Reference : Na(1.50)Mn(2.48)Al(0.85)(Po4)3, a New Synthetic Alluaudite-Type Compound
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Physical, chemical, mathematical & earth Sciences : Earth sciences & physical geography
http://hdl.handle.net/2268/7847
Na(1.50)Mn(2.48)Al(0.85)(Po4)3, a New Synthetic Alluaudite-Type Compound
English
Hatert, Frédéric mailto [Université de Liège - ULg > Département de géologie > Minéralogie et cristallochimie >]
Jan-2006
Acta Crystallographica Section C-Crystal Structure Communications
Blackwell Publishing
62
Pt 1
i1-i2
Yes (verified by ORBi)
International
0108-2701
1600-5759
Oxford
[en] The first hydrothermal synthesis of an Al-rich alluaudite-type compound, namely disodium dimanganese aluminium tris(phosphate), which has been obtained at 1073 K and 0.1 GPa starting from the composition Na2Mn2Al(PO4)(3), is reported. The crystal structure, which has been refined in the monoclinic C2/c space group, is identical to that of natural alluaudite. The structure consists of kinked chains of edge-sharing M1 and M2 octahedra, which contain Mn2+ and Al3+ ions. The chains are stacked parallel to {101} and are connected in the b direction by the P1 and P2 tetrahedra. These interconnected chains produce channels parallel to c, which contain the large A1 and AT sites occupied by Na+ and Mn2+ ions.
Researchers ; Professionals ; Students
http://hdl.handle.net/2268/7847
10.1107/S0108270105037236

File(s) associated to this reference

Fulltext file(s):

FileCommentaryVersionSizeAccess
Restricted access
Na2Mn2Al(PO4)3.pdfPublisher postprint181.81 kBRequest copy

Bookmark and Share SFX Query

All documents in ORBi are protected by a user license.