Article (Scientific journals)
Anionic polymerization of methacrylic monomers: characterization of the propagating species
Zune, Catherine; Jérôme, Robert
1999In Progress in Polymer Science, 24 (5), p. 631-664
Peer Reviewed verified by ORBi
 

Files


Full Text
Zune C 1999 Prog Polym Sci 631.pdf
Publisher postprint (440.68 kB)
Request a copy
Full Text Parts
Zune_C_1999_Prog polym sci_24_5_631.pdf
Author postprint (350.88 kB)
Download

All documents in ORBi are protected by a user license.

Send to



Details



Keywords :
anionic polymerization; review
Abstract :
[en] Ligation of the anionic species responsible for the polymerization (LAP) of alkyl(meth)acrylates has much contributed to improve polymerization control. This ligated anionic polymerization has been firstly studied by using model compounds, such as low molecular weight lithium ester enolates. Recently, effort has been devoted to the direct analysis of the species that propagate the anionic polymerization of (meth)acrylates. In addition to IR, multinuclear NMR spectroscopy has been very instrumental in the elucidation of the structure and aggregation of the active species and how these characteristic features are modified by the addition of various types of ligands. This substantial progress in the characterization of the polyalkyl(meth)acrylate anions, ligated or not, is reported in this review.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Zune, Catherine;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Anionic polymerization of methacrylic monomers: characterization of the propagating species
Publication date :
August 1999
Journal title :
Progress in Polymer Science
ISSN :
0079-6700
Publisher :
Pergamon (Elsevier)
Volume :
24
Issue :
5
Pages :
631-664
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
Commentary :
The authors acknowledge Progress in Polymer Science (Elsevier) for allowing them to archive this paper.
Available on ORBi :
since 21 January 2009

Statistics


Number of views
129 (6 by ULiège)
Number of downloads
292 (1 by ULiège)

Scopus citations®
 
63
Scopus citations®
without self-citations
59
OpenCitations
 
54

Bibliography


Similar publications



Contact ORBi