Reference : ATRP of Methacrylates Catalysed by Homo- and Heterobimetallic Ruthenium Complexes
Parts of books : Contribution to collective works
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/40279
ATRP of Methacrylates Catalysed by Homo- and Heterobimetallic Ruthenium Complexes
English
Borguet, Yannick mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
Sauvage, Xavier [> > > >]
Bicchielli, Dario [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
Delfosse, Sébastien [> > > >]
Delaude, Lionel mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
Demonceau, Albert mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
Bareille, Laurianne [> > > >]
Le Gendre, Pierre [> >]
Moïse, Claude [> >]
2009
Controlled/Living Radical Polymerization: Progress in ATRP
Matyjaszewski, Krzysztof
American Chemical Society
ACS Symposium Series 1023
97-114
0-8412-6995-5
Washington
USA
[en] The catalytic activity of a series of ruthenium-based homo- and heterobimetallic complexes was determined by investigating the atom transfer radical polymerisation of methyl methacrylate. The complexes under investigation were [(arene)Ru(µ-Cl)3RuCl(C2H4)-(L)] (L = PCy3 or a N-heterocyclic carbene ligand), [(p-cymene)-Ru(µ-Cl)3RuCl(=C=CHR)(PCy3)] (R = Ph or t-Bu), and [RuCl2-(p-cymene){PCy2(CH2)2(eta5-C5H4)TiX2(eta5-C5H5)}] (X = Cl, F, and OBz). The catalytic activity of a variety of related [(p-cymene)-ClRu(µ-Cl)2Ru(O‚^N)(=CHPh)] complexes (O^N is a Schiff base ligand) is also reported. The results clearly demonstrate that the ligands strongly affect the ability of the resulting ruthenium complexes to favour the occurrence of a well-behaved ATRP.
Researchers ; Professionals
http://hdl.handle.net/2268/40279
10.1021/bk-2009-1023.ch007

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