Reference : Sur les modifications subies par quelques phosphates acides à la suite d'une compression...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/68024
Sur les modifications subies par quelques phosphates acides à la suite d'une compression ou d'une déformation mécanique
French
[en] On the Modifications Undergone by some Acid Phosphates Under the Influence of Compression or Mechanical Deformation
Spring, Walthère [Université de Liège - ULg]
1907
Recueil des Travaux Chimiques des Pays-Bas et de la Belgique
Sijthoff
XXVI
188-202
No
International
0370-7539
Leiden
Netherlands
[en] Pressure ; Diffusion in solids ; Phosphates ; Mechanical properties
[fr] Pression ; Diffusion dans les solides ; Phosphates ; Déformation mécanique
[en] Spring, W. Recueil des Travaux Chimiques des Pays-Bas et de la Belgique (1907), 26, 188-202; SciFinder (Chemical Abstracts Service: Columbus, OH); https://scifinder.cas.org (accessed July 8, 2010).

The author subjected several acid phosphates to high pressures in a specially constructed cylinder with the following results: Ca(H2PO4)2H2O loses first its water of crystallization and finally a portion of the phosphoric acid, these two constituents being forced out of the compression cylinder. In general those constituents which were capable of liquefying under the pressure were found to be eliminated most readily. The acid phosphates of calcium, sodium and probably lithium form molecular compounds with their respective sulphates, that of calcium being insoluble in water and probably constituting one of the causes of reversion.

Reprinted with the permission of the American Chemical Society. Copyright © 2010. American Chemical Society (ACS). All Rights Reserved.
Researchers ; Professionals ; Students
http://hdl.handle.net/2268/68024
Voir aussi :
http://hdl.handle.net/2268/68100
http://hdl.handle.net/2268/68154
http://hdl.handle.net/2268/68110

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