Synthesis of pyrene-containing polymers and noncovalent sidewall functionalization of multiwalled carbon nanotubes
English
Lou, Xudong[University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Daussin, Raphaël[Université catholique de Louvain (UCL) > > Laboratory for Physics and Chemistry of Polymers (POLY) > >]
Cuenot, Stéphane[Université catholique de Louvain (UCL) > > Laboratory for Physics and Chemistry of Polymers (POLY) > >]
Duwez, Anne-Sophie[Université catholique de Louvain (UCL) > > Laboratory for Physics and Chemistry of Polymers (POLY) > Present address: NanoChemistry and Molecular Systems, Department of Chemistry, University of Liège (ULg) >]
Pagnoulle, Christophe[University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Detrembleur, Christophe[University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Bailly, Christian[Université catholique de Louvain (UCL) > > Laboratory for Physics and Chemistry of Polymers (POLY) > >]
Jérôme, Robert[University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
[en] Pyrene-containing polymers have been prepared for noncovalent sidewall functionalization of multiwalled carbon nanotubes (MWNTs). (1-Pyrene)methyl 2-methyl-2-propenoate (PyM-MP) has been synthesized and copolymerized with methyl methacrylate (MMA). Poly(ethylene-co-butylene)-b-poly(MMA-co-PyMMP) diblocks have also been synthesized. The surface of MWNTs, produced by both the CCVD and arc discharge methods, has been modified by these copolymers for making them dispersible in a variety of organic solvents. The modified MWNTs have been characterized by thermogravimetric analysis, transmission electron microscopy, and atomic force microscopy.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; The “Région Wallonne” in the frame of the “Nanotechnologies” program (ENABLE project)