ORBi: Voccia Samuel - Sequential electrografting and ring opening metathesis polymerization: a strategy for the tailoring of conductive surfaces

Reference : Sequential electrografting and ring opening metathesis polymerization: a strategy for th...


	Document type :	Scientific journals : Article
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/6985

Title :	Sequential electrografting and ring opening metathesis polymerization: a strategy for the tailoring of conductive surfaces
Language :	English
Author, co-author :	Voccia, Samuel [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Claes, Michael [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Christine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	19-May-2005
Journal title :	Macromolecular Rapid Communications
Publisher :	Wiley-V C H Verlag Gmbh
Volume :	26
Issue/season :	10
Pages :	779-783
Audience :	International
ISSN :	1022-1336
City :	Weinheim
Keywords :	[en] electropolymerization ; electrografting ; ring-opening metathesis polymerization (ROMP)
Abstract :	[en] An electrografting technique has been combined with ring-opening metathesis polymerization (ROMP). Poly(allyl methacrylate) chains have been chemisorbed onto steel and carbon plates under an appropriate cathodic potential in N,N-dimethylformamide. The allyl moieties have been converted into Ru catalysts active in ROMP of norbornene and its derivatives. Initiation of ROMP from the surface is an efficient strategy to prepare strongly adhering coatings of tunable thickness and hydrophilic/hydrophobic balance, depending on the norbornene derivative polymerized at the surface.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/6985
DOI :	10.1002/marc.200500035
Other URL :	http://www3.interscience.wiley.com/cgi-bin/fulltext/110485353/PDFSTART

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