Reference : Polymer coating of steel by a combination of electrografting and atom-transfer radica...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/4282
Polymer coating of steel by a combination of electrografting and atom-transfer radical polymerization
English
Claes, Michaël [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Voccia, Samuel [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Detrembleur, Christophe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Gilbert, Bernard mailto [University of Liège (ULg) > Department of Chemistry > Laboratory of Analytical Chemistry and Electrochemistry > >]
Leclère, Philippe [University of Mons-Hainaut > > Chemistry of New Materials Department > >]
Geskin, Victor [University of Liège (ULg) > > Laboratory of Analytical Chemistry and Electrochemistry > >]
Gouttebaron, Rachel [University of Mons-Hainaut (UMH) > > Service de Chimie Inorganique et Analytique (LASSIE) > >]
Hecq, Michel [University of Mons-Hainaut > > Service de Chimie Inorganique et Analytique (LASSIE) > >]
Lazzaroni, Roberto [University of Mons-Hainaut (UMH) > > Chemistry of New Materials Department > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
12-Aug-2003
Macromolecules
Amer Chemical Soc
36
16
5926-5933
Yes (verified by ORBi)
International
0024-9297
Washington
[en] electropolymerization ; electrografting
[en] Cathodic electrografting of poly(2-chloropropionate ethyl acrylate) (poly[cPEA]) onto steel followed by the styrene grafting-from by atom transfer radical polymerization (ATRP) is an efficient strategy to impart strong adhesion to polystyrene films onto the electrically conductive substrate. Electrografting of poly(cPEA) chains at an appropriate potential and persistence of the activated chloride in the grafted chains were confirmed by XPS. Polystyrene deposition by ATRP with a ruthenium-based catalyst was analyzed by scanning electron microscopy and Raman spectroscopy. Adhesion of the polystyrene layer to the substrate is so strong that it cannot be detached by standard Scotch brand tapes. Moreover, local thermal analysis showed a loss of mobility for the PS chains tethered at the surface.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA ; Commission européenne ; Fonds Européen de Développement Régional - FEDER ; Région wallonne
Researchers
http://hdl.handle.net/2268/4282
10.1021/ma0217130
http://pubs.acs.org/doi/pdf/10.1021/ma0217130

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