[en] A new inimer that associates an alkoxyamine, which is an initiator/mediator in nitroxide mediated radical polymerization (NMP), and a polymerizable acrylate has been synthesized and used in a two-step "grafting-from" method. The acrylate has been first electropolymerized under a cathodic potential, such that the polymer is chemisorbed on the cathode. NMP of styrene has then been initiated from the electrografted polyacrylate chains with formation of polystyrene with controlled molecular weight and narrow polydispersity.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Voccia, Samuël; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Leclère, Philippe; University of Mons-Hainaut (UMH) > Chemistry of New Materials Department
Gouttebaron, Rachel; University of Mons-Hainaut (UMH) > Service de Chimie Inorganique et Analytique (LASSIE)
Hecq, Michel; University of Mons-Hainaut (UMH) > Service de Chimie Inorganique et Analytique (LASSIE)
Gilbert, Bernard ; Université de Liège - ULiège > Department of Chemistry > Laboratory of Analytical Chemistry and Electrochemistry
Lazzaroni, Roberto; University of Mons-Hainaut > Chemistry of New Materials Department
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Controlled free radical polymerization of styrene initiated from alkoxyamine attached to polyacrylate chemisorbed onto conducting surfaces
Publication date :
25 February 2003
Journal title :
Chemistry of Materials
ISSN :
0897-4756
eISSN :
1520-5002
Publisher :
American Chemical Society, Washington, United States - Washington
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture [BE] F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] Région wallonne [BE] European Community
Koutsos, V.; Van der Vegte, E. M.; Hadziioannou, G. Macromolecules 1999, 32, 1233.
Prucker, O.; Naumann, C. A.; Rühe, J.; Knoll, W.; Franck, C. W. J. Am. Chem. Soc. 1999, 121, 8766.
Zhao, B.; Brittain, W. J. Prog. Polym. Sci. 2000, 25, 677.
Matyjaszewski, K.; Miller, P. J.; Shukla, N.; Immaraporn, B.; Gelman, A.; Luokala, B. B.; Siclovan, T. M.; Kickelbick, G.; Vallan, T.; Hoffman, M.; Pakula, T. Macromolecules 1999, 32, 8716.
Husseman, M.; Malmstrom, E. E.; McNamara, M.; Mate, M.; Mecerreyes, D.; Benoit, D. G.; Hedrick, J. L.; Mansky, P.; Huang, E.; Russel, T. P.; Hawker, C. J. Macromolecules 1999, 32, 1424.
Baum, M.; Brittain, W. J. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2000, 41, 1315.
Nuß, S.; Böttcher, H.; Wurm, H.; Hallensleben, M. L. Angew. Chem., Int. Ed. 2001, 40, 4016.
Tsujii, Y., Ejaz, M.; Sato, K.; Goto, A.; Fukuda, J. Macromolecules 2001, 34, 8872.
Baum, M.; Brittain, W. J. Macromolecules 2002, 35, 610.
Möller, M.; Nederberg, F.; Lim, L. S.; Kange, R.; Hawker, C. J.; Hedrick, J. L.; Gu, Y.; Shah, R.; Abbott, N. L. J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 3529.
Benoit, D.; Chaplinsky, V.; Braslau, R.; Hawker, C. J. J. Am. Chem. Soc. 1999, 121, 3904.
Huseman, M.; Morrison, M.; Benoit, D.; Frommer, B.; Mate, C. M.; Hinsberg, W. D.; Hedrick, J. L.; Hawker, C. J. J. Am. Chem. Soc. 2000, 122, 1844.
Tanguy, J.; Deniau, G.; Augé, C.; Zalczer, G.; Lecayon, G. J. Electroanal. Chem. 1994, 377, 115.
