ORBi: Wang Wenxin - Reverse atom-transfer radical polymerization at room temperature

Reference : Reverse atom-transfer radical polymerization at room temperature


	Document type :	Scientific journals : Article
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/4490

Title :	Reverse atom-transfer radical polymerization at room temperature
Language :	English
Author, co-author :	Wang, Wenxin [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Yan, Deyue [Shanghai Jiao Tong University, College of Chemistry and Chemical Technology, China > > > >]
	Jiang, Xuling [Shanghai Jiao Tong University, College of Chemistry and Chemical Technology, China > > > >]
	Detrembleur, Christophe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Lecomte, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	Mar-2001
Journal title :	Macromolecular Rapid Communications
Publisher :	Wiley-V C H Verlag Gmbh
Volume :	22
Issue/season :	6
Pages :	439-443
Audience :	International
ISSN :	1022-1336
City :	Weinheim
Keywords :	[en] radical polymerization ; atom transfer radical polymerization (ATRP) ; (meth)acrylate
Abstract :	[en] This paper aims at reporting on the living/controlled radical polymerization of methyl methacrylate initiated with the benzoyl peroxide (BPO)/CuIX (X=Br,Cl)/2,2'-bipyridine (bpy) redox system at room temperature. No control is observed for the polymerization conducted in bulk and in toluene, whereas a polymer with predetermined molecular weight and rather narrow molecular weight distribution is formed in butanone. The solvent has thus a decisive effect on the reverse atom-transfer radical polymerization of methyl methacrylate initiated with the BPO/CuIX (X = Br,Cl)/bpy ternary system at 25°C.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/4490
DOI :	10.1002/1521-3927(20010301)22:6<439::AID-MARC439>3.0.CO;2-W
Other URL :	http://www3.interscience.wiley.com/cgi-bin/fulltext/78505179/PDFSTART

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