Electrospinning of a functional perfluorinated block copolymer as a powerful route for imparting superhydrophobicity and corrosion resistance to aluminum substrates

Grignard, Bruno; Vaillant, Alexandre; de Coninck, Joel; Piens, Marcel; Jonas, Alain M.; Detrembleur, Christophe; Jérôme, Christine

doi:10.1021/la102808w

Article (Scientific journals)

Electrospinning of a functional perfluorinated block copolymer as a powerful route for imparting superhydrophobicity and corrosion resistance to aluminum substrates

Grignard, Bruno; Vaillant, Alexandre; de Coninck, Joel et al.

2011 • In Langmuir, 27 (1), p. 335-342

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/87318

DOI
10.1021/la102808w

PubMed
21141949

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Keywords :

coating; superhydrophobic coating; electrospinning

Abstract :

[en] Superhydrophobic aluminum surfaces with excellent corrosion resistance were successfully prepared by electrospinning of a novel fluorinated diblock copolymer solution. Micro- and nanostructuration of the diblock copolymer coating was obtained by electrospinning which proved to be an easy and cheap electrospinning technology to fabricate superhydrophobic coating. The diblock copolymer is made of poly(heptadecafluorodecylacrylate-co-acrylic acid) (PFDA-co-AA) random copolymer as the first block and polyacrylonitrile (PAN) as the second one. The fluorinated block promotes hydrophobicity to the surface by reducing the surface tension, while its carboxylic acid functions anchor the polymer film onto the aluminum surface after annealing at 130 °C. The PAN block of this copolymer insures the stability of the structuration of the surface during annealing, thanks to the infusible character of PAN. It is also demonstrated that the so-formed superhydrophobic coating shows good adhesion to aluminum surfaces, resulting in excellent corrosion resistance.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Vaillant, Alexandre; University of Mons (UMons) > Laboratory for Physics of Surfaces and Interfaces (LPSI)

de Coninck, Joel; University of Mons (UMons) > Laboratory for Physics of Surfaces and Interfaces (LPSI)

Piens, Marcel; Coating Research Institute (CoRI)

Jonas, Alain M.; Université catholique de Louvain (UCL) > Institute of Condensed Matter and Nanosciences

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Electrospinning of a functional perfluorinated block copolymer as a powerful route for imparting superhydrophobicity and corrosion resistance to aluminum substrates

Publication date :

04 January 2011

Journal title :

Langmuir

ISSN :

0743-7463

eISSN :

1520-5827

Publisher :

American Chemical Society, Washington, United States - District of Columbia

Volume :

Issue :

Pages :

335-342

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/la102808w

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
The "Region Wallonne" in the frame of the CORRONET project

Available on ORBi :

since 18 March 2011

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Bibliography

Li, X.-M.; Reinhoudt, D.; Crego-Calama, M. Chem. Soc. Rev. 2007, 36, 1350-1368
Blossey, R. Nat. Mater. 2003, 2, 301
Furstner, R.; Barthlott, W.; Neinhuis, C.; Walzel, P. Langmuir 2005, 21, 956
Miwa, M.; Nakajima, A.; Fujishima, A.; Hashimoto, K.; Watanabe, T. Langmuir 2000, 16, 5754
Nakajima, A.; Hashimoto, K.; Watanabe, T.; Takai, K.; Yamauchi, G.; Fujishima, A. Langmuir 2000, 16, 7044
Otten, A.; Herminghaus, S. Langmuir 2004, 20, 2405
Barthlott, W.; Neinhuis, C. Planta 1997, 202, 1
Lafuma, A.; Quere, D. Nat. Mater. 2003, 2, 457
Saito, H.; Takai, K.; Takazawa, H.; Yamauchi, G. Mater. Sci. Res. Int. 1997, 3, 216
Kako, T.; Nakajima, A.; Irie, H.; Kato, Z.; Uematsu, K.; Watanabe, T.; Hashimoto, K. J. Mater. Sci. 2004, 39, 547
Furstner, R.; Barthlott, W.; Neinhuis, C.; Walzel, P. Langmuir 2005, 21, 956
Callies, M.; Chen, Y.; Marty, F.; Pepin, A.; Quere, D. Microelectron. Eng. 2005, 78-79, 100
Abdelsalam, M.; Bartlett, P.; Kelf, T.; Baumberg, J. Langmuir 2005, 21, 1753
Teshima, K.; Sugimura, H.; Inoue, Y.; Takai, O.; Takano, A. Appl. Surf. Sci. 2005, 244, 619
Song, X.; Zhai, J.; Wang, Y.; Jiang, L. J. Phys. Chem. B 2005, 109, 4048
Qian, B.; Shen, Z. Langmuir 2005, 21, 9007
Guo, Z.; Zhou, F.; Hao, J.; Liu, W. J. Am. Chem. Soc. 2005, 127, 15670
Li, M.; Zhai, J.; Liu, H.; Song, Y. L.; Jiang, L.; Zhu, D. J. Phys. Chem. B 2003, 107, 9954
Zhao, N.; Shi, F.; Wang, Z. Q.; Zhang, X. Langmuir 2005, 21, 4713
Shi, F.; Wang, Z. Q.; Zhang, X. Adv. Mater. 2005, 17, 1005
Ma, M.; Mao, Y.; Gupta, M.; Gleason, K.; Rutledge, G. Macromolecules 2005, 38, 9742
Liu, H.; Feng, L.; Zhai, J.; Jiang, L.; Zhu, D. Langmuir 2004, 20, 5659
Honoso, E.; Fujihara, S.; Honma, I.; Zhou, H. J. Am. Chem. Soc. 2005, 127, 13458
Riboo, R.; Voue, M.; Vaillant, A.; Seveno, D.; Conti, J.; Bondar, A. I.; Ivanov, D. A.; De Coninck, J. Langmuir 2008, 24, 9508
Han, J. T.; Zheng, Y.; Cho, J. H.; Xu, X.; Cho, K. J. Phys. Chem. B 2005, 109, 20773
Soeno, T.; Inokuchi, K.; Shiratori, S. Appl. Surf. Sci. 2004, 237, 543
Desbief, S.; Grignard, B.; Detrembleur, C.; Rioboo, R.; Vaillant, A.; Seveno, D.; Voué, M.; De Coninck, J.; Jerome, C.; Damman, P.; Lazzaroni, R. Langmuir 2009, 26 (3) 2057
Jung, D.; Park, I. J.; Choi, Y.; Lee, S.; Park, H.; Ruhe, J. Langmuir 2002, 18, 6133
Li, X.; Cao, Z.; Liu, F.; Zhang, Z.; Dang, H. Chem. Lett. 2006, 35, 94
Mahltig, B.; Bottcher, H. J. Sol-Gel Sci. Technol. 2003, 27, 43
Makita, K.; Akamatsu, Y.; Yamazaki, S.; Kai, Y.; Abe, Y. J. Ceram. Soc. Jpn. 1997, 105, 1012
Nakagawa, T.; Soga, M. J. Non-Cryst. Solids 1999, 260, 167
Rao, A.; Kulkarni, M.; Amalnerkar, D.; Seth, T. J. Non-Cryst. Solids 2003, 330, 187
Roig, A.; Molins, E.; Rodriguez, E.; Martinez, S.; Moreno-Manas, M.; Vallribera, A. Chem. Commun. 2004, 2316
Shirtcliffe, N.; McHale, G.; Newton, M.; Perry, C. Langmuir 2003, 19, 5626
Acatay, K.; Şimşek, E.; Ow-Yang, C.; Menceloǧlu, Y. Angew. Chem., Int. Ed. 2004, 43, 5210
Singh, A.; Steely, L.; Allcock, H.; Harry Langmuir 2005, 21, 11604
Ma, M.; Hill, R.; Lowery, J.; Fridrikh, S.; Rutledge, G. Langmuir 2005, 21, 5549-5554
Zhu, Y.; Zhang, J.; Zheng, Y.; Huang, Z.; Feng, L.; Jiang, L. Adv. Func. Mater. 2006, 16, 568
Lim, J.-M.; Yi, G.-R; Moon, J.; Heo, C.-J.; Yang, S.-M.; Seung-Man Langmuir 2007, 23, 7981
Ma, M.; Gupta, M.; Li, Z.; Zhai, L.; Gleason, K.; Cohen, R.; Rubner, M.; Rutledge, G.; Gregory Adv. Mater. 2007, 19, 255
Zhu, Y.; Feng, L.; Xia, F.; Zhai, J.; Wan, M.; Jiang, L. Macromol. Rapid Commun. 2007, 28, 1135-1141
Zhu, M.; Zuo, W.; Yu, H.; Yang, W.; Chen, Y. J. Mater. Sci. 2006, 41, 3793
Han, D.; Steckl, A. Langmuir 2009, 25, 9454
Valtola, L.; Koponen, A.; Karesoja, M.; Hietala, S.; Laukkanen, A.; Tenhu, H.; Denifl, P. Polymer 2009, 50, 3103
Deitzel, J.; Kosik, W.; McKnight, S.; Beck Tan, N; Desimone, J. M.; Crette, S. Polymer 2002, 43, 1025
Gaines, G. L. J. Chem. Phys. 1969, 73, 3143
Schmitt, R.; Gardella, J.; Magill, J.; Salvati, L. Macromolecules 1985, 18, 2675
Pan, D.; Prest, W J. Appl. Phys. 1985, 58, 2861
Bhatia, Q.; Pan, D; Koberstein, J Macromolecules 1988, 21, 2166
Thomas, R.; Anton, R; Graham, D; Darmon, W; Sauer, M; Stika, B; Swartzfager, K Macromolecules 1997, 30, 2883
Montefusco, F.; Bongiovanni, R.; Priola, A.; Ameduri, B. Macromolecules 2004, 37, 9804
Fir, M.; Orel, B.; Vuk, A. S.; Vilcnik, A.; Jese, R.; Francetic, V. Langmuir 2007, 23, 5505
Alexander, M; Payan, S.; Duc, T. M. Surf. Interface Anal. 1998, 26 (13) 961