Reference : The Dissociative Ionization of C2H2. The C+, C2+ and CH2+ Dissociation Channels. The ...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/872
The Dissociative Ionization of C2H2. The C+, C2+ and CH2+ Dissociation Channels. The Vinylidene Ion as a Transient?
English
[fr] L'ionisation dissociative de C2H2. Les canaux de dissociation conduisant à C+, C2+ et CH2+. L'ion vinylidene comme espèce transitoire?
Locht, Robert mailto [Université de Liège - ULg > Département de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences) > >]
Davister, M. [ > > ]
1995
Chemical Physics
Elsevier Science
195
443-456
Yes (verified by ORBi)
International
0301-0104
Amsterdam
The Netherlands
[en] Electroionization ; Dissociation ; Kinetic energy ; Appearance energy ; C+, C2+, CH2+ ; C2H2 ; Transient vinylidene
[en] The dissociative electroionization of C2H2 has been investigated in the C+, C2+ and CH2+ dissociation channels. Both the translational energy and the appearance energies have been measured. The kinetic energy versus appearance energy diagrams related to these species are discussed in detail and dissociation mechanisms are proposed for all observed onset energies. For the three ionic species, the dissociation pathways leading to the fragmentation of C2H2+ into C+, C2+ and CH2+ successively have to run very likely over an isomerization mechanism of the molecular ion. The isomeric vinylidene structure could be the most probable intermediate.
Laboratoire de Dynamique Moléculaire
ARC, FRFC
Researchers
http://hdl.handle.net/2268/872
http://www.sciencedirect.com/science/journal/03010104
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