Title : Anionic polymerization of (meth)acrylic monomers: anionic polymerization of tert-butyl methacrylate in toluene
Language : English
Author, co-author : Zune, Catherine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Dubois, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert [University of LIège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date : Jul-1999
Journal title : Polymer International
Publisher : John Wiley & Sons
Volume : 48
Issue/season : 7
Pages : 565-570
Audience : International
ISSN : 0959-8103
Keywords : [en] anionic polymerization
Abstract : [en] The anionic polymerization of tBMA initiated by an organolithium compound in toluene at low temperature (-78 °C and 0 °C) has been revisited. Under these experimental conditions, no livingness is reported, consistently with formation of an important fraction of oligomers (Mn = 650).
Research units : Center for Education and Research on Macromolecules (CERM)
Target : Researchers
Permalink : http://hdl.handle.net/2268/4416
DOI : 10.1002/(SICI)1097-0126(199907)48:7<565::AID-PI177>3.0.CO;2-3
Other URL : http://www3.interscience.wiley.com/cgi-bin/fulltext/62002170/PDFSTART
Commentary : Polymer International