The Rotational Predissociation of the CH4+ and CD4+ Ions.

Flamme, J. P.; Wankenne, H.; Locht, Robert; Momigny, J.; Nowak, P.J.C.M.; Los, J.

doi:10.1016/0301-0104(78)85160-X

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Article (Scientific journals)

The Rotational Predissociation of the CH4+ and CD4+ Ions.

Flamme, J. P.; Wankenne, H.; Locht, Robert et al.

1978 • In Chemical Physics, 27, p. 45-49

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/211

DOI
10.1016/0301-0104(78)85160-X

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Keywords :

Metastable decomposition; Translational energy spectroscopy; CH3+/CH4, CD3+/CD4; Tunneling through a rotational barrier; Kinetic energy release

Abstract :

[en] The metastable transitions producing CH3+/CH4 and CD3+/CD4 have been investigated by means of translational spectroscopy. For the first time structures are observed in a metastable peak corresponding to the dissociation of a polyatomic ion. They are interpreted by tunneling through a rotational barrier from discrete quasi-bound states. Kinetic energy releases have been measured.

Disciplines :

Chemistry

Author, co-author :

Flamme, J. P.

Wankenne, H.

Locht, Robert ; Université de Liège - ULiège > Département de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)

Momigny, J.

Nowak, P.J.C.M.

Los, J.; FOM Instituut voor Atoom- en Molekuulfysika > Amsterdam

Language :

English

Title :

The Rotational Predissociation of the CH4+ and CD4+ Ions.

Alternative titles :

[fr] La predissociation rotationnelle des ions CH4+ et CD4+.

Publication date :

1978

Journal title :

Chemical Physics

ISSN :

0301-0104

Publisher :

Elsevier Science, Amsterdam, Netherlands

Volume :

Pages :

45-49

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

FOM, FRFC, FNRS

Commentary :

- Printed version of reprint available on request - Version imprimée du tiré-à-part disponible sur demande

Available on ORBi :

since 10 July 2008

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Bibliography

Melton, Rosenstock J. Chem. Phys. 1957, 26:568.
Dibeler, Rosenstock J. Chem. Phys. 1963, 39:1326.
Ottinger Z. Naturforsch. 1965, 20:1232.
Rosenstock Advan. Mass Spectrom. 1968, 4:523.
Hills, Vestal, Futrell J. Chem. Phys. 1971, 54:3834.
Krauss, Wahrhaftig, Eyring (1955) Mass Spectra and the Chemical Species Produced by the Impact of Low Energy Electrons. Annual Review of Nuclear Science 5:241.
Smith, Futrell Intern. J. Mass Spectrom. Ion Phys. 1976, 20:425.
Flamme, Momigny, Wankenne J. Am. Chem. Soc. 1976, 98:1045.
Klots Chem. Phys. Letters 1971, 10:422.
Solka, Beynon, Cooks J. Phys. Chem. 1975, 79:859.
Maas, van Asselt, Los Chem. Phys. 1975, 8:37.
Locht, Maas, van Asselt, Los Chem. Phys. 1976, 15:179.
Maas, van Asselt, Nowak, Los, Peyerimhoff, Buenker Chem. Phys. 1976, 17:217.
Fournier Méthodes de spectroscopie sans largeur Doppler de niveaux excités de systèmes moléculaires simples , Coll. Intern. du CNRS no. 217 CNRS Paris; 1973, 169.
Anderson J. Chem. Phys. 1974, 60:3278.
Terwilliger, Beynon, Cooks (1974) Kinetic Energy Distributions from the Shapes of Metastable Peaks. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 341:135.
Rabalais, Bergmark, Werme, Karlsson, Siegbahn (1971) The Jahn-Teller Effect in the Electron Spectrum of Methane. Physica Scripta 3:13.
Herzberg Electronic spectra of polyatomic molecules , Van Nostrand, New York; 1966, 473.
.