Article (Scientific journals)
Polymer coating of steel by a combination of electrografting and atom-transfer radical polymerization
Claes, Michaël; Voccia, Samuel; Detrembleur, Christophe et al.
2003In Macromolecules, 36 (16), p. 5926-5933
Peer Reviewed verified by ORBi
 

Files


Full Text
Claes M 2003 Macromolecules 5926.pdf
Publisher postprint (181.82 kB)
Request a copy

All documents in ORBi are protected by a user license.

Send to



Details



Keywords :
electropolymerization; electrografting
Abstract :
[en] Cathodic electrografting of poly(2-chloropropionate ethyl acrylate) (poly[cPEA]) onto steel followed by the styrene grafting-from by atom transfer radical polymerization (ATRP) is an efficient strategy to impart strong adhesion to polystyrene films onto the electrically conductive substrate. Electrografting of poly(cPEA) chains at an appropriate potential and persistence of the activated chloride in the grafted chains were confirmed by XPS. Polystyrene deposition by ATRP with a ruthenium-based catalyst was analyzed by scanning electron microscopy and Raman spectroscopy. Adhesion of the polystyrene layer to the substrate is so strong that it cannot be detached by standard Scotch brand tapes. Moreover, local thermal analysis showed a loss of mobility for the PS chains tethered at the surface.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Author, co-author :
Claes, Michaël;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Voccia, Samuel;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Gilbert, Bernard ;  Université de Liège - ULiège > Department of Chemistry > Laboratory of Analytical Chemistry and Electrochemistry
Leclère, Philippe;  University of Mons-Hainaut > Chemistry of New Materials Department
Geskin, Victor;  Université de Liège - ULiège > Laboratory of Analytical Chemistry and Electrochemistry
Gouttebaron, Rachel;  University of Mons-Hainaut (UMH) > Service de Chimie Inorganique et Analytique (LASSIE)
Hecq, Michel;  University of Mons-Hainaut > Service de Chimie Inorganique et Analytique (LASSIE)
Lazzaroni, Roberto;  University of Mons-Hainaut (UMH) > Chemistry of New Materials Department
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Polymer coating of steel by a combination of electrografting and atom-transfer radical polymerization
Publication date :
12 August 2003
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
Amer Chemical Soc, Washington, United States - Washington
Volume :
36
Issue :
16
Pages :
5926-5933
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture [BE]
CE - Commission Européenne [BE]
FEDER - Fonds Européen de Développement Régional [BE]
Région wallonne [BE]
Available on ORBi :
since 16 January 2009

Statistics


Number of views
130 (7 by ULiège)
Number of downloads
0 (0 by ULiège)

Scopus citations®
 
37
Scopus citations®
without self-citations
27
OpenCitations
 
34

Bibliography


Similar publications



Contact ORBi