ORBi: Naeem Saira - Non-innocent Behaviour of Dithiocarboxylate Ligands Based on N-Heterocyclic Carbenes

Reference : Non-innocent Behaviour of Dithiocarboxylate Ligands Based on N-Heterocyclic Carbenes


	Document type :	Scientific journals : Article
	Discipline(s) :	Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/75806

Title :	Non-innocent Behaviour of Dithiocarboxylate Ligands Based on N-Heterocyclic Carbenes
Language :	English
Author, co-author :	Naeem, Saira [> > > >]
	Thompson, Amber L. [> > > >]
	Delaude, Lionel [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
	Wilton-Ely, James D. E. T. [> > > >]
Publication date :	2010
Journal title :	Chemistry : A European Journal
Publisher :	Wiley
Volume :	16
Issue/season :	36
Pages :	10971-10974
Audience :	International
ISSN :	0947-6539
e-ISSN :	1521-3765
City :	Weinheim
Country :	Germany
Keywords :	[en] alkene lignads ; carbene ligands ; dithiocarboxylates ; ruthenium
Abstract :	[en] The ruthenium(II) complex [Ru(CH=CHC6H4Me-4)(κ2-S2C•NHC)(CO)(PPh3)2]+ is formed on reaction of NHC•CS2 (NHC = ICy, IMes) with [Ru(CH=CHC6H4Me-4)Cl(CO)(BTD)(PPh3)2] in the presence of NH4PF6, whereas the analogous reaction with the more bulky IDip•CS2 leads to the remarkable product, [Ru{κ2-SC(H)S(CH=CHC6H4Me-4)•IDip}Cl(CO)(PPh3)2]+.
Target :	Researchers ; Professionals
Permalink :	http://hdl.handle.net/2268/75806
DOI :	10.1002/chem.201001235

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