ORBi: Lou Xudong - Electrografting of preformed aliphatic polyesters onto metallic surfaces

Reference : Electrografting of preformed aliphatic polyesters onto metallic surfaces


	Document type :	Scientific journals : Article
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/4239

Title :	Electrografting of preformed aliphatic polyesters onto metallic surfaces
Language :	English
Author, co-author :	Lou, Xudong [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Christine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Detrembleur, Christophe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	2-Apr-2002
Journal title :	Langmuir
Publisher :	Amer Chemical Soc
Volume :	18
Issue/season :	7
Pages :	2785-2788
Audience :	International
ISSN :	0743-7463
City :	Washington
Keywords :	[en] electropolymerization ; electrografting
Abstract :	[en] Preformed aliphatic polyesters bearing pendent acrylate groups, poly(4-acryloyloxy-epsilon-caprolactone)co-epsilon-caprolactone) [poly(ACL-co-epsilonCL)], were grafted onto metallic surfaces by a cathodic electrochemical process. Content of acrylates must exceed a lower limit for them to be adsorbed on the cathode with the proper orientation and for the grafting to be successful. The strongly adhering films were analyzed by IR reflection-absorption spectroscopy and scanning electron microscopy. As a result of the known miscibility of poly-e-caprolactone with poly(vinyl chloride) (PVC), the pregrafting of poly(ACL-co-epsilonCL) imparts strong adhesion to PVC topcoats.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/4239
DOI :	10.1021/la011289g
Other URL :	http://pubs.acs.org/doi/pdf/10.1021/la011289g

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