Reference : New monomers tailored for direct electrografting onto carbon in water
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/4349
New monomers tailored for direct electrografting onto carbon in water
English
Cecius, Michaël [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
16-Apr-2007
Macromolecular Rapid Communications
Wiley-V C H Verlag Gmbh
28
8
948-954
Yes (verified by ORBi)
International
1022-1336
Weinheim
[en] electropolymerization ; electrografting
[en] Electrografting, which is an electropolymerization technique dedicated to the chemisorption of polyacrylates onto conductive surfaces, was actively studied in anhydrous organic media until now. This communication aims at extending this technique to aqueous media for the grafting of polyacrylates onto carbon. The key criterion for the successful electrografting under these not very demanding experimental conditions (water vs. anhydrous organic solvents) is the use of amphiphilic acrylic monomers. The impact of the chemical structure of these new monomers on the coating properties was investigated. Composition of the coatings was analyzed by FT-IR ATR and XPS, whereas film thickness and morphology were analyzed by ellipsometry and AFM, respectively.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; the "Deutsche Forschungsgemeinschaft, Graduiertenkolleg 1035 (Biointerface)"
Researchers
http://hdl.handle.net/2268/4349
10.1002/marc.200600882
http://www3.interscience.wiley.com/cgi-bin/fulltext/114209635/PDFSTART
The authors acknowledge Macromolecular Rapid Communications (Wiley) for allowing them to archive this paper.

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