Reference : “One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in superc...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/3883
“One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in supercritical carbon dioxide: towards the formation of functional microspheres
English
Grignard, Bruno [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Calberg, Cédric mailto [University of Liège (ULg) > Department of Applied Chemistry > Laboratory of Industrial Chemistry > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Detrembleur, Christophe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jun-2010
Journal of Supercritical Fluids
Elsevier Science
53
1-3
151-155
Yes (verified by ORBi)
International
0896-8446
Amsterdam
The Netherlands
[en] green technology ; supercritical carbon dioxide ; click chemistry ; copper-mediated Huisgen's cycloaddition ; radical polymerization ; atom transfer radical polymerization (ATRP)
[en] Functional polymers were successfully prepared in scCO2 by combining alkyne-azide 1,3-dipolar Huisgen’s cycloaddition and dispersion ATRP in a “one pot” process using new perfluorinated polymeric amino-based ligands that had a dual role, i.e. the complexation of the copper catalyst and the stabilization of growing particles.
Center for Education and Researchon Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; The “Région Wallonne” and the FEDER in the frame of the POLYTISS program
Researchers
http://hdl.handle.net/2268/3883
10.1016/j.supflu.2009.12.014

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