Reference : Polymer design by organometallic-mediated radical polymerization (OMRP)

	Document type :	Scientific journals : Article
	Discipline(s) :	Physical, chemical, mathematical & earth Sciences : Chemistry Engineering, computing & technology : Materials science & engineering
	To cite this reference:	http://hdl.handle.net/2268/99618

Title :	Polymer design by organometallic-mediated radical polymerization (OMRP)
Language :	English
Author, co-author :	Debuigne, Antoine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Christine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Detrembleur, Christophe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	2011
Journal title :	Polymer Preprints of Japan
Volume :	60
Issue/season :	2
Pages :	2565-2567
Audience :	International
Keywords :	[en] radical polymerization ; cobalt-mediated radical polymerization (CMRP)
Abstract :	[en] Transition metal-assisted polymerization techniques have always played a crucial role in polymer synthesis. As an illustration, metallic compounds have deeply marked the field of living/controlled radical polymerization (L/CRP) which gives access to well-defined polymers under non drastic conditions. Indeed, atom transfer radical polymerization (ATRP) is one of the most successful methods to polymerize vinyl monomers in a controlled manner. Besides this very successful system, another metal-assisted CRP technique is emerging, i.e. organometallic-mediated radical polymerization (OMRP). In contrast to ATRP, OMRP involves the reversible formation of a covalent bond between a transition metal and the polymer chains, which strongly decreases the extent of termination reactions and leads to polymers with predictable molecular weights. This lecture aims to provide a comprehensive overview of the synthetic and mechanistic aspects of OMRP as well as major achievements and remaining challenges in this field.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/99618

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	Fulltext file(s): File Commentary Version Size Access Restricted access Debuigne A 2011 Polym Preprint Jpn 60 (2), 2565.pdf Publisher postprint 255.38 kB Request copy

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