Article (Scientific journals)
Na(1.50)Mn(2.48)Al(0.85)(Po4)3, a New Synthetic Alluaudite-Type Compound
Hatert, Frédéric
2006In Acta Crystallographica. Section C, Crystal Structure Communications, 62 (Pt 1), p. 1-i2
Peer Reviewed verified by ORBi
 

Files


Full Text
Na2Mn2Al(PO4)3.pdf
Publisher postprint (186.18 kB)
Download

All documents in ORBi are protected by a user license.

Send to



Details



Abstract :
[en] The first hydrothermal synthesis of an Al-rich alluaudite-type compound, namely disodium dimanganese aluminium tris(phosphate), which has been obtained at 1073 K and 0.1 GPa starting from the composition Na2Mn2Al(PO4)(3), is reported. The crystal structure, which has been refined in the monoclinic C2/c space group, is identical to that of natural alluaudite. The structure consists of kinked chains of edge-sharing M1 and M2 octahedra, which contain Mn2+ and Al3+ ions. The chains are stacked parallel to {101} and are connected in the b direction by the P1 and P2 tetrahedra. These interconnected chains produce channels parallel to c, which contain the large A1 and AT sites occupied by Na+ and Mn2+ ions.
Disciplines :
Chemistry
Earth sciences & physical geography
Author, co-author :
Hatert, Frédéric  ;  Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie
Language :
English
Title :
Na(1.50)Mn(2.48)Al(0.85)(Po4)3, a New Synthetic Alluaudite-Type Compound
Publication date :
January 2006
Journal title :
Acta Crystallographica. Section C, Crystal Structure Communications
ISSN :
0108-2701
eISSN :
1600-5759
Publisher :
Blackwell Publishing, Oxford, United Kingdom
Volume :
62
Issue :
Pt 1
Pages :
i1-i2
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 05 March 2009

Statistics


Number of views
62 (1 by ULiège)
Number of downloads
5 (0 by ULiège)

Scopus citations®
 
18
Scopus citations®
without self-citations
15
OpenCitations
 
12

Bibliography


Similar publications



Contact ORBi