Article (Scientific journals)
Synthesis and deposition of water-dispersed prussian blue nanocrystals on polymers and CNTs
Boccharova, Vera; Gorodyska, Ganna; Kiriy, Anton et al.
2006In Progress in Colloid and Polymer Science, 132, p. 161-167
Peer reviewed
 

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Keywords :
carbon nanotube
Abstract :
[en] Nanoparticles can be used for decoration and functionalization of single polymer molecules that have been adsorbed to a solid substrate. Initial attempts to prepare Prussian Blue nanoclusters by a layer-by-layer deposition technique of hexacyanoferrate anions and ferric cations onto isolated polycation chains in water failed because of the desorption of the first layer upon deposition of the next one. A simple method for the preparation of charge-stabilized Prussian Blue nanoparticles of readily adjustable size is reported. Prussian Blue nanoparticles have been purified by addition of non-solvents and redispersed in water without aggregation. Thus formed Prussian Blue nanoparticles are crystalline and display a long-range ferromagnetic ordering at 5.1 K. Prussian Blue nanoparticles were selectively deposited along single polycation molecules to form a one-dimensional array or were attached to the surface of carbon nanotubes (CNTs) functionalized with poly2-vinylpyridine (P2VP). These nanoparticle-based nanostructures might be useful materials for manufacture of electrooptical devices, or mechanically robust ion-sieving membranes.
Research center :
the “Deutsche Forschungsgemeinschaft” (DFG)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Boccharova, Vera;  Leibniz-Institut für Polymerforschung Dresden, Dresden, Germany
Gorodyska, Ganna;  Leibniz-Institut für Polymerforschung Dresden, Dresden, Germany
Kiriy, Anton;  Leibniz-Institut für Polymerforschung Dresden, Dresden, Germany
Stamm, Manfred;  Leibniz-Institut für Polymerforschung Dresden, Dresden, Germany
Simon, Paul;  Max-Planck-Institut for Chemical Physics, Dresden, Germany
Mönch, Ingolf;  Leibniz Institute for Solid State and Materials Research Dresden, Dresden, Germany
Elefant, Dieter;  Leibniz Institute for Solid State and Materials Research Dresden, Dresden, Germany
Lou, Xudong;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Stoffelbach, François;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Synthesis and deposition of water-dispersed prussian blue nanocrystals on polymers and CNTs
Publication date :
2006
Journal title :
Progress in Colloid and Polymer Science
ISSN :
0340-255X
Publisher :
Springer
Volume :
132
Pages :
161-167
Peer reviewed :
Peer reviewed
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
DFG - Deutsche Forschungsgemeinschaft [DE]
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