Reference : Chapter 7 NHC-Iron, Ruthenium and Osmium Complexes in Catalysis
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Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/93598
Chapter 7 NHC-Iron, Ruthenium and Osmium Complexes in Catalysis
English
Delaude, Lionel mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique]
Demonceau, Albert mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
2011
N-Heterocyclic Carbenes
Diez-Gonzalez, Silvia
The Royal Society of Chemistry
196-227
978-1-84973-042-6
Cambridge
United Kingdom
[en] In this Chapter, the catalytic applications of organometallic species -either pre-formed or generated in situ- based on Group 8 transition metals and N-heterocyclic carbene (NHC) ligands are surveyed. Thus far, only a few reports on the use of NHC-Fe complexes in organic catalysis are available, although significant work has been reported in the related field of biocatalysis. Contrastingly, the chemistry of NHC-Ru complexes has reached an unprecedented level of maturity, thanks to the relentless research efforts thrown into the development of olefin metathesis catalysts. Other carbon skeletal transformations based on NHC-Ru promoters include cyclopropanation, allylation, or cycloisomerisation reactions. Lastly, with only two reports to date concerning olefin metathesis and transfer hydrogenation, NHC-Os-based catalysis can hardly be considered anything else than a curiosity.
Researchers ; Professionals
http://hdl.handle.net/2268/93598
10.1039/9781849732161-00196

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