Reference : Exfoliated polylactide/clay nanocomposites by in-situ coordination-insertion polymerizat...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/9054
Exfoliated polylactide/clay nanocomposites by in-situ coordination-insertion polymerization
English
Paul, Marie-Amélie [University of Mons-Hainaut (UMH) > > Laboratory of Polymeric and Composite Materials (LPCM) > >]
Alexandre, Michaël mailto [University of Mons-Hainaut (UMH) > > Laboratory of Polymeric and Composite Materials (LPCM) > >]
Degée, Philippe [University of Mons-Hainaut (UMH) > > Laboratory of Polymeric and Composite Materials (LPCM) > >]
Calberg, Cédric mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Dubois, Philippe [University of Mons-Hainaut (UMH) > > Laboratory of Polymeric and Composite Materials (LPCM) > >]
16-Jun-2003
Macromolecular Rapid Communications
Wiley-V C H Verlag Gmbh
24
9
561-566
Yes (verified by ORBi)
International
1022-1336
Weinheim
[en] nanostructured material ; nanocomposite ; clay ; ring-opening polymerization (ROP) ; lactone
[en] Poly(L-lactide)/layered aluminosilicate nanocomposites were synthesized in bulk by ring-opening polymerization in the presence of two organo-modified montmorillonites. When the organo-modifier consisted of an ammonium cation bearing primary hydroxyl groups, polymerization was initiated by the alcohol functions after adequate activation. The growing polymer chains were directly "grafted" onto the clay surface through the hydroxyl-functionalized ammonium cations yielding exfoliated nano-composites with enhanced thermal stability.
Center for Education and Research on Macromolecules (CERM)
Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; The "Région wallonne" and the European Community (FEDER, FSE) in the frame of "Pôle d'excellence Materia Nova" ; The "Région wallonne" in the frame of the WDU program TECMAVER
Researchers
http://hdl.handle.net/2268/9054
10.1002/marc.200390082
http://www3.interscience.wiley.com/cgi-bin/fulltext/104536522/PDFSTART

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