Article (Scientific journals)
Nanostructured PMMA: from lamellar sheets to double-layered vesicles
Koulic, Christian; Jérôme, Robert
2004In Macromolecules, 37 (3), p. 888-893
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Keywords :
nanostructured material; polymer blend; self assembly in bulk
Abstract :
[en] PMMA was nanostructured by similar to100 nm liposome-like vesicular objects by melt blending with 20 wt % of a symmetric poly(styrene)-b-poly(isoprene)-b-poly(methyl methacrylate) (PS-b-PIP-b-PMMA) triblock copolymer in the dry-brush regime. Whenever the blend was prepared by casting toluene solution, thus under zero-shear conditions, a continuous network of lamellar copolymer sheets was formed in PMMA, which however underwent a transition to the aforementioned vesicles upon application of large amplitude oscillatory shear.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Koulic, Christian;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Nanostructured PMMA: from lamellar sheets to double-layered vesicles
Publication date :
10 February 2004
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
Amer Chemical Soc, Washington, United States - Washington
Volume :
37
Issue :
3
Pages :
888-893
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
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