Reference : Thermal Energy Distribution Observed in Electrospray Ionization
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/4515
Thermal Energy Distribution Observed in Electrospray Ionization
English
Drahos, Laszlo [FOM Institute for Atomic and Molecular Physics > > > >]
Heeren, Ron [FOM Institute for Atomic and Molecular Physics > > > >]
Collette, Caroline mailto [Université de Liège - ULg > Département de Chimie > Laboratoire de Spectrométrie de Masse > >]
De Pauw, Edwin mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie physique, spectrométrie de masse >]
Vékey, Karoly [Institute of Chemistry of the Hungarian Academy of Sciences > > > >]
1999
Journal of Mass Spectrometry [=JMS]
John Wiley & Sons, Inc
34
1373-1379
Yes (verified by ORBi)
International
1076-5174
Chichester
United Kingdom
[en] Electrospray mass spectrometry ; Internal energy ; RRKM
[en] A new method was developped which fits a thermal internal energy distribution to ions formed by electrospray ionization. The molecular ion survival yield was measured and determined by RRKM calculations as a function of temperature. The "characteristic" temperature was determined when the calculated and measured molecular survival yields were equal. The validity of the method was also checked performing blackbody infrared radiation and on-resonance excitation experiments on a Fourier transform ion cyclotron resonance instrument with benzylpyridine salts and leucine enkephalin.
FOM Institute for Atomic and Molecular Physics- Amsterdam ; Laboratoire de Spectrométrie de Masse- Université de Liège ; Institute of Chemistry of the Hungarian Academy of Sciences- Budapest
Nederlandse Organisatie voor Wetenschappelijke Onderzoek (NWO) ; National Committee for Technological Development ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Researchers
http://hdl.handle.net/2268/4515
10.1002/(SICI)1096-9888(199912)34:12<1373::AID-JMS907>3.0.CO;2-#
http://www3.interscience.wiley.com/journal/68500492/issue

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