Organometallic-mediated alternating radical copolymerization of tert-butyl-2- trifluoromethacrylate with vinyl acetate and synthesis of block copolymers thereof
[en] Organometallic-mediated radical polymerization (OMRP) has given access to well-defined poly(vinyl acetate-alt-tert-butyl-2-trifluoromethacrylate)-b-poly(vinyl acetate) and poly (VAc- alt-MAF-TBE) copolymers composed of two electronically distinct monomers: vinyl acetate (VAc, donor, D) and tert-butyl-2-trifluoromethacrylate (MAF-TBE, acceptor, A), with low dispersity (≤1.24) and molar masses up to 57 000 g mol−1. These copolymers have a precise 1:1 alternating structure over a wide range of comonomer feed compositions. The reactivity ratios are determined as rVAc = 0.01 ± 0.01 and rMAF-TBE = 0 at 40 °C. Remarkably, from a feed containing >50% molar VAc content, poly(VAc-alt-MAF-TBE)-b- PVAc block copolymers are produced via a one- pot synthesis. Such diblock copolymers exhibit two glass transition temperatures attributed to the alternating and homopolymer sequences. The OMRP of this fluorine-containing alter- nating monomer system may provide access to a wide range of new polymer materials.
Research center :
Center for Education and Research on Macromolecules (CERM) CESAM Complex and Entangled Systems from Atoms to Materials (CESAM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Banerjee, Sanjib; Institut Charles Gerhardt, Ingénierie et Architectures Macromoléculaires, Montpellier, France
Ladmiral, Vincent; Institut Charles Gerhardt, Ingénierie et Architectures Macromoléculaires, Montpellier, France
Debuigne, Antoine ; University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Rahaman S. M., Wahidur; University of Toulouse, CNRS, Laboratoire de Chimie de Coordination, France
Poli, Rinaldo; University of Toulouse, CNRS, Laboratoire de Chimie de Coordination > Institut Universitaire de France, Paris, France
Améduri, Bruno; Institut Charles Gerhardt, Ingénierie et Architectures Macromoléculaires, Montpellier, France
Language :
English
Title :
Organometallic-mediated alternating radical copolymerization of tert-butyl-2- trifluoromethacrylate with vinyl acetate and synthesis of block copolymers thereof
Publication date :
August 2017
Journal title :
Macromolecular Rapid Communications
ISSN :
1022-1336
eISSN :
1521-3927
Publisher :
Wiley, Weinheim, Germany
Volume :
38
Issue :
15
Pages :
1700203
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
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