Reference : Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion: Very fast forma...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/6247
Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion: Very fast formation of stable poly(vinyl acetate) latexes at low temperature
English
Detrembleur, Christophe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Debuigne, Antoine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Bryaskova, Rayna [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Charleux, Bernadette [Université Pierre et Marie Curie > > Laboratoire de Chimie des Polymères > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
3-Jan-2006
Macromolecular Rapid Communications
Wiley-V C H Verlag Gmbh
27
1
37-41
Yes (verified by ORBi)
International
1022-1336
Weinheim
[en] radical polymerization ; cobalt-mediated radical polymerization (CMRP) ; vinyl acetate
[en] Poly(vinyl acetate) macroinitiators end-capped by a Co(acac)(2) complex (PVAc-Co(acac)(2)), prepared in bulk by cobalt-mediated radical polymerization (CMRP), are used for the controlled radical polymerization of vinyl acetate in miniemulsion to give high-molecular-weight polymers and high monomer conversion. Stable poly(vinyl acetate) latexes with solid contents ranging from 25 to 30 wt.-% are prepared within unusually short reaction times (similar to 1 h) at low temperatures (0-30 degrees C).
Center for Education and Research on Macromolecules (CERM)
Solvay ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Researchers
http://hdl.handle.net/2268/6247
10.1002/marc.200500645
http://www3.interscience.wiley.com/cgi-bin/fulltext/112217675/PDFSTART

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