ORBi: Riva Raphaël - Combination of ring-opening polymerization and "click" chemistry towards functionalization of aliphatic polyesters

Reference : Combination of ring-opening polymerization and "click" chemistry towards functionalizati...


	Document type :	Scientific journals : Article
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/4203

Title :	Combination of ring-opening polymerization and "click" chemistry towards functionalization of aliphatic polyesters
Language :	English
Author, co-author :	Riva, Raphaël [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Schmeits, Stephanie [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Stoffelbach, François [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > > >]
	Jérôme, Christine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > > >]
	Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Lecomte, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > > >]
Publication date :	14-Nov-2005
Journal title :	Chemical Communications
Publisher :	Royal Society of Chemistry
Issue/season :	42
Pages :	5334-5336
Audience :	International
ISSN :	1359-7345
Keywords :	[en] ring-opening polymerization ; lactone ; click chemistry ; copper-mediated Huisgen's cycloaddition ; polymer functionalization
Abstract :	[en] Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly(ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 degrees C), such that the aliphatic polyesters are not degraded, including even poly(lactide) which is very sensitive to attack by weak nucleophiles.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/4203
DOI :	10.1039/b510282k
Other URL :	http://www.rsc.org/ej/CC/2005/b510282k.pdf

File(s) associated to this reference

Fulltext file(s):

	File	Commentary	Version	Size	Access
Restricted access	Riva R 2005 Chem Commun 5334.pdf		Publisher postprint	197.03 kB	Request copy
Open access	Riva R 2005 Chem Commun 5334.pdf		Author postprint	352.29 kB	View/Open

All documents in ORBi are protected by a user license.

Dspace v1.5