Reference : Overview of cobalt-mediated radical polymerization: roots, state of the art and future p...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/20975
Overview of cobalt-mediated radical polymerization: roots, state of the art and future prospects
English
Debuigne, Antoine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Poli, Rinaldo [Université Paul Sabatier, Institut National Polytechnique de Toulouse et Institut Universitaire de France (Paris, France) > > Laboratoire de Chimie de Coordination, UPR CNRS 8241 (Toulouse) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Detrembleur, Christophe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Mar-2009
Progress in Polymer Science
Elsevier Science
34
3
211-239
Yes (verified by ORBi)
International
0079-6700
[en] radical polymerization ; cobalt-mediated radical polymerization (CMRP) ; review
[en] Controlled radical polymerization (CRP) techniques offer the opportunity to properly design polymer chains and adjust their chemical and physical properties. Among these techniques, cobalt-mediated radical polymerization (CMRP) distinguished itself by the high level of control imparted to the polymerization of acrylic and vinyl ester monomers, even for high molar masses. This article summarizes for the first time the advances in understanding and synthetic scope of CMRP since its discovery. Notably, the cobalt–carbon bond formation by dual contribution of reversible termination and degenerative chain transfer is discussed, as well as the impact of additives able to coordinate the metal. The potential of computational chemistry in the field of CMRP as a rationalization and predicting tool is also presented. These mechanistic considerations and achievements in macromolecular engineering will be discussed along with challenges and future prospects in order to assess the CMRP system as a whole.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; The Institut Universitaire de France and the “Agence National de la Recherche”
Researchers
http://hdl.handle.net/2268/20975
10.1016/j.progpolymsci.2008.11.003
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TX2-4VCNP5B-1-2H&_cdi=5578&_user=532038&_orig=browse&_coverDate=03%2F31%2F2009&_sk=999659996&view=c&wchp=dGLzVzz-zSkWb&md5=84f0833987af97850b508b879ce5a12a&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/418/description#description
The authors acknowledge Progress in Polymer Science (Elsevier) for allowing them to archive this paper.

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