Reference : Lipase catalysis and thiol-Michael addition: a relevant association for the synthesis...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/97776
Lipase catalysis and thiol-Michael addition: a relevant association for the synthesis of new surface active carbohydrate esters
English
Boyère, Cédric [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Favrelle, Audrey [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Broze, Guy [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Laurent, Pascal [University of Liège (ULg) > Gembloux Agro-Bio Tech > Unit of Biological and Industrial Chemistry and Unit of General and Organic Chemistry > >]
Nott, Katherine mailto [University of Liège (ULg) > Gembloux Agro-Bio Tech > Unit of Biological and Industrial Chemistry > >]
Paquot, Michel mailto [University of Liège (ULg) > Gembloux Agro-Bio Tech > Unit of Biological and Industrial Chemistry > >]
Blecker, Christophe [University of Liège (ULg) > Gembloux Agro-Bio Tech > Unit of Food Technology > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Debuigne, Antoine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
18-Oct-2011
Carbohydrate Research
Elsevier
346
14
2121-2125
Yes (verified by ORBi)
International
0008-6215
Amsterdam
The Netherlands
[en] thiol ene reaction ; enzymatic reaction ; polymer functionalization
[en] A novel class of surface-active carbohydrate esters is prepared by a two-step strategy that takes advantage of the selectivity of enzymatic catalysis and the versatility of the thiol-Michael addition reaction. The surfactant performance of the produced aliphatic, fluorinated and silicon based sugar esters are evaluated by surface tension measurements. The novel thiolated mannose, made available in this work, appears as a powerful building block for the incorporation of unprotected sugar moieties into complex molecules.
Center for Education and Research on Macromolecules (CERM)
The French Community of Belgium in the frame of the SUPERZYM-ARC program ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Researchers
http://hdl.handle.net/2268/97776
10.1016/j.carres.2011.07.011
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TFF-53C6515-3-2&_cdi=5225&_user=532038&_pii=S0008621511003697&_origin=search&_zone=rslt_list_item&_coverDate=07%2F21%2F2011&_sk=999999999&wchp=dGLbVzz-zSkzk&md5=f14e89f7dcee056ceb97e9a6ca021998&ie=/sdarticle.pdf

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