Reference : Comparison of the Internal Energy Distributions of Ions Produced by Different Electrospr...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/4514
Comparison of the Internal Energy Distributions of Ions Produced by Different Electrospray Sources
English
Collette, Caroline mailto [Université de Liège - ULg > Département de Chimie > Laboratoire de Spectrométrie de Masse > >]
Drahos, Laszlo [Institute of Chemistry of Hungarian Academy of Sciences > > > >]
De Pauw, Edwin mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie physique, spectrométrie de masse >]
Vékey, Karoly [Institute of Chemistry of Hungarian Academy of Sciences > > > >]
1998
Rapid Communications in Mass Spectrometry : RCM
John Wiley & Sons, Inc
12
1673-1678
Yes (verified by ORBi)
International
0951-4198
Chichester
United Kingdom
[en] Electrospray mass spectrometry ; Internal energy ; Thermometer ions
[en] The internal energies of the emitted ions can be modulated in an electrospray source through different experimental conditions. However, the fragmentation pattern depends also on conditions that cannot be controlled by the operator. These differences make difficult the comparison of the electrospray mass spectra obtained with different mass spectrometers. A method for the calibration of the internal energies of ions produced by an electrospray source has been presented previously to study the influence of experimental conditions on the internal energies of the ions. In this work, new results were obtained with modified values of fragmentation energy taking into account the kinetic shift of thermometer ions.
Laboratoire de Spectrométrie de Masse-Université de Liège ; Institute of Chemistry of Hungarian Academy of Sciences- Budapest
Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Researchers
http://hdl.handle.net/2268/4514
10.1002/(SICI)1097-0231(19981130)12:22<1673::AID-RCM385>3.0.CO;2-A
http://www3.interscience.wiley.com/journal/25000294/issue

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