Reference : Combination of ring-opening polymerization and "click" chemistry towards functionalizati...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/4203
Combination of ring-opening polymerization and "click" chemistry towards functionalization of aliphatic polyesters
English
Riva, Raphaël [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Schmeits, Stephanie [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Stoffelbach, François [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Lecomte, Philippe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > > >]
14-Nov-2005
Chemical Communications
Royal Society of Chemistry
42
5334-5336
Yes (verified by ORBi)
International
1359-7345
[en] ring-opening polymerization ; lactone ; click chemistry ; copper-mediated Huisgen's cycloaddition ; polymer functionalization
[en] Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly(ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 degrees C), such that the aliphatic polyesters are not degraded, including even poly(lactide) which is very sensitive to attack by weak nucleophiles.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Researchers
http://hdl.handle.net/2268/4203
10.1039/b510282k
http://www.rsc.org/ej/CC/2005/b510282k.pdf

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