Reference : Sequential electrografting and ring opening metathesis polymerization: a strategy for th...
Scientific journals : Article
Engineering, computing & technology : Materials science & engineering
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/6985
Sequential electrografting and ring opening metathesis polymerization: a strategy for the tailoring of conductive surfaces
English
Voccia, Samuel [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Claes, Michael [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
19-May-2005
Macromolecular Rapid Communications
Wiley-V C H Verlag Gmbh
26
10
779-783
Yes (verified by ORBi)
International
1022-1336
Weinheim
[en] electropolymerization ; electrografting ; ring-opening metathesis polymerization (ROMP)
[en] An electrografting technique has been combined with ring-opening metathesis polymerization (ROMP). Poly(allyl methacrylate) chains have been chemisorbed onto steel and carbon plates under an appropriate cathodic potential in N,N-dimethylformamide. The allyl moieties have been converted into Ru catalysts active in ROMP of norbornene and its derivatives. Initiation of ROMP from the surface is an efficient strategy to prepare strongly adhering coatings of tunable thickness and hydrophilic/hydrophobic balance, depending on the norbornene derivative polymerized at the surface.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Researchers
http://hdl.handle.net/2268/6985
10.1002/marc.200500035
http://www3.interscience.wiley.com/cgi-bin/fulltext/110485353/PDFSTART

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