Reference : PH-responsive biodegradable amphiphilic networks
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/3670
PH-responsive biodegradable amphiphilic networks
English
Zednik, Jiri [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Riva, Raphaël [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Lussis, Perrine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Lecomte, Philippe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
4-Feb-2008
Polymer
Elsevier
49
3
697-702
Yes (verified by ORBi)
International
0032-3861
Oxford
England
[en] ring-opening polymerization ; network ; click chemistry ; lactone ; copper-mediated Huisgen's cycloaddition
[en] Copper-mediated azide - alkyne Huisgen's 1,3-dipolar cycloaddition is a "click" reaction that was successfully used to prepare pH-responsive, amphiphilic and biodegradable networks. Indeed, this reaction proved to be very efficient in the "one pot" grafting of amino alkyne onto azide containing poly(epsilon-caprolactone) and the cross-linking of these chains by alpha,omega-dialkynyl poly(ethylene oxide). The pH-controlled release of guests hosted during the cross-linking step was illustrated with an entrapped model dye.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Researchers
http://hdl.handle.net/2268/3670
10.1016/j.polymer.2007.12.029
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TXW-4RFJ4M6-1-M&_cdi=5601&_user=532038&_orig=browse&_coverDate=02%2F04%2F2008&_sk=999509996&view=c&wchp=dGLbVzz-zSkWA&md5=c68c7236b24c85cec76b901504911ca4&ie=/sdarticle.pdf
The authors acknowledge Polymer (Elsevier) for allowing them to archive this paper.

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