thiol ene reaction; enzymatic reaction; polymer functionalization
Abstract :
[en] A novel class of surface-active carbohydrate esters is prepared by a two-step strategy that takes advantage of the selectivity of enzymatic catalysis and the versatility of the thiol-Michael addition reaction. The surfactant performance of the produced aliphatic, fluorinated and silicon based sugar esters are evaluated by surface tension measurements. The novel thiolated mannose, made available in this work, appears as a powerful building block for the incorporation of unprotected sugar moieties into complex molecules.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Boyère, Cédric ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Favrelle, Audrey ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Broze, Guy ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Laurent, Pascal ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Unit of Biological and Industrial Chemistry and Unit of General and Organic Chemistry
Nott, Katherine ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Unit of Biological and Industrial Chemistry
Paquot, Michel ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Unit of Biological and Industrial Chemistry
Blecker, Christophe ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Unit of Food Technology
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Lipase catalysis and thiol-Michael addition: a relevant association for the synthesis of new surface active carbohydrate esters
The French Community of Belgium in the frame of the SUPERZYM-ARC program BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
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