Reference : Electrografting of thin polymer films: Three strategies for the tailoring of functional ...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/7015
Electrografting of thin polymer films: Three strategies for the tailoring of functional adherent coatings
English
Voccia, Samuel [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Gabriel, Sabine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Serwas, Harry [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
1-Feb-2006
Progress in Organic Coatings
Elsevier
55
2
175-181
Yes (verified by ORBi)
International
0300-9440
Lausanne
[en] electropolymerization ; electrografting
[en] Cathodic electrografting is an efficient technique to impart adhesion to poly(meth)acrylate coatings onto inorganic conducting surfaces. Although this technique was restricted for many years to very few monomers ((meth)acrylonitrile and (meth)acrylates) and to deposition of very thin polymer films, recent developments have overcome these limitations. First of all, classical controlled/living polymerization techniques have been combined with cathodic electrografting as a powerful strategy for tuning thickness, properties and reactivity of the chemisorbed organic films. Secondly, thanks to the successful electrografting of a new reactive monomer bearing an activated ester, electrografted surfaces are now available for further derivatization by a wide variety of nucleophiles. Finally, the electrografting process has been extended to the direct electrografting of reactive polymers, i.e. preformed polymers beating pendant acrylic functions, which opens the way to the grafting of, e.g., polycondensates.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Researchers
http://hdl.handle.net/2268/7015
10.1016/j.porgcoat.2005.08.012
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6THD-4J79BP0-2-Y&_cdi=5280&_user=532038&_orig=browse&_coverDate=02%2F01%2F2006&_sk=999449997&view=c&wchp=dGLbVtb-zSkWA&md5=9032165095542e053ad3f727f080e227&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/504100/description#description
The authors acknowledge Progress in Organic Coatings (Elsevier) for allowing them to archive this paper.

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