[en] green technology ; supercritical carbon dioxide ; click chemistry ; copper-mediated Huisgen's cycloaddition ; radical polymerization ; atom transfer radical polymerization (ATRP)
[en] Functional polymers were successfully prepared in scCO2 by combining alkyne-azide 1,3-dipolar Huisgen’s cycloaddition and dispersion ATRP in a “one pot” process using new perfluorinated polymeric amino-based ligands that had a dual role, i.e. the complexation of the copper catalyst and the stabilization of growing particles.
Center for Education and Researchon Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; The “Région Wallonne” and the FEDER in the frame of the POLYTISS program