Reference : Copolymerization of vinyl acetate with 1-octene and ethylene by cobalt-mediated radic...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/4105
Copolymerization of vinyl acetate with 1-octene and ethylene by cobalt-mediated radical polymerization
English
Bryaskova, Rayna [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Willet, Nicolas mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Degée, Philippe [University of Mons-Hainaut > > Laboratory of Polymeric and Composite Materials (SMPC) > >]
Dubois, Philippe [University of Mons-Hainaut > > Laboratory of Polymeric and Composite Materials (SMPC) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Detrembleur, Christophe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
15-Jun-2007
Journal of Polymer Science. Part A, Polymer Chemistry
Wiley
45
12
2532-2542
Yes (verified by ORBi)
International
0887-624X
1099-0518
Hoboken
[en] radical polymerization ; cobalt-mediated radical polymerization (CMRP)
[en] The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with I-alkenes (ethylene or 1-octene). In agreement with the low amount of I-alkene that could be incorporated into the copolymer, a gradient structure was predictable, but a. rather low polydispersity was observed. A poly(vinyl acetate)-b-poly(octene) copolymer was also successfully synthesized, leading to a poly (vinyl alcohol)-b-poly(octene) amphiphilic copolymer upon the methanolysis of the poly (vinyl acetate) block.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds Social Européen - FSE
Researchers
http://hdl.handle.net/2268/4105
10.1002/pola.21963
http://www3.interscience.wiley.com/cgi-bin/fulltext/114262036/PDFSTART
The authors acknowledge Journal of Polymer Science Part A-Polymer Chemistry(Wiley) for allowing them to archive this paper.

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