Reference : Reverse atom-transfer radical polymerization at room temperature
Scientific journals : Article
Engineering, computing & technology : Materials science & engineering
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/4490
Reverse atom-transfer radical polymerization at room temperature
English
Wang, Wenxin [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Yan, Deyue [Shanghai Jiao Tong University, College of Chemistry and Chemical Technology, China > > > >]
Jiang, Xuling [Shanghai Jiao Tong University, College of Chemistry and Chemical Technology, China > > > >]
Detrembleur, Christophe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Lecomte, Philippe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Mar-2001
Macromolecular Rapid Communications
Wiley-V C H Verlag Gmbh
22
6
439-443
Yes (verified by ORBi)
International
1022-1336
Weinheim
[en] radical polymerization ; atom transfer radical polymerization (ATRP) ; (meth)acrylate
[en] This paper aims at reporting on the living/controlled radical polymerization of methyl methacrylate initiated with the benzoyl peroxide (BPO)/CuIX (X=Br,Cl)/2,2'-bipyridine (bpy) redox system at room temperature. No control is observed for the polymerization conducted in bulk and in toluene, whereas a polymer with predetermined molecular weight and rather narrow molecular weight distribution is formed in butanone. The solvent has thus a decisive effect on the reverse atom-transfer radical polymerization of methyl methacrylate initiated with the BPO/CuIX (X = Br,Cl)/bpy ternary system at 25°C.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Researchers
http://hdl.handle.net/2268/4490
10.1002/1521-3927(20010301)22:6<439::AID-MARC439>3.0.CO;2-W
http://www3.interscience.wiley.com/cgi-bin/fulltext/78505179/PDFSTART

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