Article (Scientific journals)
Control of the radical polymerization of tert-butyl methacrylate in water by a novel combination of sodium nitrite and iron(II) sulfate
Detrembleur, Christophe; Teyssié, Philippe; Jérôme, Robert
2002In Macromolecules, 35 (5), p. 1611-1621
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Keywords :
radical polymerization; nitroxide-mediated polymerization (NMP)
Abstract :
[en] Addition of iron(II) sulfate to sodium nitrite is a new way to control the radical polymerization of tert-butyl methacrylate (tBMA) in water at 80 degreesC. Nitric oxide is released in the reaction medium as result of the reduction of sodium nitrite by FeSO4. This reaction is of utmost importance because three repeated additions of an alkyl radical to nitric oxide leads to the formation of nitroxide radicals. The basic mechanism for the control of the radical polymerization is thus a nitroxide-mediated process.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Control of the radical polymerization of tert-butyl methacrylate in water by a novel combination of sodium nitrite and iron(II) sulfate
Publication date :
26 February 2002
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
Amer Chemical Soc, Washington, United States - District of Columbia
Volume :
35
Issue :
5
Pages :
1611-1621
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
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