[en] This paper reports on an efficient 'in-situ' one pot synthesis of an initiatior/ligand adduct, which can be used to initiate the anionic polymerization of methyl methacrylate in toluene at 0 °C. Predominantly syndiotactic PMMA is formed.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Zundel, Thomas; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
The in situ formation of a new initiator system for the syndiotactic anionic polymerization of methyl methacrylate in toluene at 0°C