Reference : Elaboration of new formulations to remove micropollutants in MSWI flue gas
Scientific journals : Article
Engineering, computing & technology : Materials science & engineering
Engineering, computing & technology : Chemical engineering
Life sciences : Environmental sciences & ecology
http://hdl.handle.net/2268/20301
Elaboration of new formulations to remove micropollutants in MSWI flue gas
English
Brasseur, Alain [Université de Liège - ULG > Département de Chimie appliquée > Génie chimique - Chimie physique appliquée > >]
Gambin, Amandine [> > > >]
Laudet, Alain [Lhoist S.A. > Recherche et Développement > > >]
Marien, José mailto [Université de Liège - ULg > Département de chimie appliquée > Chimie générale et chimie physique >]
Pirard, Jean-Paul mailto [Université de Liège - ULg > Département de chimie appliquée > Génie chimique - Chimie physique appliquée > >]
2004
Chemosphere
Elsevier Science
56
8
745-756
Yes (verified by ORBi)
International
0045-6535
Oxford
United Kingdom
[en] sepiolite ; micropollutants ; chlorobenzene ; MSWI ; adsorption ; temperature programmed desorption
[en] This study consists in identifying and testing potential inorganic substitutes to carbon based materials commonly used as adsorbents for the removal of organic pollutants such as dioxins and furans released from Municipal Solid Waste Incinerators (MSWI). Although carbon materials enable to reach the current regulation in terms of dioxins and furans emissions, they exhibit a potential auto ignition risk when present in hot flue gases. Here, the adsorption potential of carbon based products is compared to the one of some inorganic materials. Chlorobenzene was chosen as a reference molecule to compare the removal performance of the different adsorbents. This comparison was based on the determination of the adsorption energies derived from temperature programmed desorption (TPD) experiments. In the first part of this study, five inorganic materials were selected according to their chlorobenzene adsorption performance compared to those of carbon based products currently used to remove micropollutants from MSWI flue gases. In the second part of the study, the influence of the inlet concentration of adsorbate on the adsorption potential of sorbents is investigated. Actually, the organic compound concentration was decreased in order to be closer to those met in MSWI. Furthermore, the adsorption experiments were performed with other adsorbates whose molecular mass or chlorine content are higher. Thanks to these adsorption results a new organic free formulation has been proposed for the removal of micropollutants. Tests carried out on an industrial scale, demonstrated that this product enables to reach the current norm concerning dioxins and furans emissions. (C) 2004 Elsevier Ltd. All rights reserved.
http://hdl.handle.net/2268/20301
also: http://hdl.handle.net/2268/20208
10.1016/j.chemosphere.2004.04.049

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