Article (Scientific journals)
“One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in supercritical carbon dioxide: towards the formation of functional microspheres
Grignard, Bruno; Calberg, Cédric; Jérôme, Christine et al.
2010In Journal of Supercritical Fluids, 53 (1-3), p. 151-155
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Keywords :
green technology; supercritical carbon dioxide; click chemistry; copper-mediated Huisgen's cycloaddition; radical polymerization; atom transfer radical polymerization (ATRP)
Abstract :
[en] Functional polymers were successfully prepared in scCO2 by combining alkyne-azide 1,3-dipolar Huisgen’s cycloaddition and dispersion ATRP in a “one pot” process using new perfluorinated polymeric amino-based ligands that had a dual role, i.e. the complexation of the copper catalyst and the stabilization of growing particles.
Research center :
Center for Education and Researchon Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Grignard, Bruno ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Calberg, Cédric ;  Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Industrial Chemistry
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
“One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in supercritical carbon dioxide: towards the formation of functional microspheres
Publication date :
June 2010
Journal title :
Journal of Supercritical Fluids
ISSN :
0896-8446
Publisher :
Elsevier Science, Amsterdam, Netherlands
Volume :
53
Issue :
1-3
Pages :
151-155
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
The “Région Wallonne” and the FEDER in the frame of the POLYTISS program
Available on ORBi :
since 14 January 2010

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