Anionic polymerization of (meth)acrylic monomers: anionic polymerization of tert-butyl methacrylate in toluene

[en] The anionic polymerization of tBMA initiated by an organolithium compound in toluene at low temperature (-78 °C and 0 °C) has been revisited. Under these experimental conditions, no livingness is reported, consistently with formation of an important fraction of oligomers (Mn = 650).

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Zune, Catherine; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Dubois, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Anionic polymerization of (meth)acrylic monomers: anionic polymerization of tert-butyl methacrylate in toluene

Publication date :

July 1999

Journal title :

Polymer International

ISSN :

0959-8103

eISSN :

1097-0126

Publisher :

John Wiley & Sons

Volume :

Issue :

Pages :

565-570

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www3.interscience.wiley.com/cgi-bin/fulltext/62002170/PDFSTART

Commentary :

Polymer International

Available on ORBi :

since 21 January 2009

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Bibliography

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