Reference : The photoabsorption and Constant Ion State Spectroscopy of Vinyl Bromide.
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/888
The photoabsorption and Constant Ion State Spectroscopy of Vinyl Bromide.
English
[fr] La spectroscopie de photoabsorption et à état ionique constant du Bromure de vinyle.
Hoxha, A. [ > > ]
Locht, Robert mailto [Université de Liège - ULg > Département de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences) > >]
Leyh, Bernard mailto [Université de Liège - ULg > Département de chimie (sciences) > Laboratoire de dynamique moléculaire >]
Dehareng, Dominique mailto [Université de Liège - ULg > > Centre d'ingénierie des protéines >]
Hottmann, K. [ > > ]
Jochims, H.-W. [Freie Universität Berlin > > Institut für Physikalische Chemie > >]
Baumgärtel, H. [Freie Universität Berlin > > Institut für Physikalische Chemie > >]
2000
Chemical Physics
Elsevier Science
260
237-247
Yes (verified by ORBi)
International
0301-0104
Amsterdam
The Netherlands
[en] Photoabsorption spectroscopy ; CIS Spectroscopy ; Rydberg series ; Vibrational analysis ; C2H3Br
[en] In this paper we report the photoabsorption and the constant ion state spectroscopy of vinyl bromide (C2H3Br). The photoabsorption spectrum was measured using synchrotron radiation and was investigated in detail between 5.0 and 12.0 eV photon energy revealing many previously unobserved structures. These features were analyzed in terms of valence to virtual valence transitions and Rydberg series. The examination of the three Rydberg series converging towards the first ionization threshold (2a"->ns, 2a"->np and 2a"->nd) leads to wavenumbers of 335+/-30, 690+/-30 and 1305+/-30 cm-1. The vibrational wavenumbers of the progressions belonging to Rydberg series converging towards the second ionization threshold are 485+/-30 and 1145+/-50 cm-1. Ab initio calculations helped the assignment of the valence transitions and of the observed vibrational wave numbers in the Rydberg series.
Constant Ionic State spectra were recorded for vibronic states corresponding to the first and the second electronic states of the ion. Their fine structures are assigned to the autoionization of Rydberg states. The autoionization decay of these Rydberg states is analyzed qualitatively in terms of the vibrational nature of the final ionic state.
Laboratoire de Dynamique Moléculaire
ARC, EU Contract n° ERBFMGE-CT97-0123 in EU-TMR Programme
Researchers
http://hdl.handle.net/2268/888
http://www.sciencedirect.com/science/journal/03010104
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