Reference : Ring opening copolymerization of ε-caprolactone, γ-(triethylsilyloxy)-ε-caprolactone ...
Scientific journals : Article
Engineering, computing & technology : Materials science & engineering
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/3753
Ring opening copolymerization of ε-caprolactone, γ-(triethylsilyloxy)-ε-caprolactone and γ-ethylene ketal-ε-caprolactonelactone: a route to hetero-graft copolyesters
English
Stassin, Fabrice [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Halleux, Olivier [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Dubois, Philippe [University of Mons-Hainaut (UMH) > > Laboratory of Polymeric and Composite Materials (SMPC) > >]
Detrembleur, Christophe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Lecomte, Philippe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Mar-2000
Macromolecular Symposia
Wiley-V C H Verlag Gmbh
153
27-39
Yes (verified by ORBi)
International
1022-1360
1521-3900
Weinheim
[en] ring-opening polymerization ; lactone ; graft polymer
[en] ε-Caprolactone (ε-CL) has been copolymerized with two precursors of γ-hydroxy-ε-CL, i.e., γ-ethylene ketal-ε-caprolactone (TOSUO) and γ-(triethylsilyloxy)-ε-caprolactone (TeSCL). The triethylsilyloxy pendant groups can be selectively deprotected into hydroxyl groups followed by the deprotection of the acetal substituents. Each series of hydroxyl groups can be used to initiate the polymerization of cyclic monomers so leading to hetero-graft copolyesters with, for instance, poly-ε-CL and polylactide grafts.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Researchers
http://hdl.handle.net/2268/3753
10.1002/1521-3900(200003)153:1<27::AID-MASY27>3.0.CO;2-N
http://www3.interscience.wiley.com/cgi-bin/fulltext/76504663/PDFSTART

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