiers”.

Takayama, T., Maekawa, K., Detrembleur, C., Debuigne, A., & Jérôme, C. (20 May 2020). Polyvinyl alcohol and method for producing polyvinyl alcohol.

Detrembleur, C., Demarteau, J., Debuigne, A., & Kermagoret, A. (27 June 2019). Block copolymerization of ethylene by cobalt-mediated radical polymerization.

Debuigne, A., Dréan, M., Guégan, P., Jérôme, C., Midoux, P., & Rieger, J. (25 October 2017). Improvement in or relating to organic material.

Takayama, T., Amano, Y., Maekawa, K., Detrembleur, C., Debuigne, A., & Jérôme, C. (05 October 2017). Polyvinyl alcohol and method for producing same.

Bodart, V., Piette, Y., Detrembleur, C., Debuigne, A., & Jérôme, C. (14 June 2012). Controlled radical polymerization of halogenated monomers.

Bodart, V., Piette, Y., Detrembleur, C., Debuigne, A., & Jérôme, C. (14 June 2012). Controlled radical polymerization of halogenated monomers.