Article (Scientific journals)
Hyperfine interactions and lattice dynamics of Sn21O6Cl16(OH)(14)
Sougrati, Moulay Tahar; Jouen, S.; Hannoyer, Béatrice et al.
2008In Journal of Solid State Chemistry, 181 (9), p. 2473-2479
Peer Reviewed verified by ORBi
 

Files


Full Text
JSSC-2008.pdf
Publisher postprint (867.12 kB)
Request a copy

All documents in ORBi are protected by a user license.

Send to



Details



Keywords :
tin; tin(II) oxy-hydroxychloride; Mossbauer spectroscopy; low temperature; recoil-free fraction; abhurite
Abstract :
[en] In this study, the tin(II) oxy-hydroxychloride Sn21O6Cl16(OH)(14) has been synthesised and investigated, This compound is the synthetic equivalent of mineral abhurite, which was discovered in 1985 as a tin corrosion product formed on the surface of tin ingots after long immersion in seawater. The Mossbauer parameters of Sn(21)O6Cl(16)(OH)(14) determined at various temperatures are reported and discussed for the first time. At room temperature, the isomer shift and the quadrupole splitting are, respectively, delta = 3.22 mm s(-1) and Delta = 1.71 mm s(-1) relative to the centroid of the spectrum of BaSnO3. ne Mossbauer recoil-free fraction has been also evaluated over a wide range of temperature. At 300 K, the recoil-free fraction of Sn21O6Cl16(OH)(14) is f(300) = 0.09 +/- 0.02. (C) 2008 Elsevier Inc. All rights reserved.
Disciplines :
Chemistry
Author, co-author :
Sougrati, Moulay Tahar ;  Université de Liège - ULiège > Département de physique > Département de physique
Jouen, S.
Hannoyer, Béatrice
Lefez, B.
Language :
English
Title :
Hyperfine interactions and lattice dynamics of Sn21O6Cl16(OH)(14)
Publication date :
2008
Journal title :
Journal of Solid State Chemistry
ISSN :
0022-4596
eISSN :
1095-726X
Publisher :
Academic Press, San Diego, United States - California
Volume :
181
Issue :
9
Pages :
2473-2479
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 17 December 2008

Statistics


Number of views
63 (8 by ULiège)
Number of downloads
1 (1 by ULiège)

Scopus citations®
 
5
Scopus citations®
without self-citations
4
OpenCitations
 
4

Bibliography


Similar publications



Contact ORBi