Alternative atom transfer radical polymerization for MMA using FeCl3 and AIBN in the presence of triphenylphosphine: an easy way to well-controlled PMMA

Moineau, Georges; Dubois, Philippe; Jérôme, Robert; Senninger, Thierry; Teyssié, Philippe

doi:10.1021/ma971132o

Article (Scientific journals)

Alternative atom transfer radical polymerization for MMA using FeCl3 and AIBN in the presence of triphenylphosphine: an easy way to well-controlled PMMA

Moineau, Georges; Dubois, Philippe; Jérôme, Robert et al.

1998 • In Macromolecules, 31 (2), p. 545-547

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https://hdl.handle.net/2268/4354

DOI
10.1021/ma971132o

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Keywords :

radical polymerization; atom transfer radical polymerization (ATRP)

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Moineau, Georges; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Dubois, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Senninger, Thierry; Groupement de Recherches de Lacq, France > Service Polymères de Grande Diffusion et Catalyse

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Alternative atom transfer radical polymerization for MMA using FeCl3 and AIBN in the presence of triphenylphosphine: an easy way to well-controlled PMMA

Publication date :

27 January 1998

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

545-547

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma971132o

Funders :

Elf Atochem [FR]
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]

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since 19 January 2009

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Bibliography

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(b) Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614.
(c) Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 2216.
(d) Percec, V.; Barboiu, B.; Neumann, A.; Ronda, J. C.; Zhao, M. Macromolecules 1996, 29, 3665.
(e) Granel, C.; Dubois, P.; Jérôme, R.; Teyssié, P. Macromolecules 1996, 29, 8576.
(f) Haddleton, D. M.; Jasieczek, C. B.; Hannon, M. J.; Shooter, A. J. Macromolecules 1997, 30, 2190.
(g) Ando, T.; Kamigaito, M.; Sawamoto, M. Macromolecules 1997, 30, 4507.
Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7572.
(b) Matyjaszewski, K.; Patten, T. E.; Xia, J. J. Am. Chem. Soc. 1997, 119, 674.
Fisher, H. J. J. Am. Chem. Soc. 1986, 108, 3925.
(b) Fisher, H. J. Macromolecules 1997, 30, 5666.
Nishikawa, T.; Ando, T.; Kamigaito, M.; Sawamoto, M. Macromolecules 1997, 30, 2244.
(b) Moineau, G.; Dubois, Ph.; Jérôme, R.; Senninger, T.; Teyssié, Ph., to be submitted.
Initiation efficiency = Mn(calc)/Mn(SEC) with Mn(calc) = ([MMA]0/[macroinitiator]0) × MWMMA × conversion.
Conditions: T = 85 °C; solvent, toluene; [MMA]0 = 5.34 mol·L-1, [4,4′-azobis-4-cyanopentanoic acid]0 = 4.09 × 10-3 mol·L-1, [FeCl3]0 = 16.6 × 10-3 mol·L-1, [PPh3]0 = 49.8 × 10-3 mol·L-1; reaction time, 18 h; yield, 50%; Mn(SEC) = 77 000, Mw/Mn = 1.14. See also: Baumert, M.; Mülhaupt, R. Macromol. Rapid Commun. 18, 787 (1997).